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The effect of compression ratio on sensitivity to changes in start of injection and air-fuel ratio has been investigated on a single-cylinder DI diesel engine at fixed low and medium speeds and loads. Compression ratio was set to 17.9:1 or 13.7:1 by using pistons with different bowl sizes. Injection timing and air-to-fuel ratio were swept around a nominal map point at which gross IMEP and NOx values were matched for the two compression ratios. It was found that CO, HC and ISFC were higher at low compression ratio, but the soot/NOx trade-off improved and this could be exploited to reduce the fuel economy penalty. Sensitivity to inputs is generally similar, but high compression ratio tended to have steeper response gradients. Reducing compression ratio to 13.7 gave rise to a marked degradation of performance at light load, producing high CO emissions and a fall in combustion efficiency. This could be eased by reducing rail pressure, but the advantage in smoke emission was lost.

The increased severity and prevalence of insoluble deposits formed on fuel injectors in gasoline direct injection (GDI) engines precipitates negative environmental, economic and healthcare impacts. A necessary step in mitigating deposits is to unravel the molecular compositions of these complex layered materials. But very little molecular data has been acquired. Mass spectrometry shows promise but most techniques require the use of solvents, making them unsuited for analyzing insoluble deposits. Here, we apply the high mass-resolving power and in-situ analysis capabilities of 3D OrbitrapTM secondary ion mass spectrometry (3D OrbiSIMS) to characterize deposits formed on the external tip and internal needle from a GDI injector. This is the first application of the technique to study internal GDI deposits. Polycyclic aromatic hydrocarbons (PAHs) are present up to higher maximum masses in the external deposit.

A Ford 2.4-liter 115PS light-duty diesel engine was modified to allow solenoid control of the oil feed to the piston cooling jets, enabling these to be switched on or off on demand. The influence of the jets on piston temperatures, engine thermal state, gaseous emissions and fuel economy has been investigated. With the jets switched off, piston temperatures were measured to be between 23 and 88°C higher. Across a range of speed-load points, switching off the jets increased engine-out emissions of NOx typically by 3%, and reduced emissions of CO by 5-10%. Changes in HC were of the same order and were reductions at most conditions. Fuel consumption increased at low-speed, high-load conditions and decreased at high-speed, low-load conditions. Applying the results to the NEDC drive cycle suggests active on/off control of the jets could reduce engine-out emissions of CO by 6%, at the expense of a 1% increase in NOx, compared to the case when the jets are on continuously.

Soot formation and distribution inside the cylinder of a light-duty direct injection diesel engine, have been predicted using Kiva-3v CFD software. Pathlines of soot particles traced from specific in-cylinder locations and crank angle instants have been explored using the results for cylinder charge motion predicted by the Kiva-3v code. Pathlines are determined assuming soot particles are massless and follow charge motion. Coagulation and agglomeration have not been taken into account. High rates of soot formation dominate during and just after the injection. Oxidation becomes dominant after the injection has terminated and throughout the power stroke. Computed soot pathlines show that soot particles formed just below the fuel spray axis during the early injection period are more likely to travel to the cylinder wall boundary layer. Soot particles above the fuel spray have lesser tendency to be conveyed to the cylinder wall.

In a context of global warming and our needs to reduce CO2 emissions, building envelopes will play an important role. A new imperative has been put forth to architects and engineers to develop innovative materials, components and systems, in order to make building envelopes adaptive and responsive to variable and extreme climate conditions. Envelopes serve multiple functions, from shielding the interior environment to collecting, storing and generating energy. Perhaps a more recent concern of terrestrial habitats is permeability and leakages within the building envelope. Such air tight and concealed envelopes with zero particle exchange are a necessity and already exist in regard to space capsules and habitats. This paper attempts to acknowledge existing and visionary envelope concepts and their functioning in conjunction with maintaining a favourable interior environment. It introduces several criteria and requirements of advanced façades along with interior pressurization control.

Characterization of soot nanoparticle morphology can be used to develop understanding of nanoparticle interaction with engine lubricant oil and its additives. It can be used to help direct modelling of soot-induced thickening, and in a more general sense for combatting reductions in engine efficiency that occur with soot-laden oils. Traditional 2D transmission electron microscopy (TEM) characterization possesses several important shortcomings related to accuracy that have prompted development of an alternative 3D characterization technique utilizing electron tomography, known as 3D-TEM. This work details progress made towards facilitating semi-automated image acquisition and processing for location of structures of interest on the TEM grid. Samples were taken from a four cylinder 1.4 L gasoline turbocharged direct injection (GTDI) engine operated in typically extra-urban driving conditions for 20,284 km, with automatic cylinder deactivation enabled.

