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A program has been completed to evaluate ultra-low sulfur diesel fuels and passive diesel particulate filters (DPFs) in truck and bus fleets operating in southern California. The fuels, ECD and ECD-1, are produced by ARCO (a BP Company) and have less than 15 ppm sulfur content. Vehicles were retrofitted with two types of catalyzed DPFs, and operated on ultra-low sulfur diesel fuel for over one year. Exhaust emissions, fuel economy and operating cost data were collected for the test vehicles, and compared with baseline control vehicles. Regulated emissions are presented from two rounds of tests. The first round emissions tests were conducted shortly after the vehicles were retrofitted with the DPFs. The second round emissions tests were conducted following approximately one year of operation. Several of the vehicles retrofitted with DPFs accumulated well over 100,000 miles of operation between test rounds.

Transit agencies across the United States operate bus fleets primarily powered by diesel, natural gas, and hybrid drive systems. Passenger loading affects the power demanded from the engine, which in turn affects distance-specific emissions and fuel consumption. Analysis shows that the nature of bus activity, taking into account the idle time, tire rolling resistance, wind drag, and acceleration energy, influences the way in which passenger load impacts emissions. Emissions performance and fuel consumption from diesel and natural gas powered buses were characterized by the West Virginia University (WVU) Transportable Emissions Testing Laboratory. A comparison matrix for all three bus technologies included three common driving cycles (the Braunschweig Cycle, the OCTA Cycle, and the ADEME-RATP Paris Cycle). Each bus was tested at three different passenger loading conditions (empty weight, half weight, and full weight).

The effects of fuel composition on emissions levels from compression ignition engines can be profound, and this understanding has led to mandated reductions in both sulfur and aromatic content of automotive diesel fuels. A Navistar T444E (V8, 7.3 liter) engine was installed on an engine dynamometer and subjected to transient emissions measurement using a variety of fuels, namely federal low sulfur pump diesel; California pump diesel; Malaysian Fischer-Tropsch fuel with very low sulfur and aromatic content; various blends of soy-derived biodiesel; a Fischer-Tropsch fuel with very low sulfur and 10% aromatics; and the same Fischer-Tropsch fuel with 10% isobutanol by volume. The biodiesel blends showed their ability to reduce particulate matter, but at the expense of increasing oxides of nitrogen (NOx), following the simple argument that cetane enhancement led to earlier ignition. However, the Fischer-Tropsch fuels showed their ability to reduce all of the regulated emissions.

Reactivity controlled compression ignition (RCCI) is a form of dual-fuel combustion that exploits the reactivity difference between two fuels to control combustion phasing. This combustion approach limits the formation of oxides of nitrogen (NOX) and soot while retaining high thermal efficiency. The research presented herein was performed to determine the influences that high reactivity (diesel) fuel properties have on RCCI combustion characteristics, exhaust emissions, fuel efficiency, and the operable load range. A 4-cylinder, 1.9 liter, light-duty compression-ignition (CI) engine was converted to run on diesel fuel (high reactivity fuel) and compressed natural gas (CNG) (low reactivity fuel). The engine was operated at 2100 revolutions per minute (RPM), and at two different loads, 3.6 bar brake mean effective pressure (BMEP) and 6 bar BMEP.

Pollutants are a major issue of diesel engines, with oxides of nitrogen (NOx) and airborne total particulate matter (TPM) of primary concern. Current emission standards rely on laboratory testing using an engine dynamometer with a standard test procedure. Results are reported as an integrated value for emissions from a transient set of engine speed and load conditions over a length of time or a set of prescribed speed-load points. To be considered a valid test by the US EPA, the measured engine speed and load are compared to the prescribed engine speed and load and must be within prescribed regression limits.

With the advent of stricter vehicle emission standards, the improvement of three way catalyst performance and durability remains a pressing issue. A critical consideration in catalyst design is the potential for variations in fuel sulfur levels to have a significant impact on the ability to reach TLEV, LEV, and ULEV emission levels. As a result, a better understanding of the role of PGM composition in the interplay between thermal durability and sulfur tolerance is required. Three way catalysts representative of standard Pd-only, Pd/Rh and Pt/Rh formulations were studied over a variety of aging and evaluation conditions. The parameters investigated included aging temperature, air fuel ratio and sulfur level. Evaluations were performed on a 1994 TLEV vehicle using different sulfur level fuels. The effect of PGM loading was also included within the study.

