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Previous research has shown that the homogeneous charge compression ignition (HCCI) combustion concept holds promise for reducing pollutants (i.e. NOx, soot) while maintaining high thermal efficiency. However, it can be difficult to control the operation of the HCCI engines even under steady state running conditions. Power density may also be limited if high inlet air temperatures are used for achieving ignition. A methodology using a small pilot quantity of diesel fuel injected during the compression stroke to improve the power density and operation control is considered in this paper. Multidimensional computations were carried out for an HCCI engine based on a CAT3401 engine. The computations show that the required initial temperature for ignition is reduced by about 70 K for the cases of the diesel pilot charge and a 25∼35% percent increase in power density was found for those cases without adversely impacting the NOx emissions.

A Three-Way Catalyst (TWC) model with global TWC kinetics for lean burn DISI engines were developed and validated. The model incorporates kinetics of hydrocarbons and carbon monoxide oxidations, NOx reduction, water-gas and steam reforming and oxygen storage. Ammonia (NH₃) and new nitrous oxide (N₂O) kinetics were added into the model to study NH₃ and N₂O formation in TWC systems. The model was validated over a wide range of engine operating conditions using various types of experimental data from a lean burn automotive SIDI engine. First, well-controlled time-resolved steady state data were used for calibration and initial model tests. In these steady state operations, the engine was switched between lean and rich conditions for NOx emission control. Then, the model was further validated using a large set of time-averaged steady state data. Temperature dependencies of NH₃ and N₂O kinetics in the TWC model were examined and well captured by the model.

The effects of thermal and chemical aging on the performance of cordierite-based and high-porosity mullite-based diesel particulate filters (DPFs), were quantified, particularly their filtration efficiency, pressure drop, and regeneration capability. Both catalyzed and uncatalyzed core-size samples were tested in the lab using a diesel fuel burner and a chemical reactor. The diesel fuel burner generated carbonaceous particulate matter with a pre-specified particle-size distribution, which was loaded in the DPF cores. As the particulate loading evolved, measurements were made for the filtration efficiency and pressure drop across the filter using, respectively, a Scanning Mobility Particle Sizer (SMPS) and a pressure transducer. In a subsequent process and on a different bench system, the regeneration capability was tested by measuring the concentration of CO plus CO2 evolved during the controlled oxidation of the carbonaceous species previously deposited on the DPF samples.

Fuel properties impact the engine-out emission directly. For some geographic regions where diesel engines can meet emission regulations without aftertreatment, the change of fuel properties will lead to final tailpipe emission variation. Aftertreatment systems such as Diesel Particulate Filter (DPF) and Selective Catalytic Reduction (SCR) are required for diesel engines to meet stringent regulations. These regulations include off-road Tier 4 Final emission regulations in the USA or the corresponding Stage IV emission regulations in Europe. As an engine with an aftertreatment system, the change of fuel properties will also affect the system conversion efficiency and regeneration cycle. Previous research works focus on prediction of engine-out emission, and many are based on chemical reactions. Due to the complex mixing, pyrolysis and reaction process in heterogeneous combustion, it is not cost-effective to find a general model to predict emission shifting due to fuel variation.

A study was performed in which the effects on the regulated emissions from a commercial small DI diesel engine were measured for different refinery-derived fuel blends. Seven different fuel blends were tested, of which two were deemed to merit more detailed evaluation. To investigate the effects of fuel properties on the combustion processes with these fuel blends, two-color pyrometry was used via optically accessible cylinderheads. Additional data were obtained with one of the fuel blends with a heavy-duty DI diesel engine. California diesel fuel was used as a baseline. The fuel blends were made by mixing the components typically found in gasoline, such as methyl tertiary-butyl ether (MTBE) and whole fluid catalytic cracking gasoline (WH-FCC). The mixing was performed on a volume basis. Cetane improver (CI) was added to maintain the same cetane number (CN) of the fuel blends as that of the baseline fuel.

A single cylinder, Cummins NH, direct-injection, diesel engine has been operated in order to evaluate the effects of aromatic content and aromatic structure on diesel engine particulates. Results from three fuels are shown. The first fuel, a low sulfur Chevron diesel fuel was used as a base fuel for comparison. The other fuels consisted of the base fuel and 10% by volume of 1-2-3-4 tetrahydronaphthalene (tetralin) a single-ring aromatic and naphthalene, a double-ring aromatic. The fuels were chosen to vary aromatic content and structure while minimizing differences in boiling points and cetane number. Measurements included exhaust particulates using a mini-dilution tunnel, exhaust emissions including THC, CO2, NO/NOx, O2, injection timing, two-color radiation, soluble organic fraction, and cylinder pressure. Particulate measurements were found to be sensitive to temperature and flow conditions in the mini-dilution tunnel and exhaust system.

