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Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

Biodiesel is a desirable alternative fuel for the diesel engine due to its low engine-out soot emission tendency. When blended with petroleum-based diesel fuels, soot emissions generally decrease in proportion to the volume fraction of biodiesel in the mixture. This paper presents an experimental investigation of biodiesel impact on in-cylinder soot temperature and concentrations in a single-cylinder, small-bore, optical access, compression ignition engine. While in-cylinder soot measurements have been widely performed with two-color thermometry implemented on digital cameras, their finite dynamic range limits the observation of soot due to its dramatically different radiation intensities. To expand the dynamic range of two-color measurements, this investigation utilizes three cameras. A high-speed CMOS color camera with a wide-band Bayer filter is used to obtain simultaneous measurements of soot temperature and KL factor for high intensity soot clouds within one cycle.

This paper presents an experimental investigation conducted to determine the parameters that control the behavior of autoignition in a small-bore, single-cylinder, optically-accessible diesel engine. Depending on operating conditions, three types of autoignition are observed: a single ignition, a two-stage process where a low temperature heat release (LTHR) or cool flame precedes the main premixed combustion, and a two-stage process where the LTHR or cool flame is separated from the main heat release by an apparent negative temperature coefficient (NTC) region. Experiments were conducted using commercial grade low-sulfur diesel fuel with a common-rail injection system. An intensified CCD camera was used for ultraviolet imaging and spectroscopy of chemiluminescent autoignition reactions under various operating conditions including fuel injection pressures, engine temperatures and equivalence ratios.

Due to the single fuel concept implemented by the US military, the soot production of diesel engines fueled with JP-8 has important implications for military vehicle visual signature and survivability. This work compares in-cylinder soot formation and oxidation of JP-8 and ULSD in a small-bore, optical diesel engine. Experimental engine-out soot emission measurements are compared to crank-angle resolved two-color measurements of soot temperature and optical thickness, KL. A 3-D chemical kinetic-coupled CFD model with line of sight integration is employed in order to investigate the soot distribution in a 2-D projection associated with the imaging plane, as well as to aid in interpreting the third dimension along the optical depth which is not available within the experimental work. The study also examines the effect of volatility on soot emission characteristics by CFD simulation.