The performance characteristics of a commercial lean-NOX trap catalyst were evaluated between 200 and 500°C, using H2, CO, and a mixture of both H2 and CO as reductants before and after different high-temperature aging steps, from 600 to 750°C. Tests included NOX reduction efficiency during cycling, NOX storage capacity (NSC), oxygen storage capacity (OSC), and water-gas-shift (WGS) and NO oxidation reaction extents. The WGS reaction extent at 200 and 300°C was negatively affected by thermal degradation, but at 400 and 500°C no significant change was observed. Changes in the extent of NO oxidation did not show a consistent trend as a function of thermal degradation. The total NSC was tested at 200, 350 and 500°C. Little change was observed at 500°C with thermal degradation but a steady decrease was observed at 350°C as the thermal degradation temperature was increased.

As a part of the FutureTruck 2000 advanced technology student vehicle competition sponsored by the US Department of Energy and General Motors, West Virginia University has converted a full-size sport utility vehicle into a high fuel efficiency, low emissions vehicle. The environmental impact of the Chevrolet Suburban SUV, in terms of both greenhouse gas emissions and exhaust emissions, was reduced through hybridization without losing any of the functionality and utility of the base vehicle. The approach taken was one of using a high efficiency, state-of-the-art direct injection, turbocharged diesel engine coupled to a high output electric traction motor for power assist and to recover regenerative braking energy. The vehicle employs a state-of-the-art combination lean NOx catalyst, oxidation catalyst and particulate filter to ensure low exhaust emissions.

Progress made in reducing engine-out particulate emissions has prompted a revival in the design of flow-through oxidation catalysts for diesel engine applications. Effort in this area has focused primarily in the area of SOF control for the further reduction of particulate emissions. The work reported here covers some of the catalyst design parameters important for SOF and gas phase pollutant control. This is illustrated with both laboratory reactor and engine evaluation data for several formulary and operating parameters. Platinum-based catalysts are shown to be generally the most active, but they require treatments or additives to reduce the inherently high activity of platinum for the oxidation of SO2 present in the exhaust. The effect of additives and their loading on the oxidation activity of Pt/alumina for HC, CO, SOF and SO2 oxidation is discussed in detail and additives are identified which reduce SO2 oxidation with minimal effect on HC, CO or SOF oxidation activity.

As part of the 1998 Consent Decrees concerning alternative ignition strategies between the six settling heavy-duty diesel engine manufacturers and the United States government, the engine manufacturers agreed to perform in-use emissions measurements of their engines. As part of the Consent Decrees, pre- (Phase III, pre-2000 engines) and post- (Phase IV, 2001 to 2003 engines) Consent Decree engines used in over-the-road vehicles were tested to examine the emissions of oxides of nitrogen (NOx) and carbon dioxide (CO2). A summary of the emissions of NOx and CO2 and fuel consumption from the Phase III and Phase IV engines are presented for 30 second “Not-to-Exceed” (NTE) window brake-specific values. There were approximately 700 Phase III tests and 850 Phase IV tests evaluated in this study, incorporating over 170 different heavy duty diesel engines spanning 1994 to 2003 model years. Test vehicles were operated over city, suburban, and highway routes.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.

Selective NOx recirculation (SNR), involving adsorption, selective external recirculation and decomposition of the NOx by the combustion process, is itself a promising technique to abate NOx emissions. Three types of materials containing Ba: barium aluminate, barium tin perovskite and barium Y-zeolites have been developed to adsorb NOx under lean-burn or Diesel conditions, with or without the presence of S02. All these materials adsorb NO2 selectively (lean-burn conditions), and store it as nitrate/nitrite species. The desorption takes place by decomposition of these species at higher temperatures. Nitrate formation implies also sulfate formation in the presence of SO2 and SO3, while the NO2/SO2 competition governs the poisoning of such catalysts.

The SNR-technique is a new NOx aftertreatment system for lean burn gasoline and diesel applications. The objective of SNR is NOx removal from lean exhaust gas by NOx adsorption and subsequent selective external recirculation and decomposition of NOx in the combustion process. The SNR-project is composed of two major parts. Firstly the development of NOx adsorbents which are able to store large quantities of NOx in lean exhaust gas, and secondly the NOx decomposition by the combustion process. Emphasis of this paper is the investigation of NOx reduction in the combustion process, including experimental investigation and numerical simulation. The NOx decomposition process has been proven in diesel and lean-burn gasoline engines. Depending on the type of engine NOx-conversion rates up to 90 % have been observed. Regarding the complete SNR-system, including the efficiency of the adsorbing material and the NOx decomposition by the combustion, a NOx removal of more than 50% is achievable.

