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Technical Paper

Validation Methods for Lean NOx Trap Mount Designs

2006-10-31
2006-01-3567
A unique validation method is proposed for mount designs of Lean NOx Traps (LNT's), in which characteristic curves of failure points as functions of thermal cycles and vibration amplitudes are generated. LNT's are one of the several new types of emissions control devices applied to Diesel Exhaust Systems, and they reduce the amount of NOx through chemical adsorption. Desulfation must occur nearly every hour, which involves raising the inlet gas temperature of the LNT to around 700°C to “burn off” sulfur from the catalyst, which otherwise would decrease its catalytic activity. This temperature is held for several minutes, and its cyclic occurrence has a negative effect on the long-term performance of the support mat, a major component of its mount design. As substrate temperatures increase, shell temperatures do as well, and thermal growth differences between the ceramic substrate and metallic shell cause the gap between them, which is filled by the support mat, to increase.
Technical Paper

Transient Performance of an HC LNC Aftertreatment System Applying Ethanol as the Reductant

2012-09-24
2012-01-1957
As emissions regulations around the world become more stringent, emerging markets are seeking alternative strategies that align with local infrastructures and conditions. A Lean NOx Catalyst (LNC) is developed that achieves up to 60% NOx reduction with ULSD as its reductant and ≻95% with ethanol-based fuel reductants. Opportunities exist in countries that already have an ethanol-based fuel infrastructure, such as Brazil, improving emissions reduction penetration rates without costs and complexities of establishing urea infrastructures. The LNC performance competes with urea SCR NOx reduction, catalyst volume, reductant consumption, and cost, plus it is proven to be durable, passing stationary test cycles and adequately recovering from sulfur poisoning. Controls are developed and applied on a 7.2L engine, an inline 6-cylinder non-EGR turbo diesel.
Technical Paper

The Role of CFD Combustion Simulation in Diesel Burner Development

2009-10-06
2009-01-2878
Diesel burners introduce combustion of diesel fuel to raise exhaust gas temperature to Diesel Oxidization Catalyst (DOC) light-off or Diesel Particulate Filter (DPF) regeneration conditions, thereby eliminating the need of engine measures such as post-injections. Such diesel combustion requirement nevertheless poses challenges to burner development especially in combustion control and risk mitigation of DPF material failure. In particular, burner design must satisfy good soot distribution and heat distribution at DPF front face after meeting minimum requirements of ignition, heat release, and backpressure. In burner development, Computational Fluid Dynamics (CFD) models have been developed based on commercial codes for burner thermal and flow management with capability of predicting comprehensive physical and chemical phenomena including turbulence induced mixing, fuel injection, fuel droplet transport, diesel combustion, radiation, conjugate heat transfer and etc.
Journal Article

Secondary Fuel Injection Layout Influences on DOC-DPF Active Regeneration Performance

2013-09-24
2013-01-2465
Catalysts and filters continue to be applied widely to meet particulate matter regulations across new and retrofit diesel engines. Soot management of the filter continues to be enhanced, including regeneration methodologies. Concerns regarding in-cylinder post-injection of fuel for active regeneration increases interests in directly injecting this fuel into the exhaust. Performance of secondary fuel injection layouts is discussed, and sensitivities on thermal uniformity are measured and analyzed, providing insight to packaging challenges and methods to characterize and improve application designs. Influences of end cone geometries, mixers, and injector mounting positions are quantified via thermal distribution at each substrate's outlet. A flow laboratory is applied for steady state characterization, repeated on an engine dynamometer, which also provides transient results across the NRTC.
Technical Paper

SOLID SCR®: Demonstrating an Improved Approach to NOx Reduction via a Solid Reductant

