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Combustion experiments were conducted with an optically accessible engine that allowed the entire bore area to be visualized for the purpose of making clear the characteristics that induce extremely rapid HCCI combustion and knocking accompanied by cylinder pressure oscillations. The HCCI combustion regime was investigated in detail by high-speed in-cylinder visualization of autoignition and combustion and emission spectroscopic measurements. The results revealed that increasing the equivalence ratio and advancing the ignition timing caused the maximum pressure rise rate and knocking intensity to increase. In moderate HCCI combustion, the autoignited flame was initially dispersed temporally and spatially in the cylinder and then gradually spread throughout the entire cylinder.

The application of emulsified fuel for diesel engines is expected to reduce NOx and soot simultaneously. The purpose of this study is to clarify the influence of water content in emulsified fuel and fuel injection timing on diesel engine performance. The engine performance of emulsified fuel was compared with the water injection method. In the water injection test, water was injected to intake manifold and diesel fuel was directly injected into combustion chamber. Two emulsified fuels of which mixing ratio of water and emulsifier to diesel fuel were 15 and 30 vol.% were tested. Engine performance and exhaust gas emission of water injection method were almost similar to those of diesel fuel, so that water presented in combustion chamber had almost no influence on engine performance. Therefore, it can be considered that the micro explosion of fuel droplet enhanced the fuel atomization and mixing of fuel and air.

Emission intensity was measured at a wavelength of 395 2 nm (corresponding to the characteristic spectrum of the HCHO radical) and absorbance was measured at 306 4 nm (corresponding to that of the OH radical). The emission intensity and absorbance waveforms recorded during engine operation on n-heptane show behavior indicative of the passage and degeneracy of cool flame in the preflame reaction interval. As the combustion chamber wall temperature approached an overheated state in the transition from normal combustion to knocking operation different preflame reaction behavior was observed which is thought to correspond to the presence of a negative temperature coefficient region related to the ignition delay time.

The purpose of this research was to obtain a better understanding of engine knocking phenomena. Measurements were made of the behavior of formaldehyde (HCHO), an important intermediate product of cool flame reactions, and of the HCO radical, characterized by distinctive light emission during blue flame reactions. The test engine was operated on a blended fuel (50 RON) of n-heptane and iso-octane. Simultaneous measurements were made of the behavior of HCHO and the OH radical using absorption spectroscopy and of the behavior of HCO and OH radicals using emission spectroscopy. Absorbance spectroscopic measurements revealed behavior thought to correspond to the passage of a cool flame and emission spectroscopic measurements showed behavior thought to correspond to the passage of a blue flame.

There is an urgent need today to improve the thermal efficiency of spark- ignition (SI) engines in order to reduce carbon dioxide emission and conserve energy in an effort to prevent global warming. However, a major obstacle to improving thermal efficiency by raising the compression ratio of SI engine is the easily occurrence of engine knocking. The result of studies done by numerous researchers have shown that knocking is an abnormal combustion in which the unburned gas in the end zone of the combustion chamber autoignites. However, the combustion reaction mechanism from autoignition to the occurrence of knocking is still not fully understood. The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.

With the aim of elucidating the mechanism generating knock, an examination was made of the preflame reaction behavior of end gas in the combustion chamber in the transition from normal combustion to abnormal combustion characterized by the occurrence of knocking. Simultaneous measurements were made in the same cycle of the light absorption and emission behavior of the OH (characteristic spectrum of 306.4 nm), CH (431.5 nm) and C2 (516.5 nm) radicals in the end-gas region using spectroscopic methods. The absorbance behavior of a blue flame prior to autoignition is believed to be an important factor in the mechanism causing knock.

The study deals with the light absorption and emission behavior in the preflame reaction interval before hot flame reactions.(1-3) Absorption spectroscopy was used to measure the behavior of HCHO and OH radicals during a progression from normal combustion to knocking operation. Emission spectroscopic measurements were obtained in the same way that radical added HCO. Radical behavior in preflame reactions was thus examined on the basis of simultaneous measurements, which combined each absorption wavelength with three emission wavelength by using a monochromator and a newly developed polychromator.(4-5) When n-heptane (0 RON) and blended fuel (50 RON) were used as test fuel, it was observed that radical behavior differed between normal combustion and knocking operation and a duration of the preflame reaction was shorter during the progression from normal combustion to a condition of knocking.

In this study, optical measurements were made of the combustion chamber gas during operation of a Homogeneous Charge Compression Ignition (HCCI) engine in order to obtain a better understanding of the ignition and combustion characteristics. The principal issues of HCCI engines are to control the ignition timing and to optimize the combustion state following ignition. Autoignition in HCCI engines is strongly influenced by the complex low-temperature oxidation reaction process, alternatively referred to as the cool flame reaction or negative temperature coefficient (NTC) region. Accordingly, a good understanding of this low-temperