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Using renewable fuels is a reliable approach for decarbonization of combustion engines. iso-Butanol and n-butanol are known as longer chain alcohols and have the potential of being used as gasoline substitute or a renewable fraction of gasoline. The combustion behavior of renewable fuels in modern combustion engines and advanced combustion concepts is not well understood yet. Low-temperature combustion (LTC) is a concept that is a basis for some of the low emissions-high efficiency combustion technologies. Fuel ɸ-sensitivity is known as a key factor to be considered for tailoring fuels for these engines. The Lund ɸ-sensitivity method is an empirical test method for evaluation of the ɸ-sensitivity of liquid fuels and evaluate fuel behavior in thermal. iso-Butanol and n-butanol are two alcohols which like other alcohol exhibit nonlinear behavior when blended with (surrogate) gasoline in terms of RON and MON.

A detailed description of a numerical method for computing unsteady flows in engine intake and exhaust systems is given. The calculations include the effects of heat transfer and friction. The inclusion of such calculations in a mathematically simulated engine cycle is discussed and results shown for several systems. In particular, the effects of bell-mouth versus plain pipe terminations and the effects of a finite surge tank are calculated. Experimental data on the effect of heat transfer from the back of the intake valve on wave damping are given and show the effect to be negligible. Experimental data on wave damping during the valve closed period and on the temperature rise of the air near the valve are also given.

The ratio of two temperature gradients across the combustion-chamber wall in a diesel engine is used to provide a heat flow ratio showing the radiant heat transfer as a per cent of local total heat transfer. The temperature gradients were obtained with a thermocouple junction on each side of the combustion-chamber wall. The first temperature gradient was obtained by covering the thermocouple at the cylinder gas-wall interface with a thin sapphire window, while the second was obtained without the window. Results show that the time-average radiant heat transfer is of significant magnitude in a diesel engine, and is probably even more significant in heat transfer during combustion and expansion.

The objective of this research was to investigate the effect of injection pressure on air entrainment into transient diesel sprays. The main application of interest was the direct injection diesel engine. Particle Image Velocimetry was used to make measurements of the air entrainment velocities into a spray plume as a function of time and space. A hydraulically actuated, electronically controlled unit injector (HEUI) system was used to supply the fuel into a pressurized spray chamber. The gas chamber density was maintained at 27 kg/m3. The injection pressures that were studied in this current research project were 117.6 MPa and 132.3 MPa. For different injection pressures, during the initial two-thirds of the spray plume there was little difference in the velocities normal to the spray surface. For the last third of the spray plume, the normal velocities were 125% higher for the high injection pressure case.

A correlation was developed to predict the ignition delay of PRF blends at a wide range of engine-relevant operating conditions. Constant volume simulations were performed using Cantera coupled with a reduced reaction mechanism at a range of initial temperatures from 570-1860K, initial pressures from 10-100atm, oxygen mole percent from 12.6% to 21%, equivalence ratios from 0.30-1.5, and PRF blends from PRF0 to PRF100. In total, 6,480 independent ignition delay simulations were performed. The correlation utilizes the traditional Arrhenius formulation; with equivalence ratio (φ), pressure (p), and oxygen mole percentage (xo2) dependencies. The exponents α, β, and γ were fitted to a third order polynomial with respect to temperature with an exponential roll-off to a constant value at low temperatures to capture the behavior expressed by the reaction mechanism. The location and rate of the roll-off functions were modified by linear functions of PRF.

Dual-mode dual-fuel combustion is a promising combustion concept to achieve the required emissions and CO2 reductions imposed by the next standards. Nonetheless, the fuel formulation requirements are stricter than for the single-fuel combustion concepts as the combustion concept relies on the reactivity of two different fuels. This work investigates the effect of the low reactivity fuel sensitivity (S=RON-MON) and the octane number at different operating conditions representative of the different combustion regimes found during the dual-mode dual-fuel operation. For this purpose, experimental tests were performed using a PRF 95 with three different sensitivities (S0, S5 and S10) at operating conditions of 25% load/950 rpm, 50%/1800 rpm and 100%/2200 rpm. Moreover, air sweeps varying ±10% around a reference air mass were performed at 25%/1800 rpm and 50%/1800 rpm. Conventional diesel fuel was used as high reactivity fuel in all the cases.

With ever-demanding emission legislations in Compression Ignition (CI) engines, new premixed combustion strategies have been developed in recent years seeking both, emissions and performance improvements. Since it has been shown that in-cylinder air flow affects the combustion process, and hence the overall engine performance, the study of swirling structures and its interaction with fuel injection are of great interest. In this regard, possible Turbulent Kinetic Energy (TKE) distribution changes after fuel injection may be a key parameter for achieving performance improvements by reducing in-cylinder heat transfer. Consequently, this paper aims to gain an insight into spray-swirl interaction through the analysis of in-cylinder velocity fields measured by Particle Image Velocimetry (PIV) when PCCI conditions are proposed. Experiments are carried out in a single cylinder optical Diesel engine with bowl-in-piston geometry.

