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The use of oxygenated and renewable fuels is nowadays a widespread means to reduce regulated pollutant emissions produced by internal combustion engines, as well as to reduce the greenhouse impact of transportation. Besides PM, NOx and HC emissions, also the size distribution of particles emitted at the engine exhaust represent meaningful information, considering its adverse effects on the environment and human health. In this work, the results of a comprehensive investigation on the combustion characteristics and the exhaust emissions of a GDI high performance engine, fuelled with pure bio-ethanol and European gasoline, are shown. The engine is a 4-cylinder, 4-stroke, 1750 cm₃ displacement, and turbocharged. The engine was operated at different speed/load conditions and two fuel injection strategies were investigated: homogeneous charge mode and stratified charge mode.

Spectral flame emissivity and absorption measurements with high temporal and spatial resolution were performed in an optically accessible high-swirl divided-chamber Diesel system. Simultaneous determination of soot temperature, soot volume fraction and the OH radical concentration were made from the start to the end of the combustion in 153 locations equally distributed in the chamber. The engine was run at 2000 rpm and at fixed air-fuel ratio realizing 200 consecutive combustion cycles. To visualize the spatial and temporal spray and flame evolution, direct high-speed photographic sequences were taken at 8000 frames/s. The photographic sequences showed that the spray is strongly distorted and mixed by very high swirl resulting in a well premixed region where the combustion starts. The OH radicals were detected in the fuel reaction zone. Moreover OH concentration and soot volume fraction are well correlated with soot temperature.

Direct injection spark ignition engines represent an effective technology to achieve the goal of carbon dioxide emission reduction. Further reduction of the carbon footprint can be achieved by using carbon-neutral fuels. Oxygenated alcohols are well consolidated fuels for spark ignition engines providing also the advantages of knock resistance and low soot tendency production. Methanol and ethanol are possible candidates as alternative fuels to gasoline due to their similar properties. In this study a blend at 25 % v/v of ethanol in gasoline (E25) and a blend with 80% gasoline, 5 % v/v ethanol and 15% v/v of methanol (GEM) were tested. These blends were considered since E25 is already available at fuel pump in some countries. The GEM blend, instead, could represent a valid alternative in the next future. Experiments were carried out on a high performance, turbocharged 1.8 L direct injection spark ignition engine over the Worldwide Harmonized Light Vehicles Test Cycle.

In view of the new emission regulations seeking to lower the particle cut-off size down to the current 23 nm, an extensive comprehension on the nature of sub-23 nm particles is crucial. In this regard, a new challenge lies ahead considering an even more massive use of biofuels. The objective of this research study was to characterize the sub-23 nm particles and to evaluate their volatile organic fraction (VOF) from a high performance, 1.8 L gasoline direct injection (GDI) engine under the Worldwide harmonized Light vehicles Test Cycle (WLTC). Particle emissions were measured through an Engine Exhaust Particle Sizer (EEPS) capable of particle sizing and counting in the range 5.6 - 560 nm. The sampling and conditioning were performed by both a single diluter and the Dekati Engine Exhaust Diluter (DEED) a Particle Measurement Programme (PMP) compliant sample conditioning system.

Nowadays, the regulation regards only the particles larger than 23 nm. The attention is shifting towards the sub-23 nm particles because of their large presence at the exhaust of the modern engines and their negative impact on human health. The main challenge of the regulation of these particles is the definition of a proper procedure for their measure. The nature of the sub-23 nm particles is not well understood, and their measure is strongly affected by the sampling conditions leading to not reliable measure. The aim of this paper is to provide information on the emissions of sub-23 nm particles from GDI vehicles/engines. At the same time, the presence of volatiles, which mainly contribute to the formation of sub-23 nm particles, was evaluated and the effect of sampling conditions was investigated. The analysis was performed on a 1.8L GDI powered vehicle, widely used both in North America and Europe, and a 4-cylinder GDI engine, whose features are similar to those of the vehicle.

In order to meet the increasingly strict emission regulations, several solutions for NOx and PM emissions reduction have been studied. Exhaust gas recirculation (EGR) technology has become one of the more used methods to accomplish the NOx emissions reduction. However, actual control strategies do not consider, in the definition of optimal EGR, its effect on particle size and density. These latter have a great importance both for the optimal functioning of after-treatment systems, but also for the adverse effects that small particles have on human health. Epidemiological studies, in fact, highlighted that the toxicity of particulate particles increases as the particle size decreases. The aim of this paper is to present a Neural Network model able to provide real time information about the characteristics of exhaust particles emitted by a Diesel engine.

This paper deals with the combustion behavior and exhaust emissions of a small compression ignition engine modified to operate in diesel/methane dual fuel mode. The engine is a three-cylinder, 1028 cm3 of displacement, equipped with a common rail injection system. The engine is provided with the production diesel oxidation catalyst. Intake manifold was modified in order to set up a gas injector managed by an external control unit. Experiments were carried out at different engine speeds and loads. For each engine operating condition, the majority of the total load was supplied by methane while a small percentage of the load was realized using diesel fuel; the latter was necessary to ignite the premixed charge of gaseous fuel. Thermodynamical analysis of the combustion phase was performed by in-cylinder pressure signal. Gas emissions and particulate matter were measured at the exhaust by commercial instruments.

