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Pre-chamber combustion (PCC) has re-emerged in recent last years as a potential solution to help to decarbonize the transport sector with its improved engine efficiency as well as providing lower emissions. Research into the combustion process inside the pre-chamber is still a challenge due to the high pressure and temperatures, the geometrical restrictions, and the short combustion durations. Some fundamental studies in constant volume combustion chambers (CVCC) at low and medium working pressures have shown the complexity of the process and the influence of high pressures on the turbulence levels. In this study, the pre-chamber combustion process was investigated by combustion visualization in an optically-accessible pre-chamber under engine relevant conditions and linked with the jet emergence inside the main chamber. The pre-chamber geometry has a narrow-throat. The total nozzle area is distributed in two six-hole rows of nozzle holes.

The NO reduction in an ammonia SCR converter has been simulated by a 1D+1D model for a single representative channel to parametrically study the characteristics of the system under typical operating conditions. An appropriate model has been selected interpreting the chemical behavior of the system and the parameters are calibrated based on a comprehensive set of experiments with an Fe-Zeolite washcoated monolith for different feed concentrations, temperatures and flow rates. Physical and chemical properties are determined as well as kinetics and rate parameters and the model has been verified by experimental data at different operating conditions. Three different mechanisms for the surface kinetics to model NO reduction have been assessed and the results have been compared in the cases of steady DeNO performance and transient response of the system. Ammonia inhibition is considered in the model since it has a major effect specifically under transient operating conditions.

The current work utilizes computational fluid dynamics (CFD) simulations to assess the effects of different piston geometries in an active-type pre-chamber combustion engine fueled with methane. Previous works identified that the interaction of the jets with the main chamber flow and piston wall are key aspects for the local turbulent flame speed and overall burning duration. The combustion process is simulated with the G-equation model for flame propagation combined with the MZ-WSR model to determine the post-flame composition and to predict possible auto-ignition of the reactant mixture. Four setups were considered: two bowl-shaped and one flat piston, and one additional case of the flat piston with jets at wider jet angles to the cylinder axis. The results show that premature jet-wall interaction impacts the main chamber pressure build-up, turbulence, and burn rate.

Particle image velocimetry measurements of the in-cylinder flow in an optically accessible single-cylinder research engine were taken to better understand the effects of intake pressure variations on the flow field. At a speed of 1500 rpm, the engine was run at six different intake pressure loads from 0.4 to 0.95 bar under motored operation. The average velocity fields show that the tumble center position is located closer to the piston and velocity magnitudes decrease with increasing pressure load. A closer investigation of the intake flow near the valves reveals sharp temporal gradients and differences in maximum and minimum velocity with varying intake pressure load which are attributed to intake pressure oscillations. Despite measures to eliminate acoustic oscillations in the intake system, high-frequency pressure oscillations are shown to be caused by the backflow of air from the exhaust to the intake pipe when the valves open, exciting acoustic modes in the fluid volume.

This work investigates the impact of injector temperature on the characteristics of high-pressure n-dodecane sprays under conditions relevant to heavy-duty diesel engines. Sprays are injected from a pair of single-hole diesel injectors belonging to the family of “Spray C” and “Spray D” Engine Combustion Network (ECN) injectors. Low and high injector temperature conditions are achieved by activating or deactivating a cooling jacket. We quantify spray spreading angle and penetration using high-speed shadowgraphy and long-distance microscopy imaging. We evaluate differences in fuel/air mixture formation at key timings through one-dimensional modeling. Injections from a cooled injector penetrate faster than those from a higher temperature injector, especially for an injector already prone to cavitation (Spray C).

Cycle-to-cycle variations in internal combustion engines are known to lead to limitations in engine load and efficiency, as well as increases in emissions. Recent research has led to the identification of the source of cyclic variations of pressure, soot and NO emissions in direct injection common rail diesel engines, when employing a single block injection and operating under long ignition delay conditions. The variations in peak pressure arise from changes in the diffusion combustion rate, caused by randomly occurring in-cylinder pressure fluctuations. These fluctuations result from the excitation of the first radial mode of vibration of the cylinder gases which arises from the rapid premixed combustion after the long ignition delay period. Cycles with high-intensity fluctuations present faster diffusion combustion, resulting in higher cycle peak pressure, as well as higher measured exhaust NO concentrations.

Past research has shown that post injections have the potential to reduce Diesel engine exhaust PM concentration without any significant influence in NOx emissions. However, an accurate, widely applicable rule of how to parameterize a post injection such that it provides a maximum reduction of PM emissions does not exist. Moreover, the underlying mechanisms are not thoroughly understood. In past research, the underlying mechanisms have been investigated in engine experiments, in constant volume chambers and also using detailed 3D CFD-CMC simulations. It has been observed that soot reduction due to a post injection is mainly due to two reasons: increased turbulence from the post injection during soot oxidation and lower soot formation due to lower amount of fuel in the main combustion at similar load conditions. Those studies do not show a significant temperature rise caused by the post injection.