In this work a detailed soot model based on stationary flamelets is used to simulate soot emissions of a reactive Diesel spray. In order to represent soot formation and oxidation processes properly, a calibration of the soot reaction rates has to be performed. This model calibration is usually performed on basis of engine out soot measurements. Contrary to this, in this work the soot model is calibrated on local soot concentrations along the spray axis obtained from laser extinction chamber measurements. The measurements are performed with B7 certification Diesel and a series production multihole injector to obtain engine similar boundary conditions. In order to ensure that the flow and mixture field is captured well by the CFD-simulation, the simulated liquid penetration lengths and flame lift-off lengths are compared to chamber measurements.

In the past few years’ various studies have shown how the application of a highly premixed dual fuel combustion for CI engines leads a strong reduction for both pollutant emissions and fuel consumption. In particular a drastic soot and NOx reduction were achieved. In spite of the most common strategy for dual fueling has been represented by using two different injection systems, various authors are considering the advantages of using a single injection system to directly inject blends in the chamber. In this scenario, a characterization of the behavior of such dual-fuel blend spray became necessary, both in terms of inert and reactive ambient conditions. In this work, a light extinction imaging (LEI) has been performed in order to obtain two-dimensional soot distribution information within a spray flame of different diesel/gasoline commercial fuel blends. All the measurements were conducted in an optically accessible two-stroke engine equipped with a single-hole injector.

A detailed mathematical model of the thermodynamic events of a crankcase scavenged, two-stroke, SI engine is described. The engine is divided into three thermodynamic systems: the cylinder gases, the crankcase gases, and the inlet system gases. Energy balances, mass continuity equations, the ideal gas law, and thermodynamic property relationships are combined to give a set of coupled ordinary differential equations which describe the thermodynamic states encountered by the systems of the engine during one cycle of operation. A computer program is used to integrate the equations, starting with estimated initial thermodynamic conditions and estimated metal surface temperatures. The program iterates the cycle, adjusting the initial estimates, until the final conditions agree with the beginning conditions, that is, until a cycle results.

Schlieren/shadowgraphy has been adopted in the combustion research as a standard technique for tip penetration analysis of sprays under diesel-like engine conditions. When dealing with schlieren images of reacting sprays, the combustion process and the subsequent light emission from the soot within the flame have revealed both limitations as well as considerations that deserve further investigation. Seeking for answers to such concerns, the current work reports an experimental study with this imaging technique where, besides spatial filtering at the Fourier plane, both short exposure time and chromatic filtering were performed to improve the resulting schlieren image, as well as the reliability of the subsequent tip penetration measurement. The proposed methodology has reduced uncertainties caused by artificial pixel saturation (blooming).

Highly time resolved measurements of cylinder pressure acquired simultaneously from three transducers were used to investigate the nature of knocking combustion and to identify biases that the pressure measurements induce. It was shown by investigating the magnitude squared coherence (MSC) between the transducer signals that frequency content above approximately 40 kHz does not originate from a common source, i.e., it originates from noise sources. The major source of noise at higher frequency is the natural frequency of the transducer that is excited by the impulsive knock event; even if the natural frequency is above the sampling frequency it can affect the measurements by aliasing. The MSC analysis suggests that 40 kHz is the appropriate cutoff frequency for low-pass filtering the pressure signal. Knowing this, one can isolate the knock event from noise more accurately.

The continuous improvement of internal combustion engines (ICEs) with strategies that can be applied to existing vehicle platforms, either directly or with minor modifications, can improve efficiency and reduce GHG emissions to help achieve Paris climate targets. Low carbon fuels (LCF) as diesel substitutes for light and heavy-duty vehicles are currently being considered as a promising alternative to reduce well-to-wheel (WTW) CO2 emissions by taking advantage of the carbon offset their synthesis pathway can promote, which could capture more CO2 than it releases into the atmosphere. Additionally, some low carbon fuels, like OMEx blends, have non-sooting properties that can significantly improve the NOx-soot tradeoff. The current work studies the calibration optimization of a EU6D-TEMP light-duty engine using various LCFs with different renewable contents with the goal of reduced NOx emissions.

