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The recent development of biofuel production worldwide is closely linked to GHG savings objectives and to regional agricultural policies. Many existing studies intend to evaluate the net non renewable energy and GHG savings associated to the various biofuel production pathways. However, there is no consensus on the results of those studies. The main explanations of variations among the results are the following: energy consumption and GHG emissions of the reference fossil pathway, data used for the representation of farming processes and biofuel production processes, accounting for carbon storage in agricultural soils, reference use of the land, choice of an allocation method in case of coproduction. There is a strong drive in the European Union for a certification on the sustainability of biofuel pathways.

In former high compression ratio Diesel engines a single injection was used to introduce the fuel into the combustion chamber. With actual direct injection engines which exhibit a compression ratio between 17:1 and 18:1 single or multiple early injections called “pilot injections” are also added in order to reduce the combustion noise. For after-treatment reasons a late injection during the expansion stroke named “post injection” may also be used in some operating conditions. Investigations have been conducted on lower compression ratio Diesel engine and in high EGR rate operating conditions to evaluate the benefits of multiple injection strategies to improve the trade off between engine emissions, noise and fuel economy.

Detailed chemistry and turbulence-chemistry interaction need to be properly taken into account for a realistic combustion simulation of IC engines where advanced combustion modes, multiple injections and stratified combustion involve a wide range of combustion regimes and require a proper description of several phenomena such as auto-ignition, flame stabilization, diffusive combustion and lean premixed flame propagation. To this end, different approaches are applied and the most used ones rely on the well-stirred reactor or flamelet assumption. However, well-mixed models do not describe correctly flame structure, while unsteady flamelet models cannot easily predict premixed flame propagation and triple flames. A possible alternative for them is represented by transported probability density functions (PDF) methods, which have been applied widely and effectively for modeling turbulent reacting flows under a wide range of combustion regimes.

The reduction of NOx emissions required by the future Euro 6 standards leads engine manufacturers to develop Diesel Homogeneous Charge Compression Ignition (HCCI) combustion processes. Because this concept allows reducing both NOx and particulates simultaneously, it appears as a promising way to meet the next environmental challenges. Unfortunately, HCCI combustion often increases CO and HC emissions. Conventional oxidation catalyst technologies, currently used for Euro 4 vehicles, may not be able to convert these emissions because of the saturation of active catalytic sites. As a result, such increased CO and HC emissions have to be reduced under standard levels using innovative catalysts or emergent technologies. The work reported in this paper has been conducted within the framework of the PAGODE project (PSA, IFP, Chalmers University, APTL, CRF, Johnson Matthey and Supelec) and financed by the European Commission.

The mixing and combustion processes of short double Diesel injections are investigated by optical diagnostics. A single hole Common Rail Diesel injector allowing high injection pressure up to 120MPa is used. The spray is observed in a high pressure, high temperature cell that reproduces the thermodynamic conditions which exist in the combustion chamber of a Diesel engine during injection. Three configurations are studied: a single short injection serving as a reference case and two double short injections with short and long dwell time (time between the injections). Several optical diagnostics were performed successively. The mixing process is studied by normalized Laser Induced Exciplex Fluorescence giving access to the vapor fuel concentration fields. In addition, the flow fields both inside and outside the jets are characterized by Particle Imaging Velocimetry.

The air entrainment of multi-hole diesel injection is investigated by high speed Particle Image Velocimetry (PIV) using a multi-hole common rail injector with an injection pressure of 100 MPa. The sprays are observed in a high pressure, high temperature cell that reproduces the thermodynamic conditions which exist in the combustion chamber of a diesel engine during injection. Typical ambient temperature of 800K and ambient density of 25 kg/m3 are chosen. The air entrainment is studied with the PIV technique, giving access to the velocity fields in the surrounding air and/or in the interior of two neighboring jets. High acquisition rate of 5000 Hz, corresponding to 200 μs between two consecutive image pairs is obtained by a high-speed camera coupled with a high-speed Nd:YLF laser. The effect of neighboring jets interaction is studied by comparing four injectors with different numbers of holes (4, 6, 8 and 12) with similar static mass flow rate per hole.

The reduction of particulate emissions from Diesel engines is a key issue to meet future emission standards. Particulate traps represent an attractive solution to the problem of this source of pollution. However, they have the disadvantage of requiring periodic and safe regeneration to release exhaust back pressure and to recover filtration efficiency. Natural regeneration of the particulate filter may occur. Nevertheless, with light-duty vehicles and their low level of exhaust gas temperature, it may be necessary to facilitate or force the regeneration. The objective of this work is to give an overview of the possibilities offered by the engine management system to increase significantly exhaust gas temperatures. Thus, different engine tunes, through injection timing, boost pressure or EGR rate, may be sufficient to ensure safe regeneration of the trap.