Pre-chamber combustion (PCC) enables leaner air-fuel ratio operation by improving its ignitability and extending flammability limit, and consequently, offers better thermal efficiency than conventional spark ignition operation. The geometry and fuel concentration of the pre-chamber (PC) is one of the major parameters that affect overall performance. To understand the dynamics of the PCC in practical engine conditions, this study focused on (i) correlation of the events in the main chamber (MC) with the measured in-cylinder pressure traces and, (ii) the effect of fuel concentration on the MC combustion characteristics using laser diagnostics. We performed simultaneous acetone planar laser-induced fluorescence (PLIF) from the side, and OH* chemiluminescence imaging from the bottom in a heavy-duty optical engine. Two different PC Fueling Ratios (PCFR, the ratio of PC fuel to the total fuel), 7%, and 13%, were investigated.

Within the Engine Combustion Network (ECN) spray combustion research frame, simultaneous line-of-sight laser extinction measurements and laser-induced incandescence (LII) imaging were performed to derive the soot volume fraction (fv). Experiments are conducted at engine-relevant high-temperature and high-pressure conditions in a constant-volume pre-combustion type vessel. The target condition, called "Spray A," uses well-defined ambient (900 K, 60 bar, 22.8 kg/m₃, 15% oxygen) and injector conditions (common rail, 1500 bar, KS1.5/86 nozzle, 0.090 mm orifice diameter, n-dodecane, 363 K). Extinction measurements are used to calibrate LII images for quantitative soot distribution measurements at cross sections intersecting the spray axis. LII images are taken after the start of injection where quasi-stationary combustion is already established.

In this study we classify established and possible future engine combustion systems according to two main criteria, i.e. charge preparation (homogeneous or stratified) and type of combustion initiation (external, typically spark ignition and internal, typically due to compression). We discuss the relevant pros and cons of the four resulting energy conversion processes with emphasis on combustion stability, thermal efficiency and pollutant emissions. We show thereby that these output parameters are dominated by specific thermochemical and fluiddynamic processes as well as their complex interaction within the time scales of a thermodynamically optimal energy conversion at a given engine speed and load. For unsteady operation in mobile applications, the complexity of new combustion concepts may, nevertheless, prevent a breakthrough, despite their in-principle attractivity.

Soot formation in high-pressure n-dodecane sprays is investigated under conditions relevant to heavy-duty diesel engines. Sprays are injected from a single-hole diesel injector belonging to the family of engine combustion network (ECN) Spray D injectors. Soot is quantified using a high-speed extinction imaging diagnostic with incident light wavelengths of 623 nm and 850 nm. Previously, soot measurements in a high-pressure spray using 406-nm and 520-nm incident light demonstrated a minimal wavelength dependence in the complex refractive index of soot (m), as demonstrated by a near unity ratio of the non-dimensional extinction coefficients (ke,406 nm/ke,520 nm). The present work, however, demonstrates a significant difference in m for measurements with infrared incident light. During the quasi-steady period of the spray combustion event, the experimentally determined ke ratio (ke,623 nm/ke,850 nm) is 1.42 ± 0.27.

The operation of dual fuel engines, operated with natural gas as main fuel, offers the potential of substantial savings in CO2. Nevertheless, the operating map area where low pollutant emissions are produced is very narrow. Especially at low load, the raw exhaust gas contains high concentrations of unburned methane and, with high pilot fuel portions due to ignition limitations, also soot. The analysis of the combustion in those conditions in particular is not trivial, since multiple combustion modes are present concurrently. The present work focuses on the evaluation of the individual combustion modes of a dual fuel engine, operated with natural gas as main and diesel as pilot fuel, using a combustion model. The combustion has been split in two partwise concurrent combustion phases: the auto-ignition phase and the premixed flame propagation phase.

Numerical simulations of soot formation were performed for n-dodecane spray using the transported probability density function (TPDF) method. Liquid n-dodecane was injected with 1500 bar fuel pressure into a constant-volume vessel with an ambient temperature, oxygen volume fraction and density of 900 K, 15% and 22.8 kg/m3, respectively. The interaction by exchange with the mean (IEM) model was employed to close the micro-mixing term. The unsteady Reynolds-averaged Navier-Stokes (RANS) equations coupled with the realizable k-ε turbulence model were used to provide turbulence information to the TPDF solver. A 53-species reduced n-dodecane chemical mechanism was employed to evaluate the reaction rates. Soot formation was modelled with an acetylene-based two-equation model which accounts for simultaneous soot particle inception, surface growth, coagulation and oxidation by O2 and OH.

