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Technical Paper

Wear and Galvanic Corrosion Protection of Mg alloy via Plasma Electrolytic Oxidation Process for Mg Engine Application

2009-04-20
2009-01-0790
Sliding wear of magnesium (Mg) engine cylinder bore surfaces and corrosion of Mg engine coolant channels are the two unsolved critical issues that automakers have to deal with in development of magnesium-intensive engines. In this paper, Plasma Electrolytic Oxidation (PEO) process was used to produce oxide coatings on AJ62 Mg alloy to provide wear and corrosion protection. In order to optimize the PEO process, orthogonal experiments were conducted to investigate the effect of PEO process parameters on the wear properties of PEO coatings. The PEO coatings showed a much better wear resistance, as well as a smaller friction coefficient, than the AJ62 substrate. The galvanic corrosion property of AJ62 Mg coupled with stainless steel and aluminum (Al) was investigated via immersion corrosion test in an engine coolant. Applying PEO coating on Mg can effectively prevent the galvanic corrosion attack to Mg.
Technical Paper

Wear and Corrosion Behaviours of PEA Alumina Coatings on Gray Cast Iron

2022-03-29
2022-01-0329
Alumina (Al2O3) thin film coatings are applied on Al alloys using Plasma Electrolytic Oxidation (PEO) method to reduce the wear and corrosion problems. Plasma Electrolytic Aluminating (PEA) is a technique which could generate Alumina coatings on cast iron, mild steel and copper alloys. In this study, the aim is to explore the anti-wear and anti-corrosion behaviours of PEA Alumina coatings on gray cast iron. The dry sliding tribology test data was obtained from Pin-on-Disk (POD) tests against SAE 52100 steel and Tungsten Carbide (WC) counterfaces. Comparing with the PEO Alumina coatings, the PEA Alumina coating has much lower Coefficient of Friction (COF) and less wear. The microstructure, chemical composition and phase composition of this coating were investigated with Scanning Electron Microscope (SEM), Energy-Dispersive X-Ray Spectroscopy (EDX) and X-Ray Diffraction (XRD), respectively. There was FeO (or FeAl2O4) found on the PEA Alumina coating.
Technical Paper

Wear Performances of Gray Cast Iron Brake Rotor with Plasma Electrolytic Aluminating Coating against Different Pads

2020-10-05
2020-01-1623
Gray cast iron brake rotor experiences substantial wear during braking and contributes largely to the wear debris emissions. Surface coating on the gray cast iron rotor represents a trending approach dealing with the problems. In this research, a new plasma electrolytic aluminating (PEA) process was used for preparing an alumina-based ceramic coating with metallurgical bonding to the gray cast iron. Three different types of brake pads (ceramic, semi-metallic and non asbestos organic (NAO)) were used for tribotests. Performances of PEA coatings vs. different brake pad materials were comparatively investigated with respect to their coefficients of friction (COFs) and wear. The PEA-coated brake rotor has a dimple-like surface which promotes the formation of a thin transferred film to protect the rotor from wear. The transferred film materials come from the wear debris of the pads. The secondary plateaus are regenerated on the brake pads through compacting wear debris of the pads.
Technical Paper

Thermal Efficiency Analyses of Diesel Low Temperature Combustion Cycles

2007-10-29
2007-01-4019
Thermal efficiency comparisons are made between the low temperature combustion and the conventional diesel cycles on a common-rail diesel engine with a conventional diesel fuel. Empirical studies have been conducted under independently controlled exhaust gas recirculation, intake boost, and exhaust backpressure. Up to 8 fuel injection pulses per cylinder per cycle have been applied to modulate the homogeneity history of the early injection diesel low temperature combustion operations in order to improve the phasing of the combustion process. The impact of heat release phasing, duration, shaping, and splitting on the thermal efficiency has been analyzed with zero-dimensional engine cycle simulations. This paper intends to identify the major parameters that affect diesel low temperature combustion engine thermal efficiency.
Technical Paper

The Impact of Intake Dilution and Combustion Phasing on the Combustion Stability of a Diesel Engine

2014-04-01
2014-01-1294
Conventionally, the diesel fuel ignites spontaneously following the injection event. The combustion and injection often overlap with a very short ignition delay. Diesel engines therefore offer superior combustion stability characterized by the low cycle-to-cycle variations. However, the enforcement of the stringent emission regulations necessitates the implementation of innovative diesel combustion concepts such as the low temperature combustion (LTC) to achieve ultra-low engine-out pollutants. In stark contrast to the conventional diesel combustion, the enabling of LTC requires enhanced air fuel mixing and hence a longer ignition delay is desired. Such a decoupling of the combustion events from the fuel injection can potentially cause ignition discrepancy and ultimately lead to combustion cyclic variations.
Journal Article