A study of fuel spray characteristics for diesel fuel from a multi-hole nozzle injector was performed yielding tip penetration length and spray cone angle for each of the spray plumes from a six hole injector. The main feature of the system used was that analysis of all the fuel plumes could occur at one time, as all the plumes were imaged on the same piece of film. Spray behavior was examined for two injection pressures (72 MPa and 122 MPa) and for ambient temperatures up to 523 K (250°C). The results in this paper show how the spray plumes behave as they leave each of the six holes of the injector. The characteristics of each hole differs during injection. The variations of spray cone angle and tip penetration length between holes are small, but significant. These variations in tip penetration and cone angle changed as the temperature of the chamber changed, but the overall characteristics of the spray plumes changed only slightly for the temperatures used in this paper.

A slipstream of exhaust from a Caterpillar 3126B engine was diverted into a plasma-catalytic NOx control system in the space velocity range of 7,000 to 100,000 hr-1. The stream was first fed through a non-thermal plasma that was formed in a coaxial cylinder dielectric barrier discharge reactor. Plasma treated gas was then passed over a catalyst bed held at constant temperature in the range of 573 to 773 K. Catalysts examined consisted of γ-alumina, indium-doped γ-alumina, and silver-doped γ-alumina. Road and rated load conditions resulted in engine out NOx levels of 250 - 600 ppm. The effects of hydrocarbon level, catalyst temperature, and space velocity are discussed where propene and in one case ultra-low sulfur diesel fuel (late cycle injection) were the reducing agents used for NOx reduction. Results showed NOx reduction in the range of 25 - 97% depending on engine operating conditions and management of the catalyst and slipstream conditions.

An experimental investigation of the spectral characteristics of turbulent flow in a scale model of a high pressure diesel fuel injector nozzle hole has been conducted. Instantaneous velocity measurements were made in a 50X transparent model of one hole of an injector nozzle using an Aerometrics Phase/Doppler Particle Analyzer (PDPA) in the velocity mode. Turbulence spectra were calculated from the velocity data using the Lomb-Scargle method. Injector hole length to diameter ratio (L/D) values of 1.3, 2.4, 4.9, and 7.7 and inlet radius to diameter ratio (R/D) values of approximately 0 and 0.3 were investigated. Results were obtained for a steady flow average Reynolds number of 10,500, which is analogous to a fuel injection velocity of 320 m/s and a sac pressure of approximately 67 MPa (10,000 psi). Turbulence time frequency spectra were obtained for significant locations in each geometry, in order to determine how geometry affects the development of the turbulent spectra.

Various gold catalysts were prepared using commercial and in-house fabricated advanced catalyst supports that included mesoporous silica, mesoporous alumina, sol-gel alumina, and transition metal oxides. Gold nanoparticles were loaded on the supports by co-precipitation, deposition-precipitation, ion exchange and surface functionalization techniques. The average gold particle size was ∼20nm or less. The oxidation activity of the prepared catalysts was studied using carbon monoxide and light hydrocarbons (ethylene, propylene and propane) in presence of water and CO2 and the results are presented.

Diesel engine downsizing aimed at reducing fuel consumption while meeting stringent exhaust emissions regulations is currently in high demand. The boost system architecture plays an essential role in providing adequate air flow rate for diesel fuel combustion while avoiding impaired transient response of the downsized engine. Electric Turbocharger Assist (ETA) technology integrates an electric motor/generator with the turbocharger to provide electrical power to assist compressor work or to electrically recover excess turbine power. Additionally, a variable geometry turbine (VGT) is able to bring an extra degree of freedom for the boost system optimization. The electrically-assisted turbocharger, coupled with VGT, provides an illuminating opportunity to increase the diesel engine power density and enhance the downsized engine transient response. This paper assesses the potential benefits of the electrically-assisted turbocharger with VGT to enable heavy-duty diesel engine downsizing.

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

NOx reduction efficiency in simulated lean exhaust conditions has been examined for three proprietary catalyst materials using a non-thermal plasma discharge as a pretreatment stage to the catalyst. Using propene as the reducing agent for selective catalytic reduction, 74% reduction of NOx has been observed in the presence of 20 ppm SO2. For sulfur-free simulated exhaust, 84% NOx reduction has been obtained. Results show that the impact of sulfur on the samples examined can vary widely from virtually no effect (< 5%) to more than 20% loss in activity depending on the catalyst. Any loss due to sulfur poisoning appears to be irreversible according to limited measurements on poisoned catalysts exposed to sulfur-free exhaust streams. Catalysts were tested over a temperature range of 473-773K, with the highest activity observed at 773K. Examination of this large temperature window has shown that the optimum C1:NOx ratio changes with temperature.

