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Use of biodiesel from non-edible vegetable oil as an alternative fuel to mineral diesel is attractive economically and environmentally. Diesel engines emit several harmful gaseous emissions and some of them are regulated worldwide, while countless others are not regulated. These unregulated species are associated with severe health hazards. Karanja biodiesel is a popular alternate fuel in South Asia and various governments are considering its large-scale implementation. Therefore it is important to study the possible adverse impact of this new alternate fuel. In this study, unregulated and regulated emissions were measured at varying engine speeds (1500, 2500 and 3500 rpm) for various engine loads (0%, 20%, 40%, 60%, 80% and 100% rated load) using 20% Karanja biodiesel blend (KB20) and diesel in a 4-cylinder 2.2L common rail direct injection (CRDI) sports utility vehicle (SUV) engine.

Better understanding of flow phenomena inside the combustion chamber of a diesel engine and accurate measurement of flow parameters is necessary for engine optimization i.e. enhancing power output, fuel economy improvement and emissions control. Airflow structures developed inside the engine combustion chamber significantly influence the air-fuel mixing. In this study, in-cylinder air flow characteristics of a motored, four-valve diesel engine were investigated using time-resolved high-speed Tomographic Particle Imaging Velocimetry (PIV). Single cylinder optical engine provides full optical access of combustion chamber through a transparent cylinder and flat transparent piston top. Experiments were performed in different vertical planes at different engine speeds during the intake and compression stroke under motoring condition. For visualization of air flow pattern, graphite particles were used for flow seeding.

In this study, 3D air-flow-field evolution in a single cylinder optical research engine was determined using tomographic particle imaging velocimetry (TPIV) at different engine speeds. Two directional projections of captured flow-field were pre-processed to reconstruct the 3D flow-field by using the MART (multiplicative algebraic reconstruction technique) algorithm. Ensemble average flow pattern was used to investigate the air-flow behavior inside the combustion chamber during the intake and compression strokes of an engine cycle. In-cylinder air-flow characteristics were significantly affected by the engine speed. Experimental results showed that high velocities generated during the first half of the intake stroke dissipated in later stages of the intake stroke. In-cylinder flow visualization indicated that large part of flow energy dissipated during the intake stroke and energy dissipation was the maximum near the end of the intake stroke.

Condensed soot coming out of vehicular exhaust is commonly classified as organic carbon (OC) and elemental carbon (EC). OC can be directly emitted to the atmosphere in the particulate form (primary carbon) from the tailpipe or can be produced by gas-to-particle conversion process (secondary organic carbon, SOC). Under typical atmospheric dilution conditions, most of the semi-volatile material is present in the form of soot. SOC holds wider implications in terms of their adverse health and climate impact. Diesel exhaust is environmentally reactive and it has long been understood that the ambient interaction of exhaust hydrocarbons and NOx results in the formation of ozone and other potentially toxic secondary organic carbon species. The current emission norms look at the primary emissions from the engine exhaust. Also, research efforts are geared towards controlling the emissions of primary carbon.

Increased environmental awareness and depletion of resources are driving industry to develop alternative fuels that are environmentally more acceptable. Fatty acids esters (biodiesel) are known to be good alternative fuels. Due to economic reasons, the use of cheap raw materials for biodiesel production is preferred. In this case, ricebran oil, non-edible grade is used. Base catalyzed transesterification of ricebran oil is investigated and process parameters for ricebran biodiesel production are optimized. Various properties like viscosity, density, flash point, calorific value of biodiesel thus prepared are characterized as per ASTM D6751 and found comparable to mineral diesel. Steady state engine dynamometer test at 1800 rpm has been carried out to evaluate the performance and emission characteristics of a medium duty transportation DI diesel engine. Emission tests with all the fuel blends have also been carried out using European 13 MODE test (ECE R49).

Considering the demand for sustainable transport, alternative fuels are a keen research topic for IC engine researchers. Among various alternative fuels being explored, Di-ethyl ether (DEE) is gaining popularity off-late for compression-ignition (CI) engines owing to its high cetane rating, oxygen presence in its molecular structure, and lower carbon content. This study explores the suitability of DEE blends in tractor engines. DEE blends [15% and 30% (v/v)] with diesel were compared with baseline diesel for combustion, and emission characterisation, keeping all parameters identical, including the fuel injection timings. Results were analysed for different engine loads at 1500 rpm. Delayed combustion was observed with DEE blends with diesel, possibly due to a higher cooling effect from DEE vaporisation and retarded dynamic fuel injection due to its higher compressibility. However, the DEE blend fuelled engine performance was comparable to baseline diesel.

