Search Results

An electrochemical cell is presented which reduces NOx emissions from a vehicle fueled by dedicated natural gas. The cell is comprised of a honeycomb shaped ceramic which is chemically coated with an electrically conductive material in two distinct regions which serve as electrodes such that, with the application of a voltage potential, a cathode and anode are formed. As the exhaust gas flows through the inner channels of the cell, the electrochemical reduction of NOx at the cathode yields nitrogen gas and oxide ions. The nitrogen continues to flow through the cell while the oxide ions dissolve in the solid electrolyte. At the anodic zone, oxide ions are converted to oxygen gas. The pressure drop across the cell was experimentally measured to insure that the back pressure created by the cell does not create a significant reduction in the efficiency of the engine.

Techniques have been developed to sample and speciate dilute heavy duty diesel exhaust to determine the specific reactivities and the ozone forming potential. While the Auto/Oil Air Quality Improvement Research Program (AQIRP) has conducted a comprehensive investigation to develop data on potential improvements in vehicle emissions and air quality from reformulated gasoline and various other alternative fuels. However, the development of sampling protocols and speciation of heavy duty diesel exhaust is still in its infancy [1, 2, 3, 4, 5 and 6]. This paper focuses on the first phase of the heavy duty diesel speciation program, that involves the development of a unique set of sampling protocols for the gas phase, semi-volatile and particulate matter from the exhaust of engines operating on different types of diesel fuel. Effects of sampling trains, sampling temperatures, semi-volatile adsorbents and driving cycles are being investigated.

Diesel soot interacts with the engine oil and leads to wear of engine parts. Engine oil additives play a crucial role in preventing wear by forming the anti-wear film between the wearing surfaces. The current study was aimed at investigating the interactions between engine soot and oil properties in order to develop high performance oils for diesel engines equipped with exhaust gas re-circulation (EGR). The effect of soot contaminated oil on wear of engine components was examined using a statistically designed experiment. To quantitatively analyze and simulate the extent of wear a three-body wear machine was designed and developed. The qualitative wear analysis was performed by examining the wear scars on an AISI 52100 stainless steel ball worn in the presence of oil test samples on a ball-on-flat disc setup. The three oil properties studied were base stock, dispersant level and zinc dithiophosphate level.

Corona discharge from a RF quarter wave coaxial cavity resonator is considered as a plasma ignition source for spark ignited (SI) internal combustion (IC) engines. The gaseous discharge processes associated with this device are analyzed using principles of gas kinetics and gaseous electronics, with assumed values for the electric field strength. Corona discharge occurs when the electric field shaped and concentrated by a single electrode exceeds the breakdown potential of the surrounding gas. Ambient electrons, naturally present due to ionizing radiation, drift in the direction of the externally applied field, gaining energy while undergoing elastic collisions with neutral molecules. After gaining sufficient energy they dissociate, excite, or ionize the neutral particles through inelastic collision, creating additional electrons. This process leads to avalanche electrical breakdown of the gas within about 10-8 sec.