Beginning 2007, heavy-duty engine certification would require that in-use emissions from vehicles be measured under ‘real-world’ operating conditions using on-board measurement devices. An on-board portable emissions measurement system called Mobile Emissions Measurement System (MEMS) was developed at West Virginia University (WVU) to record in-use, continuous and brake-specific emissions from heavy-duty diesel-powered vehicles. The objective of this paper is to present a preliminary development of a test data quality assurance methodology for emissions measured using the any portable emissions measurement system (PEMS). The first stage of the methodology requires ensuring the proper operation of the different sensors and transducers during data collection. The second stage is data synchronization and pre-processing. The next stage is systematic checking of possible errors from transducers and sensors.

The temporary deactivation of the selective catalytic reduction (SCR) device due to malfunction requires the engine control to engage multiple engine-out calibrations. Further, it is expected that emitted particles will be different in composition, size and morphology when an engine, which meets the 2010 particulate matter (PM) gravimetric limits, is programmed with multiple maps. This study investigated the correlation between SCR-out/engine-out PM emissions from an 11-liter Volvo engine. Measurement of PM concentrations and size distributions were conducted under steady state and transient cycles. Ion Chromatograph analysis on gravimetric filters at the SCR-out has revealed the presence of sulfates. Two different PM size-distributions were generated over a single engine test mode in the accumulation mode region with the aid of a design of experiment (DOE) tool. The SCR-out PM size distributions were found to correlate with the two engine-out distributions.

The effect of changing catalyst precious metal ratios and loadings on close coupled catalytic converter efficiencies has been studied. The three precious metals were platinum, palladium and rhodium. The specific matrix used for the development of response surface models is a central composite design and provides the capability of visually optimising the precious metal loadings. Catalysts were evaluated using perturbed scans. lightoff curves from the dynamometer aged, and vehicle emission tests. These scans show percent conversion efficiencies of the three legislated gases; HC, CO and NOx, over a range of Air Fuel Ratios (λ). Whilst lean and rich lightoff curves provide indications of conversion efficiencies at varying temperatures. Prior to testing the catalysts were aged, using an accelerated dynamometer ageing process, to 80K simulated kilometres. The catalysts were then fitted to a vehicle and chassis roll emission tests conducted.

In-service 1994-2003 heavy-duty trucks were acquired by West Virginia University (WVU), equipped with the WVU Mobile Emissions Measurement System (MEMS) to measure on-road NOx, and driven on road routes near Sabraton, West Virginia, and extending up to Washington, PA to obtain real-world oxides of nitrogen (NOx) emissions data on highways and local roads. The MEMS measured 5Hz NOx, and load was obtained from the electronic control unit. Trucks were loaded to about 95% of their gross vehicle weights. Emissions in g/mi and g/bhp-hr were computed over the various road routes. In addition, some of the trucks were tested 1 to 2 years later to determine emission changes that may have occurred for these trucks. Emission results varied significantly over the different road routes due to different speeds, driving patterns, and road grades.

With the purpose of reducing emission level while maintaining the high torque character of diesel engine, various solutions have been proposed by researchers over the world. One of the most attractive methods is to use dual fuel technique with premixed gaseous fuel ignited by a relatively small amount of diesel. In this study, Methane (CH4), which is the main component of natural gas, was premixed with intake air and used as the main fuel, and diesel fuel was used as ignition source to initiate the combustion. By varying the proportion of diesel and CH4, the combustion and emissions characteristics of the dual fuel (diesel/CH4) combustion system were investigated. Different cases of CFD studies with various concentration of CH4 were carried out. A validated 3D quarter chamber model of a single cylinder engine (diesel fuel only) generated by using AVL Fire ESE was modified into dual fuel mode in this study.

Due to tightening emission legislations, both within the US and Europe, including concerns regarding greenhouse gases, next-generation combustion strategies for internal combustion diesel engines that simultaneously reduce exhaust emissions while improving thermal efficiency have drawn increasing attention during recent years. In-cylinder combustion temperature plays a critical role in the formation of pollutants as well as in thermal efficiency of the propulsion system. One way to minimize both soot and NOx emissions is to limit the in-cylinder temperature during the combustion process by means of high levels of dilution via exhaust gas recirculation (EGR) combined with flexible fuel injection strategies. However, fuel chemistry plays a significant role in the ignition delay; hence, influencing the overall combustion characteristics and the resulting emissions.