2011-09-13
2011-01-2207
Stringent global emissions legislation demands effective NOx reduction strategies, particularly for the aftertreatment, and current typical liquid urea SCR systems achieve efficiencies greater than 90% [1]. However, with such high-performing systems comes the trade-off of requiring a tank of reductant (urea water solution) to be filled regularly, usually as soon as the fuel fillings or as far as oil changes. Advantages of solid reductants, particularly ammonium carbamate, include greater ammonia densities, enabling the reductant refill interval to be extended several multiples versus a given reductant volume of urea, or diesel exhaust fluid (DEF) [2]. An additional advantage is direct gaseous ammonia dosing, enabling reductant injection at lower exhaust temperatures to widen its operational coverage achieving greater emissions reduction potential [3], as well as eliminating deposits, reducing mixing lengths, and avoiding freeze/thaw risks and investments.
Journal Article

Real Time Implementation of DOC-DPF Models on a Production-Intent ECU for Controls and Diagnostics of a PM Emission Control System

2009-10-06
2009-01-2904
This paper describes the joint development by Tenneco and Pi Shurlok of a complete diesel engine aftertreatment system for controlling particulate matter emissions. The system consists of a DOC, DPF, sensors, controller and an exhaust fuel injection system to allow active DPF regeneration. The mechanical components were designed for flow uniformity, low backpressure and component durability. The overall package is intended as a complete PM control system solution for OEMs, which does not require any significant additions to the OEM's engine control strategies and minimizes integration complexity. Thus, to make it easier to adapt to different engine platforms, ranging from small off-road vehicle engines to large locomotive engines, model-based control algorithms were developed in preference to map-based controls.
Technical Paper

Passive Regeneration Response Characteristics of a DPF System

2013-04-08
2013-01-0520
This study investigates the passive regeneration behavior of diesel particulate filters (DPFS) with various PGM loadings under different engine operating conditions. Four wall-flow DPFs are used; one uncoated and three wash-coated with low, medium, and high PGM loadings, with and without an upstream diesel oxidation catalyst (DOC). DPFs with variable pre-soot loads are evaluated at two steady state temperatures (300°C and 400°C), as well as across three levels of transients based on the 13-mode ESC cycle. Passive regeneration rates are calculated based on pre and post soot gravimetric measurements along with accumulated soot mass rates for specified exhaust mass flow rates and temperatures. Results illustrate the effect of temperature, NO₂ content, and soot loading on passive regeneration without upstream DOCs or DPF wash coatings.
Technical Paper

Overview of Large Diesel Engine Aftertreatment System Development

2012-09-24
2012-01-1960
The introduction of stringent EPA 2015 regulations for locomotive / marine engines and IMO 2016 Tier III marine engines initiates the need to develop large diesel engine aftertreatment systems to drastically reduce emissions such as SOx, PM, NOx, unburned HC and CO. In essence, the aftertreatment systems must satisfy a comprehensive set of performance criteria with respect to back pressure, emission reduction efficiency, mixing, urea deposits, packaging, durability, cost and others. Given multiple development objectives, a systematic approach must be adopted with top-down structure that addresses top-level technical directions, mid-level subsystem layouts, and bottom-level component designs and implementations. This paper sets the objective to provide an overview of system development philosophy, and at the same time touch specific development scenarios as illustrations.
Technical Paper

Optimization of a Urea SCR System for On-Highway Truck Applications

2010-10-05
2010-01-1938
In order to satisfy tightening global emissions regulations, diesel truck manufacturers are striving to meet increasingly stringent Oxides of Nitrogen (NOx) reduction standards. The majority of heavy duty diesel trucks have integrated urea SCR NOx abatement strategies. To this end, aftertreatment systems need to be properly engineered to achieve high conversion efficiencies. A EuroV intent urea SCR system is evaluated and failed to meet NOx conversion targets with severe urea deposit formation. Systematic enhancements of the design have been performed to enable it to meet targets, including emission reduction efficiency via improved reagent mixing, evaporation, distribution, back pressure, and removing of urea deposits. Multiple urea mixers, injector mounting positions and various system layouts are developed and evaluated, including both CFD analysis and full scale laboratory tests.
Technical Paper