The size and morphology of soot particles and agglomerates extracted from lubricating oil drawn from the sump of a diesel engine have been investigated and compared using Transmission Electron Microscopy (TEM) and Nanoparticle Tracking Analysis (NTA). Samples were prepared for electron microscopy imaging by both centrifugation and solvent extraction to investigate the impact of these procedures on the morphological characteristics, such as skeleton length and width and circularity, of the obtained soot. It was shown that centrifugation increases the extent of agglomeration within the sample, with 15% of the agglomerates above 200 nm compared to only 11% in the solvent extracted soot. It was also observed that the width of centrifugation extracted soot was typically 10 nm to 20 nm larger than that of solvent extracted soot, suggesting that centrifugation forces the individual agglomerate chains together.

The focus of this study is to analyse changes in soot particle size along the predicted pathlines as they pass through different in-cylinder combustion histories obtained from Kiva-3v CFD simulation with a series of Matlab routines. 3500 locations representing soot particles were selected inside the cylinder at 8° CA ATDC as soot was formed in high concentration at this CA. The dominant soot particle size was recorded within the size range of 20-50 nm at earlier CA and shifted to 10-20 nm after 20° CA ATDC. Soot particle quantities reduce sharply until 20° CA ATDC after which they remain steady at around 1500 particles. Soot particles inside the bowl region tend to stick to the bowl walls and those remaining in the bowl experience an increase in size. Soot particles that move to the upper bowl and squish regions were observed to experience a decrease in size.

Engine research has increasingly focused on emission of sub 23 nm particulates in recent years. Likewise, current legislative efforts are being made for particulate number (PN) emission limits to include this previously omitted size range. In Europe, PN measurement equipment and procedures for regulatory purposes are defined by the particle measurement programme (PMP). Latest regulation drafts for sub 23 nm measurements specify counting efficiencies with a 65% cut-off size at 10 nm (d65) and a minimum of 90% above 15 nm (d90). Even though alternative instruments, such as differential mobility spectrometers (DMS), are widely used in laboratory environments, the interpretation of their sub 23 nm measurements has not yet been widely discussed. For this study, particulate emissions of a 1.0L gasoline direct injection (GDI) engine have been measured with a DMS system for low to medium speeds with two load steps.

The influence of size and concentration of carbon nanoparticle on the viscosity of an SAE 5W-30 lubricant oil has been investigated experimentally. Data were collected for oil samples drawn from sump of light duty automotive diesel engines. The average size of soot particles in the used oil samples was in the range of 180-320nm with concentrations ranging from 0 to 2 percentage by weight (wt. %.). A Brookfield DV-II Pro rotary viscometer was used to measure dynamic viscosity at low shear rates and temperatures of 40°C and 90°C. Nanoparticle concentration and particle size distribution were evaluated using Thermo-Gravimetric Analysis (TGA) and Dynamic Light Scattering (DLS) respectively. The viscosity of suspensions of graphite powder in lubricant oil was also investigated for concentrations ranging from 0 to 2 wt. %. The results show that dynamic viscosity increases with increasing soot content and decreasing temperature.

The nature of internal diesel injector deposits (IDID) continues to be of importance to the industry, with field problems such as injector sticking, loss of power, increased emissions and fuel consumption being found. The deposits have their origins in the changes in emission regulations that have seen increasingly severe conditions experienced by fuels because of high temperatures and high pressures of modern common rail systems and the introduction of low sulphur fuels. Furthermore, the effect of these deposits is amplified by the tight engineering tolerances of the moving parts of such systems. The nature and thus understanding of such deposits is necessary to both minimising their formation and the development of effective diesel deposit control additives (DCA).

Fuel losses to the crankcase, fuel/oil interactions, and fuel return as unburned hydrocarbons in the breather flow have been investigated. Hydrocarbons in the breather flow have been measured during motored and firing engine operation over a range of temperatures. Fuel desorption from the sump oil accounts for a small proportion of this. The major source is hydrocarbons transported past the piston with blowby. After a cold start, around 85% of these are retained in oil films below the ring pack. The recirculation of oil from the films to the sump contributes to bulk oil dilution. This appears to be the prime mechanism by which fuel is lost to oil dilution during cold operation. The mechanism becomes less effective as engine warm-up progresses. At fully-warm oil temperatures (∼100°C), only about 5% are removed from the blowby.

