Search Results

Use of biodiesel from non-edible vegetable oil as an alternative fuel to mineral diesel is attractive economically and environmentally. Diesel engines emit several harmful gaseous emissions and some of them are regulated worldwide, while countless others are not regulated. These unregulated species are associated with severe health hazards. Karanja biodiesel is a popular alternate fuel in South Asia and various governments are considering its large-scale implementation. Therefore it is important to study the possible adverse impact of this new alternate fuel. In this study, unregulated and regulated emissions were measured at varying engine speeds (1500, 2500 and 3500 rpm) for various engine loads (0%, 20%, 40%, 60%, 80% and 100% rated load) using 20% Karanja biodiesel blend (KB20) and diesel in a 4-cylinder 2.2L common rail direct injection (CRDI) sports utility vehicle (SUV) engine.

Condensed soot coming out of vehicular exhaust is commonly classified as organic carbon (OC) and elemental carbon (EC). OC can be directly emitted to the atmosphere in the particulate form (primary carbon) from the tailpipe or can be produced by gas-to-particle conversion process (secondary organic carbon, SOC). Under typical atmospheric dilution conditions, most of the semi-volatile material is present in the form of soot. SOC holds wider implications in terms of their adverse health and climate impact. Diesel exhaust is environmentally reactive and it has long been understood that the ambient interaction of exhaust hydrocarbons and NOx results in the formation of ozone and other potentially toxic secondary organic carbon species. The current emission norms look at the primary emissions from the engine exhaust. Also, research efforts are geared towards controlling the emissions of primary carbon.

Increased environmental awareness and depletion of resources are driving industry to develop alternative fuels that are environmentally more acceptable. Fatty acids esters (biodiesel) are known to be good alternative fuels. Due to economic reasons, the use of cheap raw materials for biodiesel production is preferred. In this case, ricebran oil, non-edible grade is used. Base catalyzed transesterification of ricebran oil is investigated and process parameters for ricebran biodiesel production are optimized. Various properties like viscosity, density, flash point, calorific value of biodiesel thus prepared are characterized as per ASTM D6751 and found comparable to mineral diesel. Steady state engine dynamometer test at 1800 rpm has been carried out to evaluate the performance and emission characteristics of a medium duty transportation DI diesel engine. Emission tests with all the fuel blends have also been carried out using European 13 MODE test (ECE R49).

Biodiesel (fatty acid methyl ester) is a non-toxic and biodegradable alternative fuel that is obtained from renewable sources. A major hurdle in the commercialization of biodiesel from virgin oil, in comparison to petroleum-based diesel, is its cost of production, primarily the raw material cost. Used cooking oils or waste cooking oils are economical sources for biodiesel production, which can help in commercialization of biodiesel. However, the products formed during cooking/frying (such as free fatty acids and various polymerized triglycerides) affect the transesterification reaction and the biodiesel properties. In present experimental investigations, wastecooking oil obtained from restaurant was used to produce biodiesel through transesterification process and the chemical kinetics of biodiesel production was studied. Biodiesel was blended with petroleum diesel in different proportions.

This experimental study was undertaken to investigate the use of vegetable oil derivatives to substitute mineral diesel fuel. Straight vegetable oils pose some problems like injector coking, carbon deposits etc., when used as a fuel in an engine. These problems are due to high viscosity, low volatility and polyunsaturated character of vegetable oils. Transesterified vegetable oil derivative called “biodiesel” appear to be most convenient way of utilizing vegetable oil as a substitute fuel in diesel engines. In present investigation, rice bran oil (non-edible) was transesterified to methyl ester and reaction conditions for transeterifcation process for rice bran oil were optimized. Various properties like viscosity, density, flash point of the biodiesel thus prepared are comparable to diesel and found to be in acceptable range as per ASTM norms (ASTM D6751). Experimental investigations were carried out on a four stroke, four cylinders, transportation DI diesel engine.

Environmental concerns have increased significantly world over in the past decade. Regulatory agencies are becoming increasingly concerned with particulate emissions as the health and environmental effects are getting understood better due to rapid development in instrumentation. Biodiesel is one of the most promising alternative diesel fuels, which is getting global acceptability among the automotive/ engine manufactures as well as users due to numerous benefits it offers over the conventional diesel. While much of literature is available on particulate emitted by diesel fuelled engine, little is known by particulate emissions from biodiesel fuelled compression ignition (CI) engine. This study concentrates on the characterization of particulate emissions from mineral diesel vis-à-vis biodiesel (B100) and its optimum blend (20%, B20) with mineral diesel.

Poor oxidation stability is the central problem associated with the commercial acceptance of the biodiesel. The EU standard (EN14214) specifies a minimum value of 6 h for biodiesel induction period at 110°C, measured with Rancimat instrument. Most of the freshly prepared biodiesel generally have lower induction periods than prescribed by the standards. Anti-oxidants are therefore added to enhance the oxidation/ storage stability of biodiesel. Oxidation is an exothermic process, and the reaction heat evolved makes it possible to use thermo gravimetric analysis (TGA). In the present study, the oxidation stability of methyl esters derived from Karanja oil and Neem oil, stabilized with anti-oxidant pyrogalol (PY) was studied by DSC. Onset temperature of freshly prepared Karanja biodiesel (KOME) and Neem biodiesel (NOME) was observed to be 148 and 153°C respectively. The stability increases with increasing anti-oxidant dosage.