Mixer Development for Urea SCR Applications

2009-10-06
2009-01-2879
2010 and future EPA regulations introduce stringent Oxides of Nitrogen (NOx) reduction targets for diesel engines. Selective Catalytic Reduction (SCR) of NOx by Urea over catalyst has become one of the main solutions to achieve these aggressive reductions. As such, urea solution is injected into the exhaust gas, evaporated and decomposed to ammonia via mixing with the hot exhaust gas before passing through an SCR catalyst. Urea mixers, in this regard, are crucial to ensure successful evaporation and mixing since its liquid state poses significant barriers, especially at low temperature conditions that incur undesired deposits. Intensive efforts have been taken toward developing such urea mixers, and multiple criteria have been derived for them, mainly including NOx reduction efficiency and uniformity. In addition, mixers must also satisfy other requirements such as low pressure drop penalty, mechanical strength, material integrity, low cost, and manufacturability.
Journal Article

Investigation of SCR Catalysts for Marine Diesel Applications

2017-03-28
2017-01-0947
Evolving marine diesel emission regulations drive significant reductions of nitrogen oxide (NOx) emissions. There is, therefore, considerable interest to develop and validate Selective Catalytic Reduction (SCR) converters for marine diesel NOx emission control. Substrates in marine applications need to be robust to survive the high sulfur content of marine fuels and must offer cost and pressure drop benefits. In principle, extruded honeycomb substrates of higher cell density offer benefits on system volume and provide increased catalyst area (in direct trade-off with increased pressure drop). However higher cell densities may become more easily plugged by deposition of soot and/or sulfate particulates, on the inlet face of the monolithic converter, as well as on the channel walls and catalyst coating, eventually leading to unacceptable flow restriction or suppression of catalytic function.
Technical Paper

Integration of Diesel Burner for Large Engine Aftertreatment using CFD

2010-10-05
2010-01-1946
Diesel burners recently have been used in Diesel Particulate Filter (DPF) regeneration process, in which the exhaust gas temperature is raised through the combustion process to burn off the soot particles. The feasibility of such process using the burner in large diesel applications is investigated along with a mixer and DPF. For such applications, only partial flow of the exhaust stream is fed into the burner and the resulting hot flow from combustion process is then mixed with the rest of the main stream. The amount of flow into the burner plays a vital role in overall system performance as it determines the amount of hot gas needed for Diesel Oxidation Catalyst (DOC) light-off (to facilitate DPF regeneration) and also oxygen amount needed for secondary combustion. A passive valve plate design is proposed for such flow split applications for the burner.
Technical Paper

Evaluation of a DPF Regeneration System and DOC Performance Using Secondary Fuel Injection

2009-10-06
2009-01-2884
An active diesel particulate filter (DPF) regeneration system is evaluated, which applies secondary fuel injection (SFI) directly within the exhaust system upstream of a diesel oxidation catalyst (DOC). Diesel fuel is oxidized in the presence of a proprietary catalyst system, increasing exhaust gas temperatures in an efficient and controlled manner, even during low engine-out gas temperatures. The exotherms produced by secondary fuel injection (SFI) have been evaluated using two different DOC volumes and platinum catalyst loadings. DOC light-off temperatures were measured using SFI under steady-state conditions on an engine dynamometer. A ΔT method was used for the light-off temperature measurements – i.e., the minimum DOC inlet gas temperature at which the exothermic reaction increases the outlet gas temperature 20°C or greater than the inlet temperature.
Technical Paper

Development of Urea SCR Systems for Large Diesel Engines

2011-09-13
2011-01-2204
EPA 2015 Tier IV emission requirements pose significant challenges to large diesel engine after treatment system development with respect to reducing exhaust emissions including HC, CO, NOx and Particulate Matter (PM). For a typical locomotive, marine or stationary generator engine with 8 to 20 cylinders and 2500 to 4500 BHP, the PM reduction target could be over 90% and NOx reduction target over 75% for a wide range of running conditions. Generally, HC, CO and PM reductions can be achieved by combining DOC, cDPF and active regeneration systems. NOx reduction can be achieved by injecting urea as an active reagent into the exhaust stream to allow NOx to react with ammonia per SCR catalysts, as the mainstream approach for on-highway truck applications.
Journal Article

Development of Common Rail and Manifold Fluid Delivery Systems for Large Diesel Engine Aftertreatement