Environmental authorities such as EPA, VCA have enforced stringent emissions legislation governing air pollutants released into the atmosphere. Of particular interest is the challenge introduced by the limit on particulate number (PN) counting (#/km) and real driving emissions (RDE) testing; with new emissions legislation being shortly introduced for the gasoline direct injection (GDI) engines, gasoline particulate filters (GPF) are considered the most immediate solution. While engine calibration and testing over the Worldwide harmonized Light vehicles Test Cycle (WLTC) allow for the limits to be met, real driving emission and cold start constitute a real challenge. The present work focuses on an experimental durability study on road under real world driving conditions. Two sets of experiments were carried out. The first study analyzed a gasoline particulate filter (GPF) (2.4 liter, diameter 5.2” round) installed in the underfloor (UF) position and driven up to 200k km.

The work examined the practicality of converting a modern production 6 cylinder 7.7 litre heavy-duty diesel engine for flex dual-fuel operation with ammonia as the main fuel. A small amount of diesel fuel (pilot) was used as an ignition source. Ammonia was injected into the intake ports during the intake stroke, while the original direct fuel injection equipment was retained and used for pilot diesel injection. A bespoke engine control unit was used to control the injection of both fuels and all other engine parameters. The aim was to provide a cost-effective retrofitting technology for existing heavy-duty engines, to enable eco-friendly operation with minimal carbon emissions. The tests were carried out at a baseline speed of 600 rpm for the load range of the engine (10-90%), with minimum pilot diesel quantity and as high as 90% substitution ratio of ammonia for diesel fuel.

DISI engine emissions and fuel economy are strongly dependent upon fuel injection and spark timings, particularly when the engine is operating in stratified charge mode. Experimental studies of the effects of injection and spark timings and the interaction between these are described. The sensitivity of HC and NOx emissions to timings during stratified charge operation, the comparison of performance under stratified and homogeneous charge modes of operation and the rationale for mode switch point settings are investigated. The high sensitivity of emissions to injection and spark timing settings gives rise to potential robustness issues. These are described.

Experimental studies of fuel utilisation during the early stages of engine warm-up after cold-starts are reported. The investigation has been carried out on a 1.81, 4 cylinder spark-ignition engine with port electronic fuel injection. The relationship between fuel supplied and fuel accounted for by the analysis of exhaust gas composition shows that a significant mass of fuel supplied is temporarily stored or permanently lost. An interpretation of data is made which allows time-dependent variations of these to be separately resolved and estimates of fuel quantities made. The data covers a range of cold-start conditions down to -5°C at which, on a per cylinder basis, fuel stored peaks typically at around 0.75g and a total of 1g is returned over 100 seconds of engine running. Fuel lost past the piston typically accounts for 2g over 200 to 300 seconds of running.

Morphology plays an important role in determining behaviour and impact of soot nanoparticles, including effect on human health, atmospheric optical properties, contribution to engine wear, and role in marine ecology. However, its nanoscopic size has limited the ability to directly measure useful morphological parameters such as surface area and effective volume. Recently, 3D morphology characterization of soot nanoparticles via electron tomography has been the subject of several introductory studies. So-called ‘3D-TEM’ has been posited as an improvement over traditional 2D-TEM characterization due to the elimination of the error-inducing information gap that exists between 3-dimensional soot structures and 2-dimensional TEM projections. Little follow-up work has been performed due to difficulties with developing methodologies into robust high-throughput techniques.

The determination of size distribution of soot particles and agglomerates in oil samples using a Nanosight LM14 to perform Nanoparticle Tracking Analysis (NTA) is described. This is the first application of the technique to sizing soot-in-oil agglomerates and offers the advantages of relatively high rates of sample analysis and low cost compared to Transmission Electron Microscopy (TEM). Lubricating oil samples were drawn from the sump of automotive diesel engines run under a mix of light duty operating conditions. The oil samples were diluted with heptane before analysing. Results from NTA analysis were compared with the outputs of a more conventional analysis based on Dynamic Light Scattering (DLS). This work shows that soot-in-oil exists as agglomerates with average size of 115 nm. This is also in good agreement with TEM analysis carried out in a previous work. NTA can measure soot particles in polydisperse oil solutions and report the size distribution of soot-in-oil aggregates.

Optimising an engine specification to improve cold start performance has been investigated. Taguchi methods were used to define a test programme to assess the effect of seven build factors. Experiments were conducted to measure mixture ratio at the spark plug location after a short period of engine cranking at test conditions covering ± 15°C and three fuel-mass-supplied values. The analysis of the results identified build modifications which improved start quality and reduced HC and CO emissions substantially compared to a reference, base-line build. Injector design and location, and inlet valve timing were found to have most influence on robustness to uncontrolled variations in mixture preparation during starts.