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The development of vehicles continues to be determined by increasingly stringent emissions standards including CO2 emissions and fuel consumption. To fulfill the simultaneous emission requirements for near zero pollutant and low CO2 levels, which are the challenges of future powertrains, many research studies are currently being carried out world over on new engine combustion process, such as Controlled Auto Ignition (CAI) for gasoline engines and Homogeneous Charge Compression Ignition (HCCI) for diesel engines. In HCCI combustion engine, ignition timing and combustion rates are dominated by physical and chemical properties of fuel/air/residual gas mixtures, boundary conditions including ambient temperature, pressure, and humidity and engine operating conditions such as load, speed etc.