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Vehicle exhaust emissions measurements are reported for full-size panel vans operating on four alternative motor fuels and control gasoline. The emissions tests produced data on in-use vans. The vans were taken directly from commercial delivery service for testing as they accumulated mileage over a 24-month period. The alternative fuels tested were compressed natural gas, propane gas, California Phase 2 reformulated gasoline (RFG), and methanol (M-85 with 15 percent RFG). The control gasoline for the emissions tests was an industry average unleaded blend (RF-A). The vehicle technologies tested represent those options available in 1992 that were commercially available from Ford, Chrysler, and Chevrolet or which these manufacturers agreed to provide as test vans for daily use in commercial service by FedEx.

A gas chromatographic technique was used to determine the vapor pressures of blends of six candidate diesel fuel oxygenates with three diesel fuels at 0, 5, 10, 30, and 100 percent blend levels. Both the oxygenates and the diesel fuels were selected to represent a variety of chemical compositions. The vapor pressures were determined over a range of temperatures from -30 C to +30 C. In each case the fraction of the vapor pressure derived from the oxygenate and the fuel was identified. The vapor pressure results showed that there were significant deviations from ideality, leading to both higher and lower vapor pressures than would be predicted from Raoult's Law. These results are significant for fire safety and evaporative emissions as well as for a more basic understanding of the behavior of these blends. Data were also obtained on the heats of vaporization for each of the blends.

Emissions from light duty vehicles have traditionally been measured using a chassis dynamometer, while heavy duty testing has been based on engine dynamometers. However, the need for in-use vehicle emissions data has led to the development of two transportable heavy duty chassis dynamometers capable of testing buses and heavy trucks. A test cycle has been developed for Class 8 trucks, which typically have unsyncronized transmissions. This test cycle has five peaks, each consisting of an acceleration, cruise period, and deceleration, with speeds and acceleration requirements that can be met by virtually all vehicles in common service. Termed the “WVU 5 peak truck test”, this 8 km (5 mile) cycle has been used to evaluate the emissions from diesel and ethanol powered over-the-road tractors and from diesel and ethanol powered snow plows, all with Detroit Diesel 6V92 engines.

A bi-fuel engine capable of operating either on compressed natural gas (CNG) or gasoline is being developed for the transition to alternative fuel usage. A Saturn 1.9 liter 4-cylinder engine was selected as a base powerplant. A control system that allows closed-loop optimization of both fuel delivery and spark timing was developed. Stock performance and emissions of the engine, as well as performance and emissions with the new controller on gasoline and CNG, have been documented. CNG operation in an engine designed for gasoline results in power loss because of the lower volumetric efficiency with gaseous fuel use, yet such an engine does not take advantage of the higher knock resistance of CNG. It is the goal of this research to use the knock resistance of CNG to recover the associated power loss. The two methods considered for this include turbocharging with a variable boost wastegate and raising the compression ratio while employing variable valve timing.

In order to obtain meaningful analyses of exhaust gas emissions and fuel economy for a heavy duty vehicle from a chassis dynamometer, the accurate simulation of road load characteristics is crucial. The adjusted amount of power to be absorbed by the chassis dynamometer during road driving of the tested vehicle needs to be calculated. In this paper, the performance of the chassis dynamometer under transient load cycle operations is discussed and the transient response of the power absorption system is presented. In addition, the design criteria of the chassis dynamometer used to test heavy duty vehicles under steady and transient load is described.

A heavy-duty engine testing project involving Cummins Engine Company, Southwest Research Institute (SwRI), and West Virginia University (WVU) has been completed. This project evaluated the transient exhaust gas emissions rate of Cummins N-14 heavy-duty diesel engines converted to natural gas. Three heavy-duty N-14 diesel engines were converted to run on natural gas using a lean burn strategy by SwRI and are in field service in Santa Barbara Air Pollution Control District (SBAPCD). Two of the engines were tested under a steady-state cycle that simulates the U.S. heavy-duty transient cycle. The third engine was tested at the WVU Engine Research Laboratory following the U.S. Federal Test Procedure (FTP). However, at WVU, lean burn combustion strategy was shifted rich of stoichiometric during idling time of the FTP test. This may have caused the engine to produce more total hydrocarbons (THC) and carbon monoxide (CO).

The paper captures the recent events in relation with the Volkswagen (VW) Emissions Scandal and addresses the impact of this event on the future of power train development. The paper analyses the impact on the perspectives of the internal combustion engine, the battery based electric car and the hydrogen based technology. The operation of the United States Environmental Protection Agency (EPA), VW and the United States prosecutor, sparked by the action of the International Council on Clean Transportation (ICCT) is forcing the Original Equipment Manufacturers (OEM) towards everything but rationale immediate transition to the battery based electric mobility. This transition voids the value of any improvement of the internal combustion engine (ICE), especially in the lean burn, compression ignition (CI) technology, and of a better hybridization of powertrains, both options that have much better short term perspectives than the battery based electric car.

