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Combustion experiments were conducted with an optically accessible engine that allowed the entire bore area to be visualized for the purpose of making clear the characteristics that induce extremely rapid HCCI combustion and knocking accompanied by cylinder pressure oscillations. The HCCI combustion regime was investigated in detail by high-speed in-cylinder visualization of autoignition and combustion and emission spectroscopic measurements. The results revealed that increasing the equivalence ratio and advancing the ignition timing caused the maximum pressure rise rate and knocking intensity to increase. In moderate HCCI combustion, the autoignited flame was initially dispersed temporally and spatially in the cylinder and then gradually spread throughout the entire cylinder.

Attention has recently been focused on homogeneous charge compression ignition combustion (HCCI) as an effective combustion process for resolving the essential nature of combustion. Meanwhile, dimethylether (DME) has attracted interest as a potential alternative fuel for compression ignition engines. Authors measured the combustion process of DME HCCI by using a spectroscopic method. A diesel engine was used as the test engine. The results of these analyses showed that changes in the compression ratio, intake air temperature and equivalence ratio influenced the ignition timing in the HCCI combustion process. This paper discusses these effects in reference to the experimental and calculated results.

This study examined the effects of fuel composition and intake pressure on two-stage high temperature heat release characteristics of a Homogeneous Charge Compression Ignition (HCCI) engine. Light emission and absorption spectroscopic measurement techniques were used to investigate the combustion behavior in detail. Chemical kinetic simulations were also conducted to analyze the reaction mechanisms in detail. Blended fuels of dimethyl ether (DME) and methane were used in the experiments. It was found that the use of such fuel blends together with a suitable intake air flow rate corresponding to the total injected heat value gave rise to two-stage heat release behavior of the hot flame, which had the effect of moderating combustion. The results of the spectroscopic measurements and the chemical kinetic simulations revealed that the main reaction of the first stage of the hot flame heat release was one that produced CO from HCHO.

Emission intensity was measured at a wavelength of 395 2 nm (corresponding to the characteristic spectrum of the HCHO radical) and absorbance was measured at 306 4 nm (corresponding to that of the OH radical). The emission intensity and absorbance waveforms recorded during engine operation on n-heptane show behavior indicative of the passage and degeneracy of cool flame in the preflame reaction interval. As the combustion chamber wall temperature approached an overheated state in the transition from normal combustion to knocking operation different preflame reaction behavior was observed which is thought to correspond to the presence of a negative temperature coefficient region related to the ignition delay time.

The purpose of this research was to obtain a better understanding of engine knocking phenomena. Measurements were made of the behavior of formaldehyde (HCHO), an important intermediate product of cool flame reactions, and of the HCO radical, characterized by distinctive light emission during blue flame reactions. The test engine was operated on a blended fuel (50 RON) of n-heptane and iso-octane. Simultaneous measurements were made of the behavior of HCHO and the OH radical using absorption spectroscopy and of the behavior of HCO and OH radicals using emission spectroscopy. Absorbance spectroscopic measurements revealed behavior thought to correspond to the passage of a cool flame and emission spectroscopic measurements showed behavior thought to correspond to the passage of a blue flame.

There is an urgent need today to improve the thermal efficiency of spark- ignition (SI) engines in order to reduce carbon dioxide emission and conserve energy in an effort to prevent global warming. However, a major obstacle to improving thermal efficiency by raising the compression ratio of SI engine is the easily occurrence of engine knocking. The result of studies done by numerous researchers have shown that knocking is an abnormal combustion in which the unburned gas in the end zone of the combustion chamber autoignites. However, the combustion reaction mechanism from autoignition to the occurrence of knocking is still not fully understood. The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.

With the aim of elucidating the mechanism generating knock, an examination was made of the preflame reaction behavior of end gas in the combustion chamber in the transition from normal combustion to abnormal combustion characterized by the occurrence of knocking. Simultaneous measurements were made in the same cycle of the light absorption and emission behavior of the OH (characteristic spectrum of 306.4 nm), CH (431.5 nm) and C2 (516.5 nm) radicals in the end-gas region using spectroscopic methods. The absorbance behavior of a blue flame prior to autoignition is believed to be an important factor in the mechanism causing knock.