This paper reports the results of an experimental investigation on the combustion characteristics and exhaust particulate emissions of a GDI high performance engine, fuelled with blends of bio-ethanol and European gasoline fuel. The engine is a 4-cylinder, 4-stroke, 1750 cm₃ displacement, and turbocharged. The engine was operated at fixed speed and load, namely 1500 rpm and 110 Nm, and fuelled with gasoline (E0), ethanol (E100) and two blends 50% v/v (E50) and 85% v/v (E85) of ethanol in gasoline. Two fuel injection strategies were investigated: homogeneous charge and stratified charge combustion mode. The study mainly focuses on the effects of fuel injection strategy and ethanol upon the emissions of particulate matter (PM), in terms of mass, number concentration and size distribution.

Fuel depletion as well as the growing concerns on environmental issues prompt to the use of more eco-friendly fuels. The compressed natural gas (CNG) is considered one of the most promising alternative fuel for engine applications because of the lower emissions. Nevertheless, recent studies highlighted the presence of ultrafine particle emissions at the exhaust of CNG engines. The present study aims to investigate the effect of CNG on particle formation and emissions when it was direct injected and when it was dual fueled with gasoline. In this latter case, the CNG was direct injected and the gasoline port fuel injected. The study was carried out on a transparent single cylinder SI engine in order to investigate the in-cylinder process by real time non-intrusive diagnostics. In-cylinder 2D chemiluminescence measurements from UV to visible were carried out.

In the urban area the internal combustion engines are the main source of CO₂, NO and particulate matter (PM) emissions. The reduction of these emissions is no more an option, but a necessity highlighted by the even stricter emission standards. In the last years, even more attention was paid to the alternative fuels. They allow both reducing the fuel consumption and the pollutant emissions. With regards to the gaseous fuels, methane is considered one of the most interesting in terms of engine application. It represents an immediate advantage over other hydrocarbon fuels because of the lower C/H ratio. In this paper the effect of the methane on the combustion process, the pollutant emissions and the engine performance was analyzed. The measurements were carried out in an optically accessible single-cylinder, Port Fuel Injection, four-stroke SI engine equipped with the cylinder head of a commercial 250 cc motorcycles engine and fuelled both with gasoline and methane.

Growing concerns about the emissions of internal combustion engines have forced the adoption of aftertreatment devices to reduce the adverse impact of diesel engines on health and environment. Diesel particulate filters are considered as an effective means to reduce the particle emissions and comply with the regulations. Research activity in this field focuses on filter configuration, materials and aging, on understanding the variation of soot layer properties during time, on defining of the optimal strategy of DPF management for on-board control applications. A model was implemented in order to simulate the filtration and regeneration processes of a wall-flow particulate filter, taking into account the emission characteristic of the engine, whose architecture and operating conditions deeply affect the size distribution of soot particles.

The growing concerns over the pollutant emissions as well as the depletion of fossil fuel led to the research of advanced combustion mode and alternative fuels for the reduction both of fuel consumption and exhaust emissions. The dual-fuel injection system can be used to improve the engine performance and reduce the fossil fuel consumption performing simultaneously a direct-injection (DI) and a port-fuel-injection (PFI) of different fuels. Ethanol is one of the most promising alternative fuels for SI engines. It offers high anti-knock quality because of the high octane number; moreover, being an oxygenated fuel is very effective in particle emissions reduction. On the other hand, it is characterized by lower energy density mainly because of the low lower heating value (LHV). The aim of the paper is the investigation of the ethanol-gasoline dual fuel combustion on engine performance and emissions.

This paper aims to correlate the in-cylinder soot formation and the exhaust particle emissions for different methods of gasoline/ethanol fueling in spark ignition engine. In particular, the engine was fueled with gasoline and ethanol separately and not, in this latter case both blended (E30) and dual fueled (EDF). For E30 the bend was direct injected and for EDF, the ethanol was injected in the combustion chamber and the gasoline into the intake duct. For both the injection configurations, the same percentage of ethanol in gasoline was supplied: 30%v/v. The measurements were carried out at 2000 and 4000 rpm, under full load, and stoichiometric condition, in small single cylinder optical engine. 2D-digital imaging was performed to follow the combustion process with a high spatial and temporal resolution through a full-bore optical piston. The two-color pyrometry was applied for the analysis of the in cylinder soot formation in the combustion chamber.