Heavy-duty diesel engines (HDDE), because of their widespread use and reputation of expelling excessive soot, have frequently been held responsible for excessive amounts of overall environmental particulate matter (PM). PM is a considerable contributor to air pollution, and a subject of primary concern to health and regulatory agencies worldwide. The U.S. Environmental Protection Agency (EPA) has provided PM emissions regulations and standards of measurement techniques since the 1980's. PM standards set forth by the EPA for HDDEs are based only on total mass, instead of size and/or concentration. The European Union adopted a particle number emission limit, and it may influence the U.S. EPA to adopt particle number or size limits in the future. The purpose of this research was to study the effects biodiesel blended fuel and cetane improvers have on particle size and number.

An alternative fuel that has demonstrated considerable potential in reducing emissions and crude oil dependence is compressed natural gas (CNG). A dedicated CNG vehicle suffers from the lack of an adequate number of fueling stations and the poor range limited by CNG storage technology. A vehicle capable of operating on either gasoline or natural gas allows alternative fuel usage without sacrificing vehicle range and mobility. Although many such bi-fuel vehicles are in existence, historically they have employed older engine designs and made compromises in engine control parameters that can degrade performance relative to gasoline and increase emissions. A modern production engine, a 1992 Saturn 1.9 liter 16 valve powerplant, is being optimized for operation on each fuel to realize the full potential of CNG in a bi-fuel system. CNG operation in an engine designed for gasoline typically suffers from reduced power, due in part to displacement of air by gaseous fuel.

The Diesel Emission Control - Sulfur Effects (DECSE) program is a joint U.S. government/industry program that studies the impact of diesel sulfur levels on four types of emission control systems. One type of system, Diesel Particulate Filters (DPF), removes particulate matter (PM) from the exhaust stream by collection on a filter. The critical operating issue for DPF technology is the cleaning or regeneration of the control device (by oxidation of the collected PM) to prevent plugging. However, oxidation of sulfur in the exhaust forms sulfates, which are measured as PM. Two types of tests are conducted to evaluate the impacts of fuel sulfur on DPF performance: (1) emissions tests for PM components and gases, and (2) experiments to measure the effect of fuel sulfur on the regeneration temperature required by the filter devices.

Growing concern over ground-level ozone and its role in smog formation has resulted in extensive investigation into identifying ozone sources. Motor vehicle exhaust, specifically oxides of nitrogen and hydrocarbons, have been identified as major ozone precursors in urban areas. Past research has concentrated on assessing the impact of emissions from gasoline fueled light duty vehicles. However, little work has been done on identifying ozone precursors from medium and heavy duty diesel fueled vehicles. This paper presents the results of testing performed on a Navistar T 444E 190 horsepower diesel engine which is certified as a light/heavy-duty emissions classification and is used in medium duty trucks up to 11,800 kg (26,000 lb) GVW. Regulated emissions and speciated hydrocarbon emissions were collected using a filter, bag and Tenax adsorption cartridges for both steady state and transient engine operation.

This paper presents results from a study on speciation of the emission profiles and on the ozone forming potential of heavy-duty diesel exhaust under steady state engine operation. Very limited attempts have been made at determining the ozone forming potential of heavy duty diesel exhaust emissions. In this study a proportional sample of the dilute exhaust was drawn from a CFV-CVS system using a temperature controlled sampling line. The particulate matter was collected on a 70 mm Teflon coated glass fiber filter (TX40HI20WW), the semi-volatiles on XAD-2 copolymer resin and volatiles in Tedlar bags. The samples were analyzed by gas chromatography after conditioning and chemical extractions. The initial phase of the study was directed towards developing techniques and establishing protocols to determine the ozone forming potential of heavy-duty diesel exhaust. A pre-chamber naturally aspirated engine was tested on steady-state modes 1, 3, 5, 7 and 8 of the ISO 8 mode cycle.

An electrochemical cell is presented which reduces NOx emissions from a vehicle fueled by dedicated natural gas. The cell is comprised of a honeycomb shaped ceramic which is chemically coated with an electrically conductive material in two distinct regions which serve as electrodes such that, with the application of a voltage potential, a cathode and anode are formed. As the exhaust gas flows through the inner channels of the cell, the electrochemical reduction of NOx at the cathode yields nitrogen gas and oxide ions. The nitrogen continues to flow through the cell while the oxide ions dissolve in the solid electrolyte. At the anodic zone, oxide ions are converted to oxygen gas. The pressure drop across the cell was experimentally measured to insure that the back pressure created by the cell does not create a significant reduction in the efficiency of the engine.