The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.(1-3) Absorption spectroscopy was used to measure the behavior of HCHO and OH radicals during a progression from normal combustion to knocking operation. Emission spectroscopic measurements were obtained in the same way that radical added HCO. Radical behavior in preflame reactions was thus examined on the basis of simultaneous measurements, which combined each absorption wavelength with three emission wavelength by using a monochromator and a newly developed polychromator.(4-5) When n-heptane (0 RON) and blended fuel (50 RON) were used as test fuel, it was observed that radical behavior differed between normal combustion and knocking operation and a duration of the preflame reaction was shorter during the progression from normal combustion to a condition of knocking.

Attention has recently been focused on homogeneous charge compression ignition (HCCI) as an effective combustion process for resolving issues inherent to the nature of combustion. Dimethyl ether (DME; CH3OCH3) has attracted interest as a potential alternative fuel for compression ignition engines. We measured the HCCI process of DME in a test diesel engine by using a spectroscopic method. Simultaneous measurements were also done on exhaust emissions of hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx). Based on the experimental data, this paper discusses the relationship between the equivalence ratio and the observed tendencies.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition. Light emission intensity was measured at wavelengths of 306.4 nm (characteristic spectrum of OH), 329.8 nm (HCO), 395.2 nm (HCHO). A four-cycle, air-cooled, single-cylinder gasoline engine with a side valve arrangement was used as the test engine. Light emission behavior was simultaneously observed at two positions (the end zone and the center zone) in the combustion chamber. The test fuel used was n-heptane (0 RON). The test engine was operated at three speed levels (1400, 1800 and 2200 rpm). As a result, preflame reactions were observed. It was also observed that the tendencies seen for the preflame reaction interval varied depending on the engine speed.

In this study, a spectroscopic method was used to measure the combustion characteristics of a test diesel engine when operated on dimethyl ether (DME) under a homogenous charge compression ignition (HCCI) combustion process. A numerical analysis was made of the elementary reactions using Chemkin 4.0 to perform the calculations. The results of the analysis showed that compression ratio changes and the methane additive influenced the autoignition timing in the DME-HCCI combustion process. In the experiments, reducing the compression ratio delayed the time of the peak cylinder pressure until after top dead center, thereby increasing the crankshaft output and thermal efficiency. The addition of methane enabled the DME-HCCI engine to provide crankshaft output equivalent to that seen for diesel engine operation at a low equivalence ratio. This paper discusses these effects in reference to the experimental and calculated results.

The composition ratio of saturated and unsaturated fatty acid methyl esters (FAME) is depended on feedstock. Three FAMEs: soybean (SME), palm (PME) and coconut oil (CME) methyl esters were mixed to make fuels which have different composition ratio. The ignitability of fuel which mainly consisted of unsaturated FAME was inferior. Power was slightly reduced with increasing of mixing ratio of CME; however exhaust gas emissions were improved because CME contained a lot of oxygen atoms. Fuel which was equal mixture SME and CME indicated almost the same ignition characteristic as that of PME because they have same composition ratio.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest as a combustion system that offers the advantages of high efficiency and low exhaust emissions. However, it is difficult to control the ignition timing in an HCCI combustion system owing to the lack of a physical means of initiating ignition like the spark plug in a gasoline engine or fuel injection in a diesel engine. Moreover, because the mixture ignites simultaneously at multiple locations in the cylinder, it produces an enormous amount of heat in a short period of time, which causes greater engine noise, abnormal combustion and other problems in the high load region. The purpose of this study was to expand the region of stable HCCI engine operation by finding a solution to these issues of HCCI combustion.

Homogeneous Charge Compression Ignition (HCCI) engines have attracted much attention and are being widely researched as engines characterized by low emissions and high efficiency. However, one issue of HCCI engines is their limited operating range because of the occurrence of rapid combustion at high loads and misfiring at low loads. It is known that knocking accompanied by in-cylinder pressure oscillations also occurs in HCCI engines at high loads, similar to knocking seen in spark-ignition engines. In this study, HCCI combustion accompanied by in-cylinder pressure oscillations was visualized by taking high-speed photographs of the entire bore area. In addition, the influence of internal exhaust gas circulation (EGR) on HCCI knocking was also investigated. The visualized combustion images revealed that rapid autoignition occurred in the end-gas region during the latter half of the HCCI combustion process when accompanied by in-cylinder pressure oscillations.

