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Alumina (Al2O3) thin film coatings are applied on Al alloys using Plasma Electrolytic Oxidation (PEO) method to reduce the wear and corrosion problems. Plasma Electrolytic Aluminating (PEA) is a technique which could generate Alumina coatings on cast iron, mild steel and copper alloys. In this study, the aim is to explore the anti-wear and anti-corrosion behaviours of PEA Alumina coatings on gray cast iron. The dry sliding tribology test data was obtained from Pin-on-Disk (POD) tests against SAE 52100 steel and Tungsten Carbide (WC) counterfaces. Comparing with the PEO Alumina coatings, the PEA Alumina coating has much lower Coefficient of Friction (COF) and less wear. The microstructure, chemical composition and phase composition of this coating were investigated with Scanning Electron Microscope (SEM), Energy-Dispersive X-Ray Spectroscopy (EDX) and X-Ray Diffraction (XRD), respectively. There was FeO (or FeAl2O4) found on the PEA Alumina coating.

Modern diesel engines employ a multitude of strategies for oxides of nitrogen (NOx) emission abatement, with exhaust gas recirculation (EGR) being one of the most effective technique. The need for a precise control on the intake charge dilution (as a result of EGR) is paramount since small fluctuations in the intake charge dilution at high EGR rates may cause larger than acceptable spikes in NOx/soot emissions or deterioration in the combustion efficiency, especially at low to mid-engine loads. The control problem becomes more pronounced during transient engine operation; currently the trend is to momentarily close the EGR valve during tip-in or tip-out events. Therefore, there is a need to understand the transient EGR behaviour and its impact on the intake charge development especially under unstable combustion regimes such as low temperature combustion.

Thermal efficiency comparisons are made between the low temperature combustion and the conventional diesel cycles on a common-rail diesel engine with a conventional diesel fuel. Empirical studies have been conducted under independently controlled exhaust gas recirculation, intake boost, and exhaust backpressure. Up to 8 fuel injection pulses per cylinder per cycle have been applied to modulate the homogeneity history of the early injection diesel low temperature combustion operations in order to improve the phasing of the combustion process. The impact of heat release phasing, duration, shaping, and splitting on the thermal efficiency has been analyzed with zero-dimensional engine cycle simulations. This paper intends to identify the major parameters that affect diesel low temperature combustion engine thermal efficiency.

Conventionally, the diesel fuel ignites spontaneously following the injection event. The combustion and injection often overlap with a very short ignition delay. Diesel engines therefore offer superior combustion stability characterized by the low cycle-to-cycle variations. However, the enforcement of the stringent emission regulations necessitates the implementation of innovative diesel combustion concepts such as the low temperature combustion (LTC) to achieve ultra-low engine-out pollutants. In stark contrast to the conventional diesel combustion, the enabling of LTC requires enhanced air fuel mixing and hence a longer ignition delay is desired. Such a decoupling of the combustion events from the fuel injection can potentially cause ignition discrepancy and ultimately lead to combustion cyclic variations.

This work investigates the suitability of n-butanol for enabling PCCI, HCCI, and RCCI combustion modes to achieve clean and efficient combustion on a high compression ratio (18.2:1) diesel engine. Systematic engine tests are conducted at low and medium engine loads (6∼8 bar IMEP) and at a medium engine speed of 1500 rpm. Test results indicate that n-butanol is more suitable than diesel to enable PCCI and HCCI combustion with the same engine hardware. However, the combustion phasing control for n-butanol is demanding due to the high combustion sensitivity to variations in engine operating conditions where engine safety concerns (e.g. excessive pressure rise rates) potentially arise. While EGR is the primary measure to control the combustion phasing of n-butanol HCCI, the timing control of n-butanol direct injection in PCCI provides an additional leverage to properly phase the n-butanol combustion.

This study investigates neat n-butanol, as a cleaner power source, to directly replace conventional diesel fuels for enabling low temperature combustion on a modern common-rail diesel engine. Engine tests are performed at medium engine loads (6∼8 bar IMEP) with the single-shot injection strategy for both n-butanol and diesel fuels. As indicated by the experimental results, the combustion of neat n-butanol offers comparable engine efficiency to that of diesel while producing substantially lower NOx emissions even without the use of exhaust gas recirculation. The greater resistance to auto-ignition allows n-butanol to undergo a prolonged ignition delay for air-fuel mixing; the high volatility helps to enhance the cylinder charge homogeneity; the fuel-borne oxygen contributes to smoke reduction and, as a result, the smoke emissions of n-butanol combustion are generally at a near-zero level under the tested engine operating conditions.