Techniques have been developed to sample and speciate dilute heavy duty diesel exhaust to determine the specific reactivities and the ozone forming potential. While the Auto/Oil Air Quality Improvement Research Program (AQIRP) has conducted a comprehensive investigation to develop data on potential improvements in vehicle emissions and air quality from reformulated gasoline and various other alternative fuels. However, the development of sampling protocols and speciation of heavy duty diesel exhaust is still in its infancy [1, 2, 3, 4, 5 and 6]. This paper focuses on the first phase of the heavy duty diesel speciation program, that involves the development of a unique set of sampling protocols for the gas phase, semi-volatile and particulate matter from the exhaust of engines operating on different types of diesel fuel. Effects of sampling trains, sampling temperatures, semi-volatile adsorbents and driving cycles are being investigated.

Results of a research effort directed towards identifying and measuring the genotoxic properties of respirable particulate matter involved in mining exposures, especially those which may synergistically affect genotoxic hazard, are presented. Particulate matter emissions from a direct injection diesel engine have been sampled and assayed to determine the genotoxic potential as a function of engine operating conditions. Diesel exhaust from a Caterpillar 3304 diesel engine, representative of the ones found in underground mines, rated 100 hp at 2200 rpm is diluted in a multi-tube mini-dilution tunnel and the particulate matter is collected on 70 mm fluorocarbon coated glass fiber filters as well as on 8″ x 10″ hi-volume filters. A six mode steady state duty cycle was used to relate engine operating conditions to the genotoxic potential.

Selective Catalytic Reduction (SCR), using urea injection, is being examined as a method for substantial reduction of oxides of nitrogen (NOx) for diesel engines, but the urea injection rates must be controlled to match the NOx production which may need to be predicted during open loop control. Unfortunately NOx is usually measured in the laboratory using a full-scale dilution tunnel and chemiluminescent analyzer, which cause delay and diffusion (in time) of the true manifold NOx concentration. Similarly, delay and diffusion of measurements of all emissions cause the task of creating instantaneous emissions models for vehicle simulations more difficult. Data were obtained to relate injections of carbon dioxide (CO2) into a tunnel with analyzer measurements. The analyzer response was found to match a gamma distribution of the input pulse, so that the analyzer output could be modeled from the tunnel CO2 input.

Relationships between diesel particulate matter (PM) mass and gaseous emissions mass produced by engines have been explored to determine whether any gaseous species may be used as surrogates to infer PM quantitatively. It was recognized that sulfur content of fuel might independently influence PM mass, since PM historically is composed of elemental carbon, organic carbon, sulfuric acid, ash and wear particles. Previous research has suggested that PM may be correlated with carbon monoxide (CO) for an engine that is exercised through a variety of speed and load cycles, but that the correlation does not extend to a group of engines. Large databases from the E-55/59 and Gasoline/Diesel PM Split programs were employed, along with the IBIS bus emissions database and several additional data sets for on- and off-road engines to examine possible relationships.

Concern over dwindling oil supplies has led to the adoption of alternate fuels to power fleet vehicles. However, during the interim period when alternate fuel supply stations are few and far between, dual fuel engines prove a necessity. In the light duty arena, these engines are typically gasoline engines modified to accommodate compressed natural gas (CNG) as an alternate fuel, but they are seldom optimized with both fuels in mind. A Saturn 1.9 liter 4 cylinder dual overhead cam engine was selected as a base for developing an optimized gasoline/CNG powerplant. Baseline data on power and steady state emissions (CO2, CO, NOx, HC) were found using the standard Saturn controller. In addition to monitoring standard sensor measurements, real-time pressure traces were taken for up to 256 cycles using a modified head with embedded PCB piezoelectric pressure transducers.

Miscibility, water tolerance, cloud point, and flash point data are presented for seven candidate diesel fuel oxygenates: dipentyl ether, dibutoxymethane, 2-ethoxyethyl ether, diethyl maleate, tripropylene glycol monomethyl ether, dibutyl maleate, and glycerol tributrate. These oxygenates were blended with three different diesel fuels: an oil sands diesel, an ultra-low sulfur diesel, and a Fischer-Tropsch diesel. Blend levels included 0, 5, 10, 30, and 100 % oxygenate. Properties were measured at temperatures of -30, -15, 0, 15, and 30 C.

Natural Gas engines are viewed as an alternative to diesel power in the quest to reduce heavy duty vehicle emissions in polluted urban areas. In particular, it is acknowledged that natural gas has the potential to reduce the inventory of particulate matter, and this has encouraged the use of natural gas engines in transit bus applications. Extensive data on natural gas and diesel bus emissions have been gathered using two Transportable Heavy Duty Vehicle Emissions Testing Laboratories, that employ chassis dynamometers to simulate bus inertia and road load. Most of the natural gas buses tested prior to 1997 were powered by Cummins L-10 engines, which were lean-burn and employed a mechanical mixer for fuel introduction. The Central Business District (CBD) cycle was used as the test schedule.