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In one-dimensional engine simulation programs the simulation of engine performance is mostly done by parameter fitting in order to match simulations with experimental data. The extensive fitting procedure is especially needed for emissions formation - CO, HC, NO, soot - simulations. An alternative to this approach is, to calculate the emissions based on detailed kinetic models. This however demands that the in-cylinder combustion-flow interaction can be modeled accurately, and that the CPU time needed for the model is still acceptable. PDF based stochastic reactor models offer one possible solution. They usually introduce only one (time dependent) parameter - the mixing time - to model the influence of flow on the chemistry. They offer the prediction of the heat release, together with all emission formation, if the optimum mixing time is given.

The California LEV1 II program will be introduced in the year 2003 and requires a further reduction of the exhaust emissions of passenger cars. The cold start emissions represent the main part of the total emissions of the FTP2-Cycle. Cold start emissions can be efficiently reduced by injecting secondary air (SA) in the exhaust port making compliance with the most stringent standards possible. The thermochemical conditions (mixing rate and temperature of secondary air and exhaust gas, exhaust gas composition, etc) prevailing in the exhaust system are described in this paper. This provides knowledge of the conditions for auto ignition of the mixture within the exhaust manifold. The thus established exothermal reaction (exhaust gas post-combustion) results in a shorter time to light-off temperature of the catalyst. The mechanisms of this combustion are studied at different engine idle conditions.

Since the mechanisms leading to cyclic combustion variabilities in direct injection gasoline engines are still poorly understood, advanced computational studies are necessary to be able to predict, analyze and optimize the complete engine process from aerodynamics to mixing, ignition, combustion and heat transfer. In this work the Scale-Adaptive Simulation (SAS) turbulence model is used in combination with a parameterized lagrangian spray model for the purpose of predicting transient in-cylinder cold flow, injection and mixture formation in a gasoline engine. An existing CFD model based on FLUENT v15.0 [1] has been extended with a spray description using the FLUENT Discrete Phase Model (DPM). This article will first discuss the validation of the in-cylinder cold flow model using experimental data measured within an optically accessible engine by High Speed Particle Image Velocimetry (HS-PIV).

Synthetic fuels are expected to play an important role for future mobility, because they can be introduced seamlessly alongside conventional fuels without the need for new infrastructure. Thus, understanding the interaction of GTL fuels with modern engines, and aftertreatment systems, is important. The current study investigates potential benefits of GTL fuel in respect of diesel particulate filters (DPF). Experiments were conducted on a Euro 4 TDI engine, comparing the DPF response to two different fuels, normal diesel and GTL fuel. The investigation focused on the accumulation and regeneration behavior of the DPF. Results indicated that GTL fuel reduced particulate formation to such an extent that the regeneration cycle was significantly elongated, by ∼70% compared with conventional diesel. Thus, the engine could operate for this increased time before the DPF reached maximum load and regeneration was needed.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.

The interaction of three bio-lubricant base oil candidates with seventeen combinations of surface treatment was studied, comparing wear scar volumes and coefficient of friction results. Substrates were initially ground, then a combination of superfinished, Dymon-iC™ DLC, an impact technique of ultra-fine shot blasting method doped with Tin and Molybdenum Disulfide, a calcium based chemical dip containing calcium sulfate and nano fullerene, were used. DLC is well reported to reduce friction. Some reports suggest wear in coated contacts is independent of the type of lubricant used, whilst others report that bio-lubricants offer reduced friction and wear in combination with DLC. Shot blasting can also reduce wear and friction, due to the surface dimples acting as lubricant reservoirs, making hydrodynamic lubrication more likely.

Crank-angle resolved, gas temperatures are determined in the combustion chamber of a Volkswagen (VW) standard-production, port-injected SI engine. During idle, two different methods are applied: (1) a direct spectroscopic emission-absorption technique at a resonance line of potassium, seeded to the air stream to generate sufficient spectral absorptance (‘colouring’ technique), and (2) a more standard, indirect method in which temperatures are derived from pressure recordings using a two-zone thermodynamic model. Combustion temperatures obtained during idle with both the spectroscopic (1) and ‘two-zone’ (2) methods are in good agreement. In addition, the spectroscopic technique is extended to transient operating conditions where the ‘two-zone’ method is not applicable. Combustion temperatures measured during cold-start and abrupt load alteration are in good agreement with former investigations.