This work investigates the particulates size distribution of reactivity controlled compression ignition combustion, a dual-fuel concept which combines the port fuel injection of low-reactive/gasoline-like fuels with direct injection of highly reactive/diesel-like fuels. The particulates size distributions from 5-250 nm were measured using a scanning mobility particle sizer at six engine speeds, from 950 to 2200 rpm, and 25% engine load. The same procedure was followed for conventional diesel combustion. The study was performed in a single-cylinder engine derived from a stock medium-duty multi-cylinder diesel engine of 15.3:1 compression ratio. The combustion strategy proposed during the tests campaign was limited to accomplish both mechanical and emissions constraints. The results confirms that reactivity controlled compression ignition promotes ultra-low levels of nitrogen oxides and smoke emissions in the points tested.

With demanding emissions legislations and the need for higher efficiency, new technologies for compression ignition engines are in development. One of them relies on reducing the heat losses of the engine during the combustion process as well as to devise injection strategies that reduce soot formation. Therefore, it is necessary a better comprehension about the turbulent kinetic energy (TKE) distribution inside the cylinder and how it is affected by the interaction between air flow motion and fuel spray. Furthermore, new diesel engines are characterized by massive decrease of NOx emissions. Therefore, considering the well-known NOx-soot trade-off, it is necessary a better comprehension and overall quantification of soot formation and how the different injection strategies can impact it.

Dual-fuel combustion engines have shown the potential to extend the operating range of Homogeneous Charge Compression Ignition (HCCI) by using several combustion modes, e.g. Reactivity Controlled Compression Ignition (RCCI) at low/medium load, and Partially Premixed Compression (PPC) at high load. In order to optimize the combustion mode operation, the respective sensitivity to the control inputs must be addressed. To this end, in this work the extremum seeking algorithm has been investigated. By definition, this technique allows to detect the control input authority over the system by perturbing its value by a known periodic signal. By analyzing the system response and calculating its gradient, the control input can be adjusted to reach optimal operation. This method has been applied to a dual-fuel engine under fully, highly and partially premixed conditions where the feedback information was provided by in-cylinder pressure and NOx sensors.

Focusing on the dual-mode dual-fuel (DMDF) combustion concept, a combined optimization of the piston bowl geometry with the fuel injection strategy was conducted at low, mid, and high loads. By coupling the KIVA-3V code with the enhanced genetic algorithm (GA), a total of 14 parameters including the piston bowl geometric parameters and the injection parameters were optimized with the objective of meeting Euro VI regulations while improving the fuel efficiency. The optimal piston bowl shape coupled with the corresponding injection strategy was summarized and integrated at various loads. Furthermore, the effects of the key geometric parameters were investigated in terms of organizing the in-cylinder flow, influencing the energy distribution, and affecting the emissions. The results indicate that the behavior of the DMDF combustion mode is further enhanced in the aspects of improving the fuel economy and controlling the emissions after the bowl geometry optimization.

A computational, three-dimensional approach to investigate the behavior of diesel soot particles in the micro-channels of wall-flow Diesel Particulate Filters is presented. The KIVA3V CFD code, already extended to solve the 2D conservation equations for porous media materials [1], has been enhanced to solve in 2-D and 3-D the governing equations for reacting and compressible flows through porous media in non axes-symmetric geometries. With respect to previous work [1], a different mathematical approach has been followed in the implementation of the numerical solver for porous media, in order to achieve a faster convergency as source terms were added to the governing equations. The Darcy pressure drop has been included in the Navier-Stokes equations and the energy equation has been extended to account for the thermal exchange between the gas flow and the porous wall.

3-D Computational Fluid Dynamics (CFD) simulations have been performed to study particulate formation in a Spark-Ignition (SI) engine under premixed conditions. A semi-detailed soot model and a chemical kinetic model, including poly-aromatic hydrocarbon (PAH) formation, were coupled with a spark ignition model and the G equation flame propagation model for SI engine simulations and for predictions of soot mass and particulate number density. The simulation results for in-cylinder pressure and particle size distribution (PSDs) are compared to available experimental studies of equivalence ratio effects during premixed operation. Good predictions are observed with regard to cylinder pressure, combustion phasing and engine load. Qualitative agreements of in-cylinder particle distributions were also obtained and the results are helpful to understand particulate formation processes.

Selective Catalytic Reduction stands for an effective methodology for the reduction of NOx emissions from Diesel engines and meeting current and future EURO standards. For it, the injection of Urea Water Solution (UWS) plays a major role in the process of reducing the NOx emissions. A LES approach for turbulence modelling allows to have a description of the physics which is a very useful tool in situations where experiments cannot be performed. The main objective of this study is to predict characteristics of the flow of interest inside the injector as well as spray morphology in the near field of the spray. For it, the nozzle geometry has been reconstructed from X-Ray tomography data, and an Eulerian-Eulerian approach commonly known as Mixture Model has been applied to study the liquid phase of the UWS with a LES approach for turbulence modeling. The injector unit is subjected to typical low-pressure working conditions.