2012-09-24
2012-01-1961
EPA 2015 Tier IV emission requirements pose significant challenges to large diesel engine aftertreatment system (EAS) development aimed at reducing exhaust emissions such as NOx and PM. An EAS has three primary subsystems, Aftertreatment hardware, controls and fluid delivery. Fluid delivery is the subsystem which supplies urea into exhaust stream to allow SCR catalytic reaction and/or periodic DOC diesel dosing to elevate exhaust temperatures for diesel particulate filter (DPF) soot regeneration. The purpose of this paper is to discuss various aspects of fluid delivery system development from flow and pressure perspective. It starts by giving an overview of the system requirements and outlining theoretical background; then discusses overall design considerations, injector and pump selection criteria, and three main injector layouts. Steady state system performance was studied for manifold layout.
Technical Paper

Design Improvements of Urea SCR Mixing for Medium-Duty Trucks

2013-04-08
2013-01-1074
To meet the 2010 diesel engine emission regulations, an aftertreatment system was developed to reduce HC, CO, NOx and soot. In NOx reduction, a baseline SCR module was designed to include urea injector, mixing decomposition tube and SCR catalysts. However, it was found that the baseline decomposition tube had unacceptable urea mixing performance and severe deposit issues largely because of poor hardware design. The purpose of this article is to describe necessary development work to improve the baseline system to achieve desired mixing targets. To this end, an emissions Flow Lab and computational fluid dynamics were used as the main tools to evaluate urea mixing solutions. Given the complicated urea spray transport and limited packaging space, intensive efforts were taken to develop pre-injector pipe geometry, post-injector cone geometry, single mixer design modifications, and dual mixer design options.
Technical Paper

DPF Regeneration Response: Coupling Various DPFs with a Thermal Regeneration Unit to Assess System Behaviors

2011-09-13
2011-01-2200
Diesel Particulate Filters (DPFs) have been successfully applied for several years to reduce Particulate Matter (PM) emissions from on-highway applications, and similar products are now also applied in off-highway markets and retrofit solutions. Most solutions are catalytically-based, necessitating minimum operating temperatures and demanding engine support strategies to reduce risks [1, 2, 3, 4, 5, 6, 7, 8]. An ignition-based thermal combustion device is applied with Cordierite and SiC filters, evaluating various DPF conditions, including effects of soot load, exhaust flow rates, catalytic coatings, and regeneration temperatures. System designs are described, including flow and temperature uniformity, as well as soot load distribution and thermal gradient response.
Technical Paper

Clean EGR for Gasoline Engines – Innovative Approach to Efficiency Improvement and Emissions Reduction Simultaneously

2017-03-28
2017-01-0683
External Exhaust Gas Recirculation (EGR) has been used on diesel engines for decades and has also been used on gasoline engines in the past. It is recently reintroduced on gasoline engines to improve fuel economy at mid and high engine load conditions, where EGR can reduce throttling losses and fuel enrichment. Fuel enrichment causes fuel penalty and high soot particulates, as well as hydrocarbon (HC) emissions, all of which are limited by emissions regulations. Under stoichiometric conditions, gasoline engines can be operated at high EGR rates (> 20%), but more than diesel engines, its intake gas including external EGR needs extreme cooling (down to ~50°C) to gain the maximum fuel economy improvement. However, external EGR and its problems at low temperatures (fouling, corrosion & condensation) are well known.
Technical Paper

CFD Optimization of Exhaust Manifold for Large Diesel Engine Aftertreatment Systems

2011-09-13
2011-01-2199
To meet EPA Tier IV large diesel engine emission targets, intensive development efforts are necessary to achieve NOx reduction and Particulate Matter (PM) reduction targets [1]. With respect to NOx reduction, liquid urea is typically used as the reagent to react with NOx via SCR catalyst [2]. Regarding to PM reduction, additional heat is required to raise exhaust temperature to reach DPF active / passive regeneration performance window [3]. Typically the heat can be generated by external diesel burners which allow diesel liquid droplets to react directly with oxygen in the exhaust gas [4]. Alternatively the heat can be generated by catalytic burners which enable diesel vapor to react with oxygen via DOC catalyst mostly through surface reactions [5].
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