A photoelastic stress analysis technique has been used to determine the contact stresses in an automotive chain drive tensioner. The tensioner in normal operation is subject to high magnitude, short duration impact stresses. These stresses are known to cause surface damage, wear, and surface pitting. In order to adequately design the drive system layout, a means for stress quantification is needed. A replica tensioner was made from epoxy resin and tested in a variety of configurations. A simple model has been created to relate the chain link load to the resulting tensioner sub-surface stress field. This model has been used to correlate the observed and predicted location of isochromatic fringes, and hence to evaluate the chain link load from the photoelastic fringe pattern. A series of static load tests were performed to calibrate the apparatus. The tensioner specimen was then assembled in a chain drive test facility.

The regulations for mobile applications will become stricter in Euro 6 and further emission levels and require the use of active aftertreatment methods for NOX and particulate matter. SCR and LNT have been both used commercially for mobile NOX removal. An alternative system is based on the combination of these two technologies. Developments of catalysts and whole systems as well as final vehicle demonstrations are discussed in this study. The small and full-size catalyst development experiments resulted in PtRh/LNT with optimized noble metal loadings and Cu-SCR catalyst having a high durability and ammonia adsorption capacity. For this study, an aftertreatment system consisting of LNT plus exhaust bypass, passive SCR and engine independent reductant supply by on-board exhaust fuel reforming was developed and investigated. The concept definition considers NOX conversion, CO2 drawback and system complexity.

A novel ultrasonic viscometer for in-situ applications in engine components is presented. The viscosity measurement is performed by shearing the solid-oil contact interface by means of shear ultrasonic waves. Previous approaches to ultrasonically measure the viscosity suffer from poor accuracy owing to the acoustic miss-match between metal component and lubricant [1]. The method described overcomes this limitation by placing an intermediate matching layer between the metal and lubricant. Results are in excellent agreement with the ones obtained with the conventional viscometers when testing Newtonian fluids. This study also highlights that when complex mixtures are tested the viscosity measurement is frequency dependent. At high ultrasonic frequencies, e.g. 10 MHz, it is possible to isolate the viscosity of the base, while to obtain the viscosity of the mixture it is necessary to choose a lower operative frequency, e.g. 100 kHz, to match the fluid particle relaxation time.

Meeting current exhaust emission standards requires rapid catalyst light-off. Closed-coupled catalysts are commonly used to reduce light-off time by minimizing exhaust heat loss between the engine and catalyst. However, this exhaust gas system design leads to a coupling of catalyst heating and engine operation. An engine-independent exhaust gas aftertreatment can be realized by combining a burner heated catalyst system (BHC) with an underfloor catalyst located far away from the engine. This paper describes some basic characteristics of such a BHC system and the results of fitting this system into a Volkswagen Touareg where a single catalyst was located about 1.8 m downstream of the engine. Nevertheless, it was possible to reach about 50% of the current European emission standard EU 4 without additional fuel consumption caused by the BHC system.

Within the European research programme IDEA (Integrated Diesel European Action), detailed experimental and theoretical studies of the fundamental phenomena of the Diesel engine like flow, injection, mixture formation, auto-ignition, combustion and pollutant formation were carried out to improve knowledge and to set up models for a simulation code. Because this basic research of the Diesel combustion process is very complex and cost intensive, it was carried out jointly by the JRC (Joint Research Committee), an association of European car manufacturers (Fiat, Peugeot SA, Renault, Volvo and Volkswagen). The activities were also subsidized by the Commission of the European Communities and the Swedish National Board of Technical Development. The results of the research work will support the design of even more efficient engines and the further reduction of soot and NOx emissions and will also enable the companies to reduce time and cost in developing new engines.

One dimensional Spontaneous Raman Scattering measurements (RS) have been performed in a spray (standard gasoline, one-component and multi-component model fuels) which was operated in a high-temperature, high-pressure chamber, so that realistic engine conditions have been simulated. The present work investigates under what conditions 1D-RS can be employed for fuel/air-ratio measurements in realistic DI gasoline sprays. The distance from the spray axis has been determined, til that, coming from the outside, quantitative Raman measurement are possible. The equivalence ratio has been quantified for the one component fuel close to the spray. It turns out that the measurement error depends strongly on the type of fuel. These problems are caused by the PAH (polycyclic aromatic hydrocarbon) content of the fuel, which leads to interfering laser-induced fluorescence signals.

Sulfur content in gasoline is known to reduce the efficiency of the catalytic converters that are used to reduce pollutants in the exhaust gas of cars. There is some concern that nitrous oxide emissions (N2O) increase when fuel with a high sulfur content is used. The engine out and tailpipe mass emissions of two cars conforming to the California LEV-standard were analyzed. The influence of the fuel sulfur content on the emissions of the regulated and some unregulated pollutants during FTP test cycles was determined. Four fuels covering the range from less than 1 to 330 ppm sulfur content were used. Over that range of fuel sulfur concentration the engine out emissions of sulfur dioxide (SO2 ) of both cars increased. Tailpipe emissions of SO2 were only found at fuel sulfur concentrations of 150 and 330 ppm. For both vehicles a correlation between the N2O emissions and the fuel sulfur content was found.