The University of Wisconsin Hybrid Vehicle Team has implemented and optimized a four-wheel drive, charge sustaining, split-parallel hybrid-electric crossover vehicle for entry into the 2008 ChallengeX competition. This four year project is based on a 2005 Chevrolet Equinox platform. Fuel economy, greenhouse gas impact (GHGI), acceleration, component packaging and consumer acceptability were appropriately weighted to determine powertrain component selections. Wisconsin's Equinox, nicknamed the Moovada, is a split-parallel hybrid utilizing a General Motors (GM) 110 kW 1.9L CDTi (common rail diesel turbo injection) engine coupled to an F40 6-speed manual transmission. The rear axle is powered by a SiemensVDO induction motor/gearbox power-limited to 65 kW by a 40-module (288 volts nominal) Johnson Controls Inc, nickel-metal hydride battery pack.

A number of oxidation catalysts have been prepared using different types of advanced support materials such as ceria-zirconia, silica-titania, spinels and perovskites. Active metals such as Pd and Au-Pd were loaded by conventional impregnation techniques and/or deposition-precipitation methods. A liquid hydrocarbon delivery system was designed and implemented for the catalyst test benches in order to simulate the diesel engine exhaust environment. The activity of fresh (no degreening) catalysts was evaluated with traditional CO and light hydrocarbons (C2H4, C3H6) as well as with heavy hydrocarbons such as C10 H22.

A computer model developed for describing multicomponent fuel vaporization, and ignition in diesel engines has been applied in this study to understand cold-starting and the parameters that are of significant influence on this phenomena. This research utilizes recent improvements in spray vaporization and combustion models that have been implemented in the KIVA-II CFD code. Typical engine fuels are blends of various fuels species, i.e., multicomponent. Thus, the original single component fuel vaporization model in KIVA-II was replaced by a multicomponent fuel vaporization model (based on the model suggested by Jin and Borman). The modelhas been extended to model diesel sprays under typical diesel conditions, including the effect of fuel cetane number variation. Necessary modifications were carried out in the atomization and collision sub-models. The ignition model was also modified to account for fuel composition effects by modifying the Shell ignition model.

Rate shaping of the fuel injection process is known to significantly impact emissions production in diesel engines. To demonstrate the ability of multidimensional engine modeling to quantify and explain the effect of rate shaping and injection duration, three injection profiles typical of common diesel fuel injection systems were investigated for three injection durations and injection timings. The present study uses an improved version of the KIVA-II engine simulation code employing the characteristic time combustion model, the Kelvin-Helmholtz and the Rayleigh-Taylor spray atomization mechanisms, the extended Zeldovich thermal NOx production model, and a single species soot model.

The fuel film thickness resulting from diesel fuel spray impingement was measured in a chamber at conditions representative of early injection timings used for low temperature diesel combustion. The adhered fuel volume and the radial distribution of the film thickness are presented. Fuel was injected normal to the impingement surface at ambient temperatures of 353 K, 426 K and 500 K, with densities of 10 kg/m3 and 25 kg/m3. Two injectors, with nozzle diameters of 100 μm and 120 μm, were investigated. The results show that the fuel film volume was strongly affected by the ambient temperature, but was minimally affected by the ambient density. The peak fuel film thickness and the film radius were found to increase with decreased temperature. The fuel film was found to be circular in shape, with an inner region of nearly constant thickness. The major difference observed with temperature was a decrease in the radial extent of the film.

This work experimentally investigates the impact of premixed fuel composition (methane/ethane, methane/propane, and methane/hydrogen mixtures having equivalent chemical energy) and pilot reactivity (cetane number) on diesel-pilot injection (DPI) combustion performance and emissions, with an emphasis on the pilot ignition delay (ID). To support the experimental pilot ignition delay trends, an analysis technique known as Mixing Line Concept (MLC) was adopted, where the cold diesel surrogate and hot premixed charge are envisioned to mix in a 0-D constant volume reactor to account for DPI mixture stratification. The results show that the dominant effect on pilot ignition is the pilot fuel cetane number, and that the premixed fuel composition plays a minor role. There is some indication of a physical effect on ignition for cases containing premixed hydrogen.

An experimental investigation of turbulent flow patterns in a scale model of a high pressure diesel fuel injector nozzle has been conducted. Instantaneous velocity measurements were made in a 50X transparent model of one hole of the injector nozzle using an Aerometrics Phase Doppler Particle Analyzer (PDPA) in the velocity mode. Length to diameter ratio (L/D) values of 1.3, 2.4, 4.9, and 7.7 and inlet radius to diameter ratio (R/D) values of approximately 0 and 0.3 were investigated. Two steady flow average Reynolds numbers (10,500 and 13,300), analogous to fuel injection velocities and sac pressures of approximately 320 and 405 m/s and 67 and 107 MPa (10,000 and 16,000 psi), were investigated. The axial progression of mean and root mean square (rms) axial velocities was obtained for both sharp and rounded inlet conditions and varying L/D. The discharge coefficient was also calculated for each geometry.