Surface Fatigue Cracking Behavior of a CrN-Coated Tool Steel Influenced by Sliding Cycles and Sliding Energy Density

2017-03-28
2017-01-0303
Light-weighting of vehicles is one of the challenges for transportation industry due to the increasing pressure of demands in better fuel economy and environment protection. Advanced high strength steels (AHSS) are considered as prominent material of choice to realize lightweight auto body and structures at least in near term. Stamping of AHSS with conventional die materials and surface coatings, however, results in frequent die failures and undesired panel surface finish. A chromium nitride (CrN) coating with plasma nitriding case hardened layer on a die material (duplex treatment) is found to offer good wear and galling resistances. The coating failure initiates from fatigue cracking on the coating surface due to cyclic sliding frictions. In this work, cyclic inclined sliding wear test was used to imitate a stamping process for study on development of coating fatigue cracking, including crack length and spacing vs. sliding-cycles and sliding energy densities.
Technical Paper

Surface Effect of a PEO Coating on Friction at Different Sliding Velocities

2015-04-14
2015-01-0687
In order to reduce the weight of an automotive engine, an aluminum (Al) alloy engine block with cast iron liner has been successfully used to replace the gray cast iron engine. For newly emerging Al linerless engine in which the low surface hardness of the aluminum alloy has to be overcome, a few surface processing technologies are used to protect the surface of cylinders. Among them, plasma transferred wire arc (PTWA) thermal spraying coating is becoming popular. Plasma electrolytic oxidation (PEO) coating is also proposed for increasing the wear resistance of aluminum alloy and reducing the friction between the cylinder and piston. In this work, a PEO coating with a thickness of ∼20 μm was prepared, and a high speed pin-on-disc tribometer was used to study the tribological behavior of the coating at oil lubricant conditions. Different surface roughness of the coating and a large range of the sliding speeds were employed for the tests.
Technical Paper

Study of Low Temperature Combustion with Neat n-Butanol on a Common-rail Diesel Engine

2015-03-10
2015-01-0003
This study investigates neat n-butanol, as a cleaner power source, to directly replace conventional diesel fuels for enabling low temperature combustion on a modern common-rail diesel engine. Engine tests are performed at medium engine loads (6∼8 bar IMEP) with the single-shot injection strategy for both n-butanol and diesel fuels. As indicated by the experimental results, the combustion of neat n-butanol offers comparable engine efficiency to that of diesel while producing substantially lower NOx emissions even without the use of exhaust gas recirculation. The greater resistance to auto-ignition allows n-butanol to undergo a prolonged ignition delay for air-fuel mixing; the high volatility helps to enhance the cylinder charge homogeneity; the fuel-borne oxygen contributes to smoke reduction and, as a result, the smoke emissions of n-butanol combustion are generally at a near-zero level under the tested engine operating conditions.
Technical Paper

Study of Dimethyl Ether Fuel Spray Characteristics and Injection Profile

2024-04-09
2024-01-2702
The majority of transportation systems have continued to be powered by the internal combustion engine and fossil fuels. Heavy-duty applications especially are reliant on diesel engines for their high brake efficiency, power density, and robustness. Although engineering developments have advanced engines towards significantly fewer emissions and higher efficiency, the use of fossil-derived diesel as fuel sets a fundamental threshold in the achievable total net carbon reduction. Dimethyl ether can be produced from various renewable feedstocks and has a high chemical reactivity making it suitable for heavy-duty applications, namely compression ignition direct injection engines. Literature shows the successful use of DME fuels in diesel engines without significant hardware modifications.
Technical Paper

Real-time Heat Release Analysis for Model-based Control of Diesel Combustion

2008-04-14
2008-01-1000
A number of cylinder-pressure derived parameters including the crank angles of maximum pressure, maximum rate of pressure rise, and 50% heat released are considered as among the desired feedback for cycle-by-cycle adaptive control of diesel combustion. For real-time computation of these parameters, the heat release analyses based on the first law of thermodynamics are used. This paper intends to identify the operating regions where the simplified heat release approach provides sufficient accuracy for control applications and also highlights those regions where its use can lead to significant errors in the calculated parameters. The effects of the cylinder charge-to-wall heat transfer and the temperature dependence of the specific heat ratio on the model performance are reported. A new computationally efficient algorithm for estimating the crank angle of 50% heat released with adequate accuracy is proposed for computation in real-time.
Technical Paper