Mono alkyl esters of long-chain fatty acids derived from renewable lipid feedstock, such as vegetable oils or animal fats, also known as biodiesel are well positioned to replace mineral diesel. The outstanding technical problem with biodiesel is that it is more susceptible to oxidation owing to its exposure to oxygen present in the air and high temperature. This happens mainly due to the presence of varying numbers of double bonds in the free fatty acid molecules. The chemical reactivity of esters can therefore be divided into oxidative and thermal instability, which can be determined by the amount and configuration of the olefinic unsaturation in the fatty acid chains. Many of the plant-derived fatty oils contain polyunsaturated fatty acids that are more prone to oxidation. Increasing production of biodiesel from vegetable oils (edible) places strain on food production, availability and price and leads to food versus fuel conflict.

Fuel atomization and air-fuel mixing processes play a dominant role on engine performance and emission characteristics in a direct injection compression ignition engine. Understanding of microscopic spray characteristics is essential to predict combustion phenomena. The present work investigated near nozzle flow and atomization characteristics of biodiesel fuels in a constant volume chamber. Waste cooking oil, Jatropha, and Karanja biodiesels were applied and the results were compared with those of conventional diesel fuel. The tested fuels were injected by a solenoid injector with a common-rail injection system. A high-speed camera with a long distance microscopic lens was utilized to capture the near nozzle flow. Meanwhile, Sauter mean diameter (SMD) was measured by a phase Doppler particle analyzer to compare atomization characteristics.

The interface between the piston rings and cylinder liner play an important role in total frictional losses and mechanical wear of internal combustion engine and is increasingly coming under scrutiny as legislated particulate emission standards are getting more and more stringent. The capacitance method is used for measurement of minimum oil film thickness between piston ring and liner interface. Measurement of capacitance formed between the piston ring and a probe mounted flush in the liner provides an accurate means of determining the oil film thickness provided that the region between the probe and liner is flooded with oil and dielectric constant of the oil is known. This paper presents detailed design and measurement of lubricating oil film thickness using capacitive micro sensor in a non-firing engine simulator. Lubricating oil film thickness was found to vary between 0.2μm to 8μm in the non firing engine simulator.

Fuel injection pressure (FIP) is one of the most important factors affecting diesel engine performance and particulate emissions. Higher FIP improves the fuel atomization, which results in lower soot formation due to superior fuel-air mixing. The objective of this spray study was to investigate macroscopic and microscopic spray parameters in FIP range of 500-1500 bar, using a solenoid injector for biodiesel blends (KB20 and KB40) and baseline mineral diesel. For these test fuels, effect of ambient pressure on macroscopic spray characteristics such as spray penetration, spray area and cone angle were investigated in a constant volume spray chamber (CVSC). Microscopic spray characteristics such as velocity distribution of droplets and spray droplet size distribution were measured in the CVSC at atmospheric pressure using Phase Doppler Interferometry (PDI).

Biodiesel is being explored as a sustainable renewable fuel for vehicles in India due to mounting foreign exchange expenditure to import crude petroleum. Significant amount of research and development work is being undertaken in India to investigate various aspects of biodiesel utilisation in different types of engines. This study is an effort to jointly investigate the use of biodiesel (B100) in an unmodified BS-III compliant sports utility vehicle (SUV) by a consortium of academia (IIT Kanpur) and Industry (M&M) to realistically assess whether biodiesel is compatible with modern engine technology vehicles. Two identical vehicles were operated in tandem using biodiesel (B100) and mineral diesel (B00) respectively for 30,000 kilometers in field conditions. The lubricating oil samples were collected and detailed analysis for assessing the comparative effect of new fuel (B100) vis-à-vis mineral diesel was carried out.

Biodiesel is mono alkyl ester derived from vegetable oils through transesterification reaction and can be used as an alternative to mineral diesel. In the present research, methyl ester of rice-bran oil (ROME) is produced through transesterification of rice-bran oil using methanol in presence of sodium hydroxide (NaOH) catalyst. Various properties like viscosity, density, flash point, calorific value of the biodiesel thus prepared are characterized and found comparable to diesel. On the basis of previous research for performance, emission and combustion characteristics, a 20% blend of ROME (B20) was selected as optimum biodiesel blend for endurance test. Endurance test of 100 hours was conducted on a medium duty direct injection transportation diesel engine. Tests were conducted under predetermined loading cycles in two phases: engine operating on mineral diesel and engine fuelled with 20% biodiesel blend.