Detailed chemistry represents a fundamental pre-requisite for a realistic simulation of combustion process in Diesel engines to properly reproduce ignition delay and flame structure (lift-off and soot precursors) in a wide range of operating conditions. In this work, the authors developed reduced mechanisms for n-dodecane starting from the comprehensive kinetic mechanism developed at Politecnico di Milano, well validated and tested in a wide range of operating conditions [1]. An algorithm combining Sensitivity and Flux Analysis was employed for the present skeletal reduction. The size of the mechanisms can be limited to less than 100 species and incorporates the most important details of low-temperature kinetics for a proper prediction of the ignition delay. Furthermore, the high-temperature chemistry is also properly described both in terms of reactivity and species formation, including unsaturated compounds such as acetylene, whose concentration controls soot formation.

Future human exploration roadmaps involve the development of temporary or permanent outposts on Moon and Mars. The capability of providing astronauts with proper conditions for living and working in extraterrestrial environments is therefore a key issue for the sustainability of those roadmaps, and closed-loop Environment Control and Life Support Systems (ECLSSs) and bio-regenerative plants represent the necessary evolution of current technologies for complying with the challenging requirements imposed. This paper presents the architectural design of a terrestrial plant to be exploited to test and validate air and water management technologies for a biological life support system in a closed environment. The plant includes a crew area and a plant growth area. These two spaces can be considered as either a unique volume or two separated environments with reduced contact, e.g. for plant harvesting or other up-keeping activities.

Modeling combustion of transportation fuels remains a difficult task due to the extremely large number of species constituting commercial gasoline and diesel. However, for this purpose, multi-component surrogate fuel models with a reduced number of key species and dedicated reaction subsets can be used to reproduce the physical and chemical traits of diesel and gasoline, also allowing to perform CFD calculations. Recently, a detailed surrogate fuel kinetic model, named C3 mechanism, was developed by merging high-fidelity sub-mechanisms from different research groups, i.e. C0-C4 chemistry (NUI Galway), linear C6-C7 and iso-octane chemistry (Lawrence Livermore National Laboratory), and monocyclic aromatic hydrocarbons (MAHs) and polycyclic aromatic hydrocarbons (PAHs) (ITV-RWTH Aachen and CRECK modelling Lab-Politecnico di Milano).

In order to asses the durability of DPF, a study has been performed in order to study the evolution of several taxis (Peugeot 607) and the performance of this after-treatment systems over 80,000 km mileage in hard urban driving conditions, which corresponds to the recommended mileage before the first DPF maintenance (this periodicity is applied on the first generation of DPF technology launched in 2000). More specifically, the following evaluations are being performed at regular intervals (around 20 000 km): Regulated gaseous pollutant emissions on NEDC cycle (New European Driving Cycle) Particulate emissions, by mass measurement on NEDC but also by particle number and size measurement with SMPS (Scanning Mobility Particle Sizer) technique on NEDC and on unconventional steady-state running points.

The use of Diesel engines has strongly increased during the last years and now represents 30% of the sales in Europe and up to 50% of the number of cars in circulation for some countries. This success is linked not only to the economical aspect of the use of such vehicles, but also to the recent technological improvements of these engines. The new technical solutions (high pressure direct injection, turbocharging…) have indeed allowed the increase of these engine performances while decreasing their fuel consumption, pollutant emissions and noise level. From an environmental point of view, Diesel engines are nevertheless penalized by their particulate and NOx emissions. The study and the treatment of the particulate, highly criticized for their potential impact on health, are the subject of numerous works of characterization and developments. PSA Peugeot-Citroën has recently launched its particulate filter technology on several types of vehicles.

Oxygen enriched air (EA) is a well known industrial mixture in which the content of oxygen is higher respect the atmospheric one, in the range 22-35%. Oxygen EA can be obtained by desorption from water, taking advantage of the higher oxygen solubility in water compared to the nitrogen one, since the Henry constants of this two gases are different. The production of EA by this new approach was already studied by experimental runs and theoretical considerations. New results using salt water are reported. EA promoted combustion is considered as one of the most interesting technologies to improve the performance in diesel engines and to simultaneously control and reduce pollution. This paper explores, by means of 3-dimensional computational fluid dynamics simulations, the effects of EA on the performance and exhaust emissions of a high-speed direct-injection diesel engine.