Technologies for further improving vehicle fuel economy have attracted widespread attention in recent years. However, one problem with some approaches is the occurrence of abnormal combustion such as low-speed pre-ignition (LSPI) that occurs under low-speed, high-load operating conditions. One proposed cause of LSPI is that oil droplets diluted by the fuel enter the combustion chamber and become a source of ignition. Another proposed cause is that deposits peel off and become a source of ignition. A four-stroke air-cooled single-cylinder engine was used in this study to investigate the influence of Ca-based additives having different properties on abnormal combustion by means of in-cylinder visualization and absorption spectroscopic measurements. The results obtained for neutral and basic Ca-based additives revealed that the former had an effect on advancing the time of autoignition.

One issue of downsized and supercharged engines is low-speed pre-ignition (LSPI) that occurs in the low-speed and high-load operating region. One proposed cause of LSPI is the influence of the engine oil and its additives. However, the effect of engine oil additives on pre-ignition and the mechanism involved are still not fully understood. This study investigated the influence of engine oil additives on abnormal combustion in a spark-ignition engine. A four-stroke air-cooled single-cylinder engine with a side valve arrangement was used in conducting combustion experiments. The research methods used were in-cylinder pressure analysis, in-cylinder visualization and absorption spectroscopic analysis. Engine oil additives were mixed individually at a fixed concentration into a primary reference fuel with an octane number of 50 and their effect on knocking was investigated.

Unresolved issues of Homogeneous Charge Compression Ignition (HCCI) combustion include an extremely rapid pressure rise on the high load side and resultant knocking. Studies conducted to date have examined ways of expanding the region of stable HCCI combustion on the high load side such as by applying supercharging or recirculating exhaust gas (EGR). However, the effect of applying EGR gas to supercharged HCCI combustion and the mechanisms involved are not fully understood. In this study, the effect of EGR gas components on HCCI combustion was investigated by conducting experiments in which external EGR gas was applied to supercharged HCCI combustion and also experiments in which nitrogen (N2) and carbon dioxide (CO2) were individually injected into the intake air pipe to simulate EGR gas components. In addition, HCCI combustion reactions were analyzed by conducting chemical kinetic simulations under the same conditions as those of the experiments.

In this research, the effect of high-temperature residual gas, resulting from the application of a certain level of EGR, on combustion was investigated using a two-stroke engine and alcohol fuels (ethanol and methanol) and gasoline as the test fuels. Measurements were made of the light emission intensity of the OH radical on the intake and exhaust port sides of the combustion chamber and of the combustion chamber wall temperature (spark plug washer temperature) and the exhaust gas temperature. Data were measured and analyzed in a progression from normal combustion to autoignited combustion to preignition and to knocking operation.

The Homogeneous Charge Compression Ignition (HCCI) engine has attracted much interest in recent years because it can simultaneously achieve high efficiency and low emissions. However, it is difficult to control the ignition timing with this type of engine because it has no physical ignition mechanism. Varying the amount of fuel supplied changes the operating load and the ignition timing also changes simultaneously. The HCCI combustion process also has the problem that combustion proceeds too rapidly. This study examined the possibility of separating ignition timing control and load control using an HCCI engine that was operated on blended test fuels of dimethyl ether (DME) and methane, which have vastly different ignition characteristics. The influence of the mixing ratios of these two test fuels on the rapidity of combustion was also investigated.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted much interest as a combustion system that can achieve both low emissions and high efficiency. But the operating region of HCCI combustion is narrow, and it is difficult to control the auto-ignition timing. This study focused on the use of a two-component fuel blend and supercharging. The blended fuel consisted of dimethyl ether (DME), which has attracted interest as alternative fuel for compression-ignition engines, and methane, the main component of natural gas. A spectroscopic technique was used to measure the light emission of the combustion flame in the combustion chamber in order to ascertain the combustion characteristics. HCCI combustion characteristics were analyzed in detail in the present study by measuring this light emission spectrum.