Prompt Heat Release Analysis to Improve Diesel Low Temperature Combustion

2009-06-15
2009-01-1883
Diesel engines operating in the low-temperature combustion (LTC) mode generally tend to produce very low levels of NOx and soot. However, the implementation of LTC is challenged by the higher cycle-to-cycle variation with heavy EGR operation and the narrower operating corridors. The robustness and efficiency of LTC operation in diesel engines can be enhanced with improvements in the promptness and accuracy of combustion control. A set of field programmable gate array (FPGA) modules were coded and interlaced to suffice on-the-fly combustion event modulations. The cylinder pressure traces were analyzed to update the heat release rate concurrently as the combustion process proceeds prior to completing an engine cycle. Engine dynamometer tests demonstrated that such prompt heat release analysis was effective to optimize the LTC and the split combustion events for better fuel efficiency and exhaust emissions.
Technical Paper

Preliminary Energy Efficiency Analysis of an EGR Fuel-Reformer

2004-10-25
2004-01-2918
Diesel engine exhausts commonly contain a high level of surplus oxygen and a significant amount of thermal energy. In this study the authors have theoretically investigated a way of utilizing the thermal energy and the surplus oxygen of exhaust gases to produce gaseous fuel in a rich combustor placed in an exhaust gas recirculation (EGR) loop. In the rich combustor, a small amount of diesel fuel will be catalytically reformed on a palladium/platinum based catalyst to produce hydrogen and carbon monoxide. Since the catalytic EGR reformer is incorporated in the EGR loop, it enables the partial recovery of exhaust heat. The gaseous fuel produced in the rich combustor can be brought back into the engine in a pre-mixed condition, potentially reducing soot formation. The preliminary energy efficiency analysis has been performed by using CHEMKIN and an in-house engine simulation software SAES.
Technical Paper

Preliminary Energy Efficiency Analyses of Diesel EGR Fuel Reforming with Flow Reversal and Central Fuelling

2007-10-29
2007-01-4035
The diesel fuel reforming process in an exhaust gas recirculation (EGR) loop of a diesel engine is capable of utilizing the engine exhaust energy to support the endothermic process of hydrogen gas generation. However, the EGR stream commonly needs to be heated to enable the operation of the reformer and thus to sustain higher yield of hydrogen. A central-fuelling and flow-reversal embedment that is energy-efficient to raise the central temperatures of the catalytic flow-bed is therefore devised and tested to drastically reduce the supplemental heating to the EGR reformer. One-dimensional modeling analyses are conducted to evaluate the fuel delivery strategies and temperature profiles of the reformer at various reforming gas flow rates and engine-out exhaust temperatures and compositions. This research attempts to quantify the energy saving by the catalytic flow-reversal and central-fuelling embedment in comparison to a unidirectional flow EGR reformer.
Journal Article

Plasmonic in Metallic Nanostructures – Fabrication, Characterization and Applications in Surface-Enhanced Spectroscopy

2008-04-14
2008-01-1267
We are witnessing a rapid and ongoing expansion of nanoscience, driven by potential applications in advanced materials and nanotechnology. There is a race to develop techniques that may allow controlling the size, shape of nanostructures that can allow the tuning of their optical and electronic properties. Plasmonics is a field that encompasses and profits from the optical enhancement in nanostructures that support plasmon excitations. One of these new techniques is surface-enhanced Raman scattering (SERS), commonly used for nanostructure characterization. In the present report, we present a theoretical model for plasmon excitation and electric field enhancement that help to provide an explanation for the special features observed in experimental SERS. Two sets of experimental results are discussed illustrating the make out of the signature of the plasmonics producing the optical enhancement.
Technical Paper

Performance and Emission Characteristics of Direct Injection DME Combustion under Low NOx Emissions

2023-04-11
2023-01-0327
Compression ignition internal combustion engines provide unmatched power density levels, making them suitable for numerous applications including heavy-duty freight trucks, marine shipping, and off-road construction vehicles. Fossil-derived diesel fuel has dominated the energy source for CI engines over the last century. To mitigate the dependency on fossil fuels and lessen anthropogenic carbon released into the atmosphere within the transportation sector, it is critical to establish a fuel source which is produced from renewable energy sources, all the while matching the high-power density demands of various applications. Dimethyl ether (DME) has been used in non-combustion applications for several decades and is an attractive fuel for CI engines because of its high reactivity, superior volatility to diesel, and low soot tendency. A range of feedstock sources can produce DME via the catalysis of syngas.
Technical Paper