In this work, an innovative piston bowl design that physically divides the combustion chamber into a central zone and a peripheral zone is employed to assist the control of the ethanol-diesel combustion process via heat release shaping. The spatial combustion zone partition divides the premixed ethanol-air mixture into two portions, and the combustion event (timing and extent) of each portion can be controlled by the temporal diesel injection scheduling. As a result, the heat release profile of ethanol-diesel dual-fuel combustion is properly shaped to avoid excessive pressure rise rates and thus to improve the engine performance. The investigation is carried out through theoretical simulation study and empirical engine tests. Parametric simulation is first performed to evaluate the effects of heat release shaping on combustion noise and engine efficiency and to provide boundary conditions for subsequent engine tests.

The majority of transportation systems have continued to be powered by the internal combustion engine and fossil fuels. Heavy-duty applications especially are reliant on diesel engines for their high brake efficiency, power density, and robustness. Although engineering developments have advanced engines towards significantly fewer emissions and higher efficiency, the use of fossil-derived diesel as fuel sets a fundamental threshold in the achievable total net carbon reduction. Dimethyl ether can be produced from various renewable feedstocks and has a high chemical reactivity making it suitable for heavy-duty applications, namely compression ignition direct injection engines. Literature shows the successful use of DME fuels in diesel engines without significant hardware modifications.

A number of cylinder-pressure derived parameters including the crank angles of maximum pressure, maximum rate of pressure rise, and 50% heat released are considered as among the desired feedback for cycle-by-cycle adaptive control of diesel combustion. For real-time computation of these parameters, the heat release analyses based on the first law of thermodynamics are used. This paper intends to identify the operating regions where the simplified heat release approach provides sufficient accuracy for control applications and also highlights those regions where its use can lead to significant errors in the calculated parameters. The effects of the cylinder charge-to-wall heat transfer and the temperature dependence of the specific heat ratio on the model performance are reported. A new computationally efficient algorithm for estimating the crank angle of 50% heat released with adequate accuracy is proposed for computation in real-time.

Diesel engines operating in the low-temperature combustion (LTC) mode generally tend to produce very low levels of NOx and soot. However, the implementation of LTC is challenged by the higher cycle-to-cycle variation with heavy EGR operation and the narrower operating corridors. The robustness and efficiency of LTC operation in diesel engines can be enhanced with improvements in the promptness and accuracy of combustion control. A set of field programmable gate array (FPGA) modules were coded and interlaced to suffice on-the-fly combustion event modulations. The cylinder pressure traces were analyzed to update the heat release rate concurrently as the combustion process proceeds prior to completing an engine cycle. Engine dynamometer tests demonstrated that such prompt heat release analysis was effective to optimize the LTC and the split combustion events for better fuel efficiency and exhaust emissions.

The diesel fuel reforming process in an exhaust gas recirculation (EGR) loop of a diesel engine is capable of utilizing the engine exhaust energy to support the endothermic process of hydrogen gas generation. However, the EGR stream commonly needs to be heated to enable the operation of the reformer and thus to sustain higher yield of hydrogen. A central-fuelling and flow-reversal embedment that is energy-efficient to raise the central temperatures of the catalytic flow-bed is therefore devised and tested to drastically reduce the supplemental heating to the EGR reformer. One-dimensional modeling analyses are conducted to evaluate the fuel delivery strategies and temperature profiles of the reformer at various reforming gas flow rates and engine-out exhaust temperatures and compositions. This research attempts to quantify the energy saving by the catalytic flow-reversal and central-fuelling embedment in comparison to a unidirectional flow EGR reformer.

We are witnessing a rapid and ongoing expansion of nanoscience, driven by potential applications in advanced materials and nanotechnology. There is a race to develop techniques that may allow controlling the size, shape of nanostructures that can allow the tuning of their optical and electronic properties. Plasmonics is a field that encompasses and profits from the optical enhancement in nanostructures that support plasmon excitations. One of these new techniques is surface-enhanced Raman scattering (SERS), commonly used for nanostructure characterization. In the present report, we present a theoretical model for plasmon excitation and electric field enhancement that help to provide an explanation for the special features observed in experimental SERS. Two sets of experimental results are discussed illustrating the make out of the signature of the plasmonics producing the optical enhancement.

The push for environmental protection and sustainability has led to strict emission regulations for automotive manufacturers as evident in EURO VII and 2026 EPA requirements. The challenge lies in maintaining fuel efficiency and simultaneously reducing the carbon footprint while meeting future emission regulations. Alcohol (primarily methanol, ethanol, and butanol) and ether (dimethyl ether) fuels, owing to their comparable energy density to existing fuels, the comparative ease of handling, renewable production, and suitable emission characteristics may present an attractive drop-in replacement, fully or in part as an additive, to the gasoline/diesel fuels, without extensive modifications to the engine geometry. Additionally, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines.