Vegetable oils have energy content suitable to be used as compression ignition (CI) engine fuel. However, several operational and durability problems of using straight vegetable oils in CI engines are reported in the literature, which are primarily caused by their higher viscosity and low volatility compared to mineral diesel. The viscosity can be brought in acceptable range by (i) chemical process of transesterification, (ii) blending of oil with mineral diesel or (iii) by heating the vegetable oil using exhaust gas waste heat. Reduction of viscosity by blending or exhaust gas heating saves the chemical processing cost of transesterification. Present experimental investigations were carried out for evaluating combustion, performance and emission behavior of Jatropha oil blends in unheated conditions in a direct injection CI engine at different load and constant engine speed (1500 rpm).

Biodiesel (fatty acid methyl ester) is a non-toxic and biodegradable alternative fuel that is obtained from renewable sources. A major hurdle in the commercialization of biodiesel from virgin oil, in comparison to petroleum-based diesel, is its cost of production, primarily the raw material cost. Used cooking oils or waste cooking oils are economical sources for biodiesel production, which can help in commercialization of biodiesel. However, the products formed during cooking/frying (such as free fatty acids and various polymerized triglycerides) affect the transesterification reaction and the biodiesel properties. In present experimental investigations, wastecooking oil obtained from restaurant was used to produce biodiesel through transesterification process and the chemical kinetics of biodiesel production was studied. Biodiesel was blended with petroleum diesel in different proportions.

This experimental study was undertaken to investigate the use of vegetable oil derivatives to substitute mineral diesel fuel. Straight vegetable oils pose some problems like injector coking, carbon deposits etc., when used as a fuel in an engine. These problems are due to high viscosity, low volatility and polyunsaturated character of vegetable oils. Transesterified vegetable oil derivative called “biodiesel” appear to be most convenient way of utilizing vegetable oil as a substitute fuel in diesel engines. In present investigation, rice bran oil (non-edible) was transesterified to methyl ester and reaction conditions for transeterifcation process for rice bran oil were optimized. Various properties like viscosity, density, flash point of the biodiesel thus prepared are comparable to diesel and found to be in acceptable range as per ASTM norms (ASTM D6751). Experimental investigations were carried out on a four stroke, four cylinders, transportation DI diesel engine.

Homogeneous charge compression ignition (HCCI) engines are attracting attention as next-generation internal combustion engines mainly because of very low NOx and PM emission potential and excellent thermal efficiency. Particulate emissions from HCCI engines have been usually considered negligible however recent studies suggest that PM number emissions from HCCI engines cannot be neglected. This study is therefore conducted on a modified four cylinder diesel engine to investigate this aspect of HCCI technology. One cylinder of the engine is modified to operate in HCCI mode for the experiments and port fuel injection technique is used for preparing homogenous charge in this cylinder. Experiments are conducted at 1200 and 2400 rpm engine speeds using gasoline, ethanol, methanol and butanol fuels. A partial flow dilution tunnel was employed to measure the mass of the particulates emitted on a pre-conditioned filter paper.

Environmental concerns have increased significantly world over in the past decade. Regulatory agencies are becoming increasingly concerned with particulate emissions as the health and environmental effects are getting understood better due to rapid development in instrumentation. Biodiesel is one of the most promising alternative diesel fuels, which is getting global acceptability among the automotive/ engine manufactures as well as users due to numerous benefits it offers over the conventional diesel. While much of literature is available on particulate emitted by diesel fuelled engine, little is known by particulate emissions from biodiesel fuelled compression ignition (CI) engine. This study concentrates on the characterization of particulate emissions from mineral diesel vis-à-vis biodiesel (B100) and its optimum blend (20%, B20) with mineral diesel.

Poor oxidation stability is the central problem associated with the commercial acceptance of the biodiesel. The EU standard (EN14214) specifies a minimum value of 6 h for biodiesel induction period at 110°C, measured with Rancimat instrument. Most of the freshly prepared biodiesel generally have lower induction periods than prescribed by the standards. Anti-oxidants are therefore added to enhance the oxidation/ storage stability of biodiesel. Oxidation is an exothermic process, and the reaction heat evolved makes it possible to use thermo gravimetric analysis (TGA). In the present study, the oxidation stability of methyl esters derived from Karanja oil and Neem oil, stabilized with anti-oxidant pyrogalol (PY) was studied by DSC. Onset temperature of freshly prepared Karanja biodiesel (KOME) and Neem biodiesel (NOME) was observed to be 148 and 153°C respectively. The stability increases with increasing anti-oxidant dosage.

Mono alkyl esters of long-chain fatty acids derived from renewable lipid feedstock, such as vegetable oils or animal fats, also known as biodiesel are well positioned to replace mineral diesel. The outstanding technical problem with biodiesel is that it is more susceptible to oxidation owing to its exposure to oxygen present in the air and high temperature. This happens mainly due to the presence of varying numbers of double bonds in the free fatty acid molecules. The chemical reactivity of esters can therefore be divided into oxidative and thermal instability, which can be determined by the amount and configuration of the olefinic unsaturation in the fatty acid chains. Many of the plant-derived fatty oils contain polyunsaturated fatty acids that are more prone to oxidation. Increasing production of biodiesel from vegetable oils (edible) places strain on food production, availability and price and leads to food versus fuel conflict.