Oxygenated Fuels as Reductants for Lean NOx Trap Regeneration

2024-04-09
2024-01-2132
The push for environmental protection and sustainability has led to strict emission regulations for automotive manufacturers as evident in EURO VII and 2026 EPA requirements. The challenge lies in maintaining fuel efficiency and simultaneously reducing the carbon footprint while meeting future emission regulations. Alcohol (primarily methanol, ethanol, and butanol) and ether (dimethyl ether) fuels, owing to their comparable energy density to existing fuels, the comparative ease of handling, renewable production, and suitable emission characteristics may present an attractive drop-in replacement, fully or in part as an additive, to the gasoline/diesel fuels, without extensive modifications to the engine geometry. Additionally, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines.
Technical Paper

Neat Biodiesel Fuel Engine Tests and Preliminary Modelling

2007-04-16
2007-01-0616
Engine performance and emission comparisons were made between the use of 100% soy, Canola and yellow grease derived biodiesel fuels and an ultra-low sulphur diesel fuel in the oxygen deficient regions, i.e. full or high load engine operations. Exhaust gas recirculation (EGR) was extensively applied to initiate low temperature combustion. An intake throttling valve was implemented to increase the differential pressure between the intake and exhaust in order to increase and enhance the EGR. The intake temperature, pressure, and EGR levels were modulated to improve the engine fuel efficiency and exhaust emissions. Furthermore, a preliminary ignition delay correlation under the influence of EGR was developed. Preliminary low temperature combustion modelling of the biodiesel and diesel fuels was also conducted. The research intends to achieve simultaneous reductions of nitrogen oxides and soot emissions in modern production diesel engines when biodiesel is applied.
Technical Paper

Load and Lubricating Oil Effects on Friction of a PEO Coating at Different Sliding Velocities

2017-03-28
2017-01-0464
Friction between the piston and cylinder accounts for large amount of the friction losses in an internal combustion (IC) engine. Therefore, any effort to minimize such a friction will also result in higher efficiency, lower fuel consumption and reduced emissions. Plasma electrolytic oxidation (PEO) coating is considered as a hard ceramic coating which can provide a dimpled surface for oil retention to bear the wear and reduce the friction from sliding piston rings. In this work, a high speed pin-on-disc tribometer was used to generate the boundary, mixed and hydrodynamic lubrication regimes. Five different lubricating oils and two different loads were applied to do the tribotests and the COFs of a PEO coating were studied. The results show that the PEO coating indeed had a lower COF in a lower viscosity lubricating oil, and a smaller load was beneficial to form the mixed and hydrodynamic lubricating regimes earlier.
Technical Paper

Investigation of Fuel Injection Pressure Impact on Dimethyl Ether Combustion

2023-10-31
2023-01-1644
Compression ignition engines used in heavy-duty applications are typically powered by diesel fuel. The high energy density and feedstock abundance provide a continuing source for the immense energy demand. However, the heavy-duty transportation sector is challenged with lowering greenhouse gas and combustion by-product emissions, including carbon dioxide, nitrogen oxides, and particulate matter. The continuing development of engine management and combustion strategies has proven the ability to meet current regulations, particularly with higher fuel injection pressure. Nonetheless, a transition from diesel to a renewable alternative fuel source will play a significant role in reducing greenhouse gases while maintaining the convenience and energy density inherent in liquid fuels. Dimethyl ether is a versatile fuel that possesses combustion properties suitable for compression ignition engines and physical properties helpful for clean combustion.
Technical Paper

Influence of Biodiesel Fuel on Diesel Engine Performance and Emissions in Low Temperature Combustion

2006-10-16
2006-01-3281
The exhaust emission and performance characteristics of a 100% biodiesel fuel was evaluated on a single cylinder direct injection diesel engine that had been modified to allow multi-pulse diesel fuel injection at the intake port and independent control of intake heating, exhaust gas recirculation and throttling. Firstly, conventional single-shot direct injection tests were conducted and comparisons made between the use of an ultra-low sulphur diesel fuel and the biodiesel fuel. Secondly, tests for the premixed combustion of neat biodiesel were performed. Exhaust gas recirculation was applied extensively to initiate the low temperature combustion for the conventional in-cylinder single injection operation and to moderate the timing of the homogeneous charge compression ignition for the intake-port sequential injection. Because of the high viscosity and low volatility of the biodiesel, pilot-ignited homogeneous charge compression ignition was used.
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