Biodiesel made from Jatropha oil by transesterification process has viscosity and other important physical properties comparable to mineral diesel hence it can be used as an alternate fuel in conventional diesel engines. It is important to investigate the spray characteristics of biodiesel because emissions from the engines are dependent on fuel atomization process and resulting fuel-air mixing. This study focuses on the Jatropha biodiesel spray investigations using Phase Doppler Interferometry (PDI) for measurement of various microscopic spray parameters such as Sauter mean diameter (SMD) and spray droplet size and velocity distributions. The spray and engine experiments were carried out for Jatropha biodiesel (JB100) and their 20% blends (JB20) with mineral diesel as baseline. Fuel injection pressure during the spray experiments was maintained at 200 bars for all tests, quite similar to small horse power agricultural engines, and the fuel injection quantity was varied.

Use of alternative fuels, and reduction of particulate and NOx emissions are major challenges for making diesel engines environmentally benign. Measures adopted for reducing gravimetric particulate emissions necessarily always do not reduce particulate number concentration, which is strongly related with adverse health effects. Current emission norms in some parts of the world limit particulate number concentration along with particulate mass. In this scenario, it becomes important to investigate effect of fuel injection parameters and fuel injection strategies such as pilot injections on particulate size-number distribution. A single cylinder research engine is used to evaluate the effect of different fuel injection strategies and injection timings (for pilot and main injections) on particulate size-number distribution and total particulate numbers.

This study was set out to characterize particulate emissions from diesel engines in terms of poly aromatic hydrocarbon emissions and Benzene Soluble Organic Fraction. The characteristics of DPM vary with engine operating conditions, quality of fuel and lubricants being used. Hence the diesel exhaust for the purpose of toxicity characterization needs to be studied for Organic Matter in terms of Poly Aromatic Hydrocarbon (PAH) and Benzene Soluble Fraction (BSF). Therefore, the objectives of the present research are to characterize the diesel exhaust particulate matter for the above parameters under varying engine operating conditions/loads. Six PAHs, namely Chrysene, Benzo (k) Flouranthene, Benzo (a) Pyrene, Dibenzo (a, h) Anthracene, Benzo (g,h,i) Perylene and Indenopyrene were analyzed on High Pressure Liquid Chromatography (HPLC). PAH concentrations in the particulates of Mahindra DI engine were affected by engine loads.

Increased environmental awareness and depletion of fossil fuel resources are driving industry to develop alternative fuels that are environmentally more acceptable. Vegetable oils are potential alternative fuels. Vegetable oils in India are produced from numerous oil-seed crops. While all vegetable oils have high energy content, most require some processing to ensure safe usage in internal combustion engines. Most detrimental properties of oils are its high viscosity, low volatility and polyunsaturated character. The most widely used method is to convert vegetable oils into biodiesel. Biodiesel fuels are primary esters, which are produced by transesterifcation of vegetable oils. Several vegetable oil esters have been investigated so far in different parts of the world and found suitable to be used in diesel engines.

Adverse health effects of particulate matter (PM) originating from diesel engine exhaust are largely attributed to the complex chemical composition of the exhaust species. This study was set out to characterize particulate emissions from a Euro-III-compliant modern automotive common rail direct injection (CRDI) sports utility vehicle (SUV) diesel engine operated at different loads at rated engine speed (1800 rpm), employing diesel and 20% biodiesel blends (B20) produced from Karanja oil. This study is mainly divided into two main sections, first one includes the gravimetric analysis in order to assess the amount of Benzene Soluble Organic Fraction (BSOF) and trace metals using Inductively Coupled Plasma-Optical Emission Spectrometer (ICPOES). The second section includes real-time measurements for Organic Carbon (OC), Elemental Carbon (EC) and total particle-bound Polycyclic Aromatic Hydrocarbons (PAHs).

The methyl esters of vegetable oils, known as biodiesel are becoming increasingly popular because of their low environmental impact and potential as a green alternative fuel for diesel engine and they would not require significant modification of existing engine hardware. Methyl ester of rice bran oil (ROME) is derived through transesterification process. Previous research has shown that ROME has comparable performance, lower bsfc in comparison to diesel. There was reduction in the emissions of CO, HC, and smoke but NOx emissions increased. Experimental investigations have been carried out to examine the combustion characteristics in a direct injection transportation diesel engine running with diesel, and 20% blend of rice bran methyl ester with diesel.

In this study, macroscopic spray characteristics of Waste cooking oil (WCO), Jatropha oil, Karanja oil based biodiesels and baseline diesel were compared under simulated engine operating condition in a constant volume spray chamber (CVSC). The high pressure and high temperature ambient conditions of a typical diesel engine were simulated in the CVSC by performing pre-ignition before the fuel injection. The spray imaging was conducted under absence of oxygen in order to prevent the fuels from igniting. The ambient pressure and temperature for non-evaporating condition were 3 MPa and 300 K. Meanwhile, the spray tests were performed under the ambient pressure and temperature of 4.17 MPa and 804 K under evaporating condition. The fuels were injected by a common-rail injection system with injection pressure of 80 MPa. High speed Mie-scattering technique was employed to visualize the evaporating sprays.