The aim of the present work is to provide further guidance into better understanding the production mechanisms of soot emissions in Spark-Ignition SI engines fueled with compressed natural gas. In particular, extensive experimental investigations were designed with the aim to isolate the contribution of the fuel from that of lubricant oil to particle emissions. This because the common thought is that particulate emerging from the engine derives mainly from fuel, otherwise the contribute of lubricant oil cannot be neglected or underestimated, especially when the fuel itself produces low levels of soot emissions, such as in the case of premixed natural gas. The fuel-derived contribution was studied by analyzing the influence that natural gas composition has on soot emitted from a single cylinder Spark-Ignition (SI) engine. To achieve this purpose, methane/propane mixtures were realized and injected into the intake manifold of a Single-Cylinder SI engine.

In this paper the methane-gasoline dual fuel combustion was investigated. Gasoline was injected in the intake manifold (PFI fuel), while methane was injected in the combustion chamber (DI fuel), in order to reproduce a stratified combustion. The combustion process and the related engine performance and pollutant emissions were analyzed. The measurements were carried out in an optically accessible small single-cylinder four-stroke engine. It was equipped with the cylinder head of a commercial 250 cc engine representative of the most popular two-wheel vehicles in Europe. Optical measurements were performed to analyze the combustion process with high spatial and temporal resolution. In particular, optical techniques based on 2D-digital imaging were used to follow the flame front propagation and the soot and temperature concentration in the combustion chamber.

The aim of the paper is the comparison of the performance, gaseous and particle emissions from different injection configurations and fuels. The engine was operated in port fuel injection (PFI), direct injection (DI) and dual fuel (DF). For DF, ethanol DI-gasoline PFI and gasoline DI-gasoline PFI strategies were performed to discern the effect of injection strategy from the effect of the fuel. The experimental activity was carried out in a small displacement single cylinder engine, representative of 2-3 wheel vehicle engines or of 3-4 cylinder small displacement automotive engines. It was equipped with a prototype gasoline direct injection (GDI) head. The tests were carried out at 3000 rpm, 4000 rpm and 5000 rpm full load. The investigated engine operating conditions are representative of the homologation urban driving cycle. The gaseous and particle emissions were measured at the exhaust by means of a gas analyzer and a smoke meter.

In this paper, the effect of the oxygen addition on engine performance and exhaust emissions was investigated. The experimental study was carried out in a small single-cylinder PFI SI four-stroke engine. The addition of the 5% vol and 10% vol of oxygen was performed in the intake duct. Typical urban driving operating conditions were investigated. The engine emissions were characterized by means of gaseous analyzers and a smokemeter. Particle size distribution function was measured in the size range from 5.6 to 560 nm by means of an Engine Exhaust Particle Sizer (EEPS). An improvement in terms of engine power output, without BSFC penalty, and HC emissions with oxygen addition was observed at all the investigated operating conditions. On the other hand, NOx and PM emissions increase.

The present paper describes the results of an experimental activity performed on a small diesel engine for quadricycles, a category of vehicles that is spreading in Europe and is recently spreading over Indian countries. The engine is a prototype three-cylinder with 1000 cc of displacement and it is equipped with a direct common-rail injection system that reaches a maximum pressure of 1400 bar. The engine was designed to comply with Euro 4 emission standard that is a future regulation for quadricycles. It is worth underlining that the engine can meet emission limits just with EGR system and a DOC, without DPF. Various diesel/RME blends were tested; pure diesel and biodiesel fuels were also used. The investigation was carried out at the engine speeds of 1400, 2000 and 3400 rpm and full load. Combustion characteristics of both blended and pure RME were analyzed by means of in-cylinder pressure and heat released histories.

The aim of this study is to investigate the combustion process and pollutant formation in a small compression ignition engine. The engine is a prototype for quadricycles. It was designed to comply with Euro 4 emission standard that is a future regulation for this type of vehicles. Two optical accesses for endoscopes were realized in the first cylinder to investigate the combustion process. Two-color pyrometry method was applied to combustion images in order to detect the flame temperature and the soot concentration. The engine ran with a biodiesel, the rapeseed methyl ester, and a conventional diesel fuel. Operating conditions at the engine speed of 2000 rpm at full and medium load were tested. NOx emissions were measured at exhaust. A smoke meter was used to determine the particulate matter concentration. The sizing and the counting of the particles were performed by means of an engine exhaust particle sizer spectrometer.

The permanent aim of the automotive industry is the further improvement of the engine efficiency and the simultaneous pollutant emissions reduction. The aim of the study was the optimization of the gasoline combustion by means of a passive prechamber. This analysis allowed the improvement of the engine efficiency in lean-burn operation condition too. The investigation was carried out in a commercial small Spark Ignition (SI) engine fueled with gasoline and equipped with a proper designed passive prechamber. It was analyzed the effects of the prechamber on engine performance, Indicated Mean Effective Pressure, Heat Release Rate and Fuel Consumption were used. Gaseous emissions were measured as well. Particulate Mass, Number and Size Distributions were analyzed. Emissions samples were taken from the exhaust flow, just downstream of the valves. Four different engine speeds were investigated, namely 2000, 3000, 4000 and 5000 rpm.