The sustainability of Martian outposts development is strongly based on the capability of achieving a high level of autonomy both in terms of operations management and of resources availability. In situ production of consumables is a key point to allow humans to work and live on Mars avoiding or limiting the need for re-supplies of materials from Earth. Required consumables can be produced in situ exploiting the locally available resources, but also by means of green-houses and waste recycle systems. Dedicated robotic missions for in situ demonstration of this type of technologies are a fundamental step of the Martian In Situ Resources Utilization (ISRU) development roadmap. This paper is focused on the extraction of oxygen and fuels (e.g. methane) from the Martian atmosphere, and presents a feasibility study for a small technological demonstration plant.

This paper presents an overview of the results on light duty vehicles collected in the “PARTICULATES” project which aimed at the characterization of exhaust particle emissions from road vehicles. A novel measurement protocol, developed to promote the production of nucleation mode particles over transient cycles, has been successfully employed in several labs to evaluate a wide range of particulate properties with a range of light duty vehicles and fuels. The measured properties included particle number, with focus separately on nucleation mode and solid particles, particle active surface and total mass. The vehicle sample consisted of 22 cars, including conventional diesels, particle filter equipped diesels, port fuel injected and direct injection spark ignition cars. Four diesel and three gasoline fuels were used, mainly differentiated with respect to their sulfur content which was ranging from 300 to below 10 mg/kg.

Diversifying energy resources and reducing greenhouse gas emissions are key priorities in the forthcoming years for the automotive industry. Currently, among the different solutions, sustainable biofuels are considered as one of the most attractive answer to these issues. This paper deals with the vehicle application of an innovative diesel fuel formulation using Ethanol to tackle these future challenges. The main goal is to better understand the impact of using biofuel blends on engine behavior, reliability and pollutants emissions. This alternative oxygenated fuel reduces dramatically particulate matter (PM) emissions; this paves the way to improve the NOx/PM/CO₂ trade-off. Another major interest is to avoid adding a particulate filter in the exhaust line and to avoid modifying powertrain and vehicle hardware and therefore to minimize the overall cost to fulfill upcoming emission regulations.

The combination of air charging and downsizing is known to be an efficient solution to reduce CO2 emissions of modern gasoline engines. The decrease of the cubic capacity and the increase of the specific performance help to reduce the fuel consumption by limiting pumping and friction losses and even the losses of energy by heat transfer. Investigations have been conducted on a highly downsized SI engine to confirm if a strong decrease of the displacement (50 %) was still interesting regarding the fuel consumption reduction and if other ways were possible to improve further more its efficiency. The first aim of our work was to identify the optimal design (bore, stroke, displacement, …) that could maximize the consumption reduction potential at part load but also improve the engine's behaviour at very high load (up to 3.0 MPa IMEP from 1000 rpm). In order to do that, four engine configurations with different strokes and bores have been tested and compared.

Partially premixed compression ignition combustion is one of the low temperature combustion techniques which is being actively investigated. This approach provides a significant reduction of both soot and NOx emissions. Comparing to the homogeneous charge compression ignition mode, PPCI combustion provides better control on ignition timing and noise reduction through air-fuel mixture stratification which lowers heat release rate compared to other advanced combustion modes. In this work, CFD simulations were conducted for a low and a high air-fuel mixture stratification cases on a light-duty optical engine operating in PPCI mode. Such conditions for PRF70 as fuel were experimentally achieved by injection timing and spray targeting at similar thermodynamic conditions.

A methodology has been developed to determine, for every cycle on which significant knock is detected, the area in which self-ignition occurs. This methodology is based on the exploitation by a dedicated algorithm of a minimum of 4 simultaneous combustion chamber pressure measurements. The algorithm has been first tested on the results of engine knocking simulation, then applied with success on a single-cylinder engine equipped with classical pressure transducers and with an instrumented cylinder head gasket developed for this application. The results obtained with these two kinds of transducers on several engine configurations and tunings are similar. If the timing and intensity of knock events depend on all engine parameters, its location is especially sensitive to such design parameters as fluid motion into the combustion chamber and spark plug position.

A computational, three-dimensional approach to investigate the behavior of diesel soot particles in the micro-channels of wall-flow Diesel Particulate Filters is presented. The KIVA3V CFD code, already extended to solve the 2D conservation equations for porous media materials [1], has been enhanced to solve in 2-D and 3-D the governing equations for reacting and compressible flows through porous media in non axes-symmetric geometries. With respect to previous work [1], a different mathematical approach has been followed in the implementation of the numerical solver for porous media, in order to achieve a faster convergency as source terms were added to the governing equations. The Darcy pressure drop has been included in the Navier-Stokes equations and the energy equation has been extended to account for the thermal exchange between the gas flow and the porous wall.