Measurements of the soot emissions and engine operating parameters from a diesel engine during transient operation were used to investigate the influence of transient operation on the soot emissions, as well as to validate a realtime mean value soot model (MVSM, [1]) for transient operation. To maximize the temporal resolution of the soot emission and engine parameter measurements (in particular EGR), fast instruments were used and their dynamic responses characterized and corrected. During tip-in transients, an increase in the soot emissions was observed due to a short term oxygen deficit compared to steady-state operation. No significant difference was seen between steady-state and transient operation for acceleration transients. When the MVSM was provided with inputs of sufficient temporal resolution, it was capable of reproducing the qualitative and, in part, quantitative soot emission trends.

Pre-chamber combustion (PCC) is a promising engine combustion concept capable of extending the lean limit at part load. The engine experiments in the literature showed that the PCC could achieve higher engine thermal efficiency and much lower NOx emission than the spark-ignition engine. Improved understanding of the detailed flow and combustion physics of PCC is important for optimizing the PCC combustion. In this study, we investigated the gas exchange and flame jet from a narrow throat pre-chamber (PC) by only fueling the PC with methane in an optical engine. Simultaneous negative acetone planar laser-induced fluorescence (PLIF) imaging and OH* chemiluminescence imaging were applied to visualize the PC jet and flame jet from the PC, respectively. Results indicate a delay of the PC gas exchange relative to the built-up of the pressure difference (△ P) between PC and the main chamber (MC). This should be due to the gas inertia inside the PC and the resistance of the PC nozzle.

In this study, numerical simulations of in-cylinder processes associated to fuel post-injection in a diesel engine operated at Low Temperature Combustion (LTC) have been performed. An extended Conditional Moment Closure (CMC) model capable of accounting for an arbitrary number of subsequent injections has been employed: instead of a three-feed system, the problem has been described as a sequential two-feed system, using the total mixture fraction as the conditioning scalar. A reduced n-heptane chemical mechanism coupled with a two-equation soot model is employed. Numerical results have been validated with measurements from the optically accessible heavy-duty diesel engine installed at Sandia National Laboratories by comparing apparent heat release rate (AHRR) and in-cylinder soot mass evolutions for three different start of main injection, and a wide range of post injection dwell times.

Numerical simulations of diesel sprays in a constant-volume vessel have been performed with the conditional moment closure (CMC) combustion model for a broad range of conditions. On the oxidizer side these include variations in ambient temperature (800-1100 K), oxygen volume fraction (15-21%) and density (7.3-58.5 kg/m₃) and on the fuel side variation in injector orifice diameter (50-363 μm) and fuel pressure (600-1900 bar); in total 22 conditions. Results are compared to experimental data by means of ignition delay and flame lift-off length (LOL). Good agreement for both quantities is reported for the vast majority of conditions without any changes to model constants: the variations relating to the air side are quantitatively accurately predicted; for the fuel side (viz. orifice diameter and injection pressure) the trends are qualitatively well reproduced.

Optical soot pyrometry is a mature experimental technique that has been applied to a broad range of combustion systems for measuring soot temperature and concentration. Even though the method is widely used and well documented, the line of sight nature of the technique makes the interpretation of its results challenging. Notably, gradients in temperature and soot concentration along the line of sight or across the field of view can introduce significant levels of uncertainty in the results. This paper presents a numerical study where the signal from the experimental two-color pyrometry technique in a marine diesel engine reference experiment is reconstructed employing computational fluid dynamics (CFD) and a detailed Line-by-Line (LBL) spectral radiation model. The analysis is aimed at qualitatively supporting interpretability of experimental observations.

Emissions and performance parameters of a medium size, medium speed D.I. diesel engine with increased charge air pressure and reduced but fixed inlet valve opening period have been measured and compared to the standard engine. While power output and fuel consumption are slightly improved, nitric oxide emissions can be reduced by up to 20%. The measurements confirm the results of simulations for both performance and emissions, for which a quasidimensional model including detailed chemistry for nitric oxide prediction has been developed.

The pre-chamber combustion (PCC) concept is a proven lean or diluted combustion technique for internal combustion engines with benefits in engine efficiency and reduced NOx emissions. The engine lean operation limit can be extended by supplying auxiliary fuel into the pre-chamber and thereby, achieving mixture stratification inside the pre-chamber over the main chamber. Introducing liquid fuels into the pre-chambers is challenging owing to the small form factor of the pre-chamber. With a conventional injector, the fuel penetrates in liquid form and impinges on the pre-chamber walls, which leads to increased unburned hydrocarbon emissions from the pre-chamber. In this study, a prototype liquid fuel injector is introduced which preheats the fuel within a heated chamber fitted with an electrical heating element before injecting an effervescently atomized spray into the pre-chamber.