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Performance of a Current generation catalytic converter using Pd/Rh (10:1) as binary catalyst impeded on an ultra thin ceramic substrate and alumina wash coat is modeled for performance prediction and parametric optimization. Kinetic rates for the catalyst are reduced after conducting series of experiments on a passenger car engine. A new concept in mass transfer coefficient is introduced for improving accuracy of the model prediction. In order to take care of the precious metal resources and to become independent of precious metal price fluctuation, a new pattern of loading of precious metal is suggested for optimum performance and metal savings about 46 percent was observed. Experimental investigations were carried out to validate the established kinetic rates over a wide range operation of the engine and for the model validation. Satisfactory agreements are observed for the model prediction and experimental results.

The effect of variation in injection pressure and Injection timing on the performance and exhaust emission characteristics of a direct injection, naturally aspirated Diesel engine operating on Diesel and Diesel-Biodiesel Blends were studied. A three-way factorial design consisting of four levels of injection pressure (150,210, 265,320 bar), four levels of injection timing (19° btdc, 21.5° btdc, 26° btdc, and 30.5° btdc) and five different fuel types (D100, B10, B20, B40, and B60) were employed in this test. The experimental analysis shows that when operating with Linseed Oil Methyl Ester-Diesel blends, we could increase the injection pressure by about 25% over the normal value of 20MPa. The engine performance and exhaust emission characteristics of the engine operating on the ester fuels at advanced injection timing were better than when operating at increased injection pressure.