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The objective of this study was to investigate which of the artificial aging cycles available in the automotive industry that causes major deactivation of three-way catalysts (TWCs) and can be used to obtain an aged catalyst similar to the road aged converter (160 000km). Standard bench cycle (SBC) aging with secondary air injection (SAI) covered aging with various mass flows - a flow from three cylinders into one catalyst system and a flow from three cylinders into two parallel connected catalysts. For rapid catalyst bench aging, secondary air injection is a very efficient tool to create exotherms. Furthermore, the effect on catalytic activity of SAI aging with poisons from oil and fuel dopants (P, Ca, Zn) was investigated. The catalysts were thoroughly characterized in light-off and oxygen storage capacity measurements, emission conversion as a function of lambda and load variation was determined.

Since several decades, passenger cars and light duty vehicles (LDV) with spark-ignited engines reach full pollutant conversion during warm up conditions; the major challenge has been represented by the cold start and warming up strategies. The focus on technology developments of exhaust after treatment systems have been done in the thermal management in order to reach the warm up conditions as soon as possible. A new challenge is now represented by the Real Driving Emission (RDE) Regulation as this bring more various, and not any longer cycle defined, cold start conditions. On the other hand, once the full conversion has been reached, it would be beneficial for many Exhaust After Treatment System (EATS) components, e.g. for overall durability if the exhaust gas temperature could be lowered. To take significant further emission steps, approaching e.g. zero emission concepts, we investigate the use of Electrical Heating Catalyst (EHC) also including pre-heating.