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A 2.5L, V-6, port-injected, spark-ignition engine was modified for optical access by separating the head from the block and installing a Bowditch extended piston with a fused-silica top and a fused-silica liner in one of the cylinders. Two heads were employed in the study. One produced swirl and permitted modulation of the swirl level, and another produced a tumbling flow in the cylinder. Planar laser-induced exciplex fluorescence, which allows the simultaneous, but separate, imaging of liquid and vapor fuel, was extended to capture components of different volatilities in a model fuel designed to simulate the distillation curve of a typical gasoline. The exciplex fluorescence technique was calibrated in a separate cell where careful control of mixture composition, temperature and pressure was possible. The results show that large-scale motion induced during intake is critical for good mixing during the intake and compression strokes.