Adoption of high-pressure common-rail (HPCR) fuel systems, which subject diesel fuels to higher temperatures and pressures, has brought into question the veracity of ASTM International specifications for biodiesel and biodiesel blend oxidation stability, as well as the lack of any stability parameter for diesel fuel. A controlled experiment was developed to investigate the impact of a light-duty diesel HPCR fuel system on the stability of 20% biodiesel (B20) blends under conditions of intermittent use and long-term storage in a relatively hot and dry climate. B20 samples with Rancimat induction periods (IPs) near the current 6.0-hour minimum specification (6.5 hr) and roughly double the ASTM specification (13.5 hr) were prepared from a conventional diesel and a highly unsaturated biodiesel. Four 2011 model year Volkswagen Passats equipped with HPCR fuel injection systems were utilized: one on B0, two on B20-6.5 hr, and one on B20-13.5 hr.

A recently developed Laser Raman Scattering system was applied to measure the in-cylinder air-fuel ratio and the residual gas content (via the water content) of the charge simultaneously in a firing spark-ignition engine during cold start and warm-up. It is the main objective of this work to elucidate the origin of misfires and the necessity to over-fuel at cool ambient temperatures. It turns out that the overall air-fuel ratio and residual gas content (in particular the residual water content) of the charge appear to be the most important parameters for the occurrence of misfires (without appropriate fuel enrichment), i.e., the engine behaviour from cycle to cycle becomes rather predictable on the basis of these data. An alternative explanation for the necessity to over-fuel is given.

Mixture formation analysis in the combustion chamber of a slightly modified mass-production SI engine with port-fuel injection using nonintrusive laser measurement techniques is presented. Laser Raman scattering and planar laser-induced tracer fluorescence are employed to measure air-fuel ratio and residual gas content of the charge with and without spatial resolution. Single-cycle measurements as well as cycle-averaged measurements are performed. Engine operation parameters like load, speed, injection timing, spark timing, coolant temperature, and mean air-fuel ratio are changed to study whether the effects on mixture formation and engine performance can be resolved by the applied laser spectroscopic techniques. Mixture formation is also analyzed by measurement of the charge composition as a function of crank angle. Clear correlations of the charge composition data and engine operating conditions are seen.

VOLKSWAGEN has conducted a number of investigations on a Multi Fuel Vehicle (MFV), designed for variable fuel operation, to determine the influence of fuel composition and clean fuels on exhaust emissions, mainly on ozone forming potential. Results of the tests indicate a small advantage of Phase II Reformulated Gasoline and a greater one for for methanol fuel M85, compared to today's gasoline. For M85 there is an about 25 % lower ozone forming potential. The most critical components in the exhaust of methanol fueled vehicles (M85) are unburned methanol and formaldehyde, forming more than 60 % of the total ozone forming potential. Therefore improvement of cold start and warmup driving during the first two to three minutes is of great importance, because in this time about 90 % of the mentioned components are formed.

The EPEFE study (European Programme on Emissions, Fuels and Engine Technologies), /1/ and other programmes have identified an increase in tailpipe NOx emissions with reduced gasoline aromatics content for modern 3-way controlled catalyst vehicles. This effect occurs with fully warmed-up catalyst under closed-loop operation. In order to understand the reasons for this effect VW and Shell have mechanistically investigated the effects of fuel properties on EMS (engine management system) and catalyst performance. Fuels with independent variation of oxygen, aromatics and mid-range volatility were tested in different VW engines. λ was monitored using sensors located both pre and post catalyst. The results confirmed that reducing gasoline aromatics content reduced engine-out emissions but increased tailpipe NOx emissions. It could be shown that differences in H/C ratio led to differences in the hydrogen content of engine-out emissions which affected the reading of the λ sensor.

To date, no generally valid statements can be made about the service life of brake pads, which may be due to factors such as driving style, the friction material used or the varying vehicle weight. While dynamic friction models including friction history are already established [1], the investigation of wear and wear dust behavior is currently in the focus of many research projects. One example is the investigation of calculation models for brake pad wear while neglecting the temperature development in the brake [2]. In cars, temperatures of up to 800°C occur in the brake under high loads, which leads to a significant increase in wear. Accordingly, the question arises how an estimation of brake pad wear can be applied to highly dynamic load cases. To do this, however, the processes taking place in the boundary layer between pad and disc must first be comprehensively understood and described.