Low temperature combustion (LTC) has been proved to overcome the trade-off between NOx and soot emissions in direct injection compression ignition engines. However, the lowered NOx emissions are accompanied by high hydrocarbon and CO emissions. Moreover, the NOx emissions under LTC has much higher NO2 concentrations compared with traditional high temperature combustion conditions. Experimental investigations have been carried out to show the hydrocarbon impact on NOx emissions and NO-NO2 conversion under various engine operation conditions, but the mechanism is less understood. The article includes numerical studies of the impact of hydrocarbons in the in-cylinder conversion of NO to NO2 during low temperature conditions in a compression ignition engine. In the present work, a stochastic reactor model with detailed chemical kinetics is utilized to investigate the reaction pathways during the NOx reduction and NO2 conversion processes.

Engine performance and emission comparisons were made between the use of 100% soy, Canola and yellow grease derived biodiesel fuels and an ultra-low sulphur diesel fuel in the oxygen deficient regions, i.e. full or high load engine operations. Exhaust gas recirculation (EGR) was extensively applied to initiate low temperature combustion. An intake throttling valve was implemented to increase the differential pressure between the intake and exhaust in order to increase and enhance the EGR. The intake temperature, pressure, and EGR levels were modulated to improve the engine fuel efficiency and exhaust emissions. Furthermore, a preliminary ignition delay correlation under the influence of EGR was developed. Preliminary low temperature combustion modelling of the biodiesel and diesel fuels was also conducted. The research intends to achieve simultaneous reductions of nitrogen oxides and soot emissions in modern production diesel engines when biodiesel is applied.

Low temperature combustion (LTC) strategies such as homogeneous charge compression ignition (HCCI), smokeless rich combustion, and reactivity controlled compression ignition (RCCI) provide for cleaner combustion with ultra-low NOx and soot emissions from compression-ignition engines. However, these strategies vary significantly in their implementation requirements, combustion characteristics, operability limits as well as sensitivity to boundary conditions such as exhaust gas recirculation (EGR) and intake temperature. In this work, a detailed analysis of the aforementioned LTC strategies has been carried out on a high-compression ratio, single-cylinder diesel engine. The effects of intake boost, EGR quantity/temperature, engine speed, injection scheduling and injection pressure on the operability limits have been empirically determined and correlated with the combustion stability and performance metrics.

Compression ignition engines used in heavy-duty applications are typically powered by diesel fuel. The high energy density and feedstock abundance provide a continuing source for the immense energy demand. However, the heavy-duty transportation sector is challenged with lowering greenhouse gas and combustion by-product emissions, including carbon dioxide, nitrogen oxides, and particulate matter. The continuing development of engine management and combustion strategies has proven the ability to meet current regulations, particularly with higher fuel injection pressure. Nonetheless, a transition from diesel to a renewable alternative fuel source will play a significant role in reducing greenhouse gases while maintaining the convenience and energy density inherent in liquid fuels. Dimethyl ether is a versatile fuel that possesses combustion properties suitable for compression ignition engines and physical properties helpful for clean combustion.

Laser cladding is a novel process of surface coating, and researchers in both academia and industry are developing additive manufacturing solutions for large, metallic components. There are many interlinked process parameters associated with laser cladding, which may have an impact on the resultant microhardness profile throughout the bead zone. A set of single bead laser cladding experiments were done using a 4 kW fiber laser coupled with a 6-axis robotic arm for 420 martensitic stainless steel powder. A design of experiments approach was taken to explore a wide range of process parameter settings. The goal of this research is to determine whether robust predictive models for hardness can be developed, and if there are predictive trends that can be employed to optimize the process settings for a given set of process parameters and microhardness requirements.

The exhaust emission and performance characteristics of a 100% biodiesel fuel was evaluated on a single cylinder direct injection diesel engine that had been modified to allow multi-pulse diesel fuel injection at the intake port and independent control of intake heating, exhaust gas recirculation and throttling. Firstly, conventional single-shot direct injection tests were conducted and comparisons made between the use of an ultra-low sulphur diesel fuel and the biodiesel fuel. Secondly, tests for the premixed combustion of neat biodiesel were performed. Exhaust gas recirculation was applied extensively to initiate the low temperature combustion for the conventional in-cylinder single injection operation and to moderate the timing of the homogeneous charge compression ignition for the intake-port sequential injection. Because of the high viscosity and low volatility of the biodiesel, pilot-ignited homogeneous charge compression ignition was used.

This study investigated neat n-butanol combustion, emissions and thermal efficiency characteristics in a compression ignition (CI) engine by using two fuelling techniques - port fuel injection (PFI) and direct injection (DI). Diesel fuel was used in this research for reference. The engine tests were conducted on a single-cylinder four-stroke DI diesel engine with a compression ratio of 18.2 : 1. An n-Butanol PFI system was installed to study the combustion characteristics of Homogeneous Charge Compression Ignition (HCCI). A common-rail fuel injection system was used to conduct the DI tests with n-butanol and diesel. 90 MPa injection pressure was used for the DI tests. The engine was run at 1500 rpm. The intake boost pressure, engine load, exhaust gas recirculation (EGR) ratio, and DI timing were independently controlled to investigate the engine performance.