Thermal loading of diesel engine pistons has increased dramatically in recent years due to applications of various advanced technologies to meet low emission and high power requirements. Control of piston temperatures by cooling of pistons has become one of the determining factors in a successful engine design. The pistons are cooled by oil jets fired at the underside from the crankcase. Any undesirable piston temperature rise may lead to engine seizure because of piston warping. However, if the temperature at the underside of the piston, where oil jet strikes the piston, is above the boiling point of the oil being used, it may contribute to the mist generation. This mist significantly contribute to the non-tail pipe emissions in the form of unburnt hydrocarbons (UBHC's), which has unfortunately not been looked into so seriously, as the current stress of all the automobile manufacturers is on meeting the tail pipe emission legislative limits.

Petroleum products are used to power internal combustion engines (ICEs). Emissions and depletion of petroleum reserves are important questions that need to be answered to ensure existence of ICEs. Indian Railways (IR) operates diesel locomotives, which emit large volume of pollutants into the environment. IR is looking for an alternative to diesel for powering the Locomotives. Methanol has emerged as a replacement for petroleum fuels because it can be produced from renewable resources as well as from non-renewable resources in large quantities on a commercially viable scale. It has similar/superior physico-chemical properties, which reduce tailpipe emissions significantly. It is therefore necessary to understand the in-cylinder phenomenon in methanol fueled engines before its implementation on a large-scale.

Thermal loading of diesel engine pistons has increased dramatically in recent years due to applications of various technologies to meet low emission and high power requirements. Control of piston temperatures by cooling of these pistons has become one of the determining factors in a successful engine design. The pistons are cooled by oil jets fired at the underside from the crankcase. Any undesirable piston temperature rise may lead to engine seizure due to piston warping. However, if the temperature at the underside of the piston, where the oil jet strikes the piston, is above the boiling point of the oil being used, it may contribute to the mist generation. This mist may significantly contribute to the non-tail pipe emissions in the form of unburnt hydrocarbons (UBHC). The problem of non-tail pipe emissions has unfortunately not been looked into so seriously, as the current stress of all the automobile manufacturers is on meeting the tail -pipe emission legislative limits.

The world energy demand has witnessed uncertainties in two dimensions. The scarcity and depletion of conventional petroleum sources are causes of great concern worldwide. Combustion of fossil fuels has led to unprecedented rise in the global CO2 level, leading to global warming. Therefore, efforts are underway in several countries to search for suitable alternative fuels that are environment friendly. Vegetable oils of non-edible nature are such alternative fuels, which can form part of potential solution. Vegetable oils, due to their agricultural origin, are able to reduce CO2 emissions to the atmosphere along with import substitution of petroleum products In the present research, experiment were designed to study the effect of reducing Neem oil's high viscosity by increasing the fuel temperature and thereby its effect on combustion and emission characteristics of the engine.

High viscosity of vegetable oil causes ignition problems when used in compression ignition engines. There is a need to reduce the viscosity before using it as engine fuel. Preheating and pre-treating of vegetable oils using waste heat of exhaust gases is one of the techniques, which reduces the viscosity and makes it possible to use it as alternate fuel for some niche applications, without requiring major modifications in the engine hardware. Several applications such as decentralized power generation, agricultural engines, and water pumping engines, can use vegetable oils as an alternative fuel. In present investigation, performance, combustion, and emission characteristics of an engine using preheated 20% blend of Jatropha oil with mineral diesel (J20) has been evaluated at a constant speed (1500 rpm) in a single cylinder four stroke direct injection diesel engine.

Fuel atomization and air-fuel mixing processes play a dominant role on engine performance and emission characteristics in a direct injection compression ignition engine. Understanding of microscopic spray characteristics is essential to predict combustion phenomena. The present work investigated near nozzle flow and atomization characteristics of biodiesel fuels in a constant volume chamber. Waste cooking oil, Jatropha, and Karanja biodiesels were applied and the results were compared with those of conventional diesel fuel. The tested fuels were injected by a solenoid injector with a common-rail injection system. A high-speed camera with a long distance microscopic lens was utilized to capture the near nozzle flow. Meanwhile, Sauter mean diameter (SMD) was measured by a phase Doppler particle analyzer to compare atomization characteristics.

Depleting fossil-fuels and increasing harmful emissions by the combustion of fossil fuels in IC engine is a matter of great concern. It is necessary to explore solutions complying with the prevailing emission norms in different sectors. Methanol has the potential amongst all primary alcohols for widespread use in transport sector due to its clean-burning, high octane rating, sources of production like high ash coal, and biomass. The addition of methanol to gasoline can significantly reduce engine-out emissions. Gasoline-Methanol blends (Gasohols) can be used to reduce dependence of the transport sector on fossil fuels. This study deals with investigation of spray characteristics of methanol-gasoline blends as it affects engine performance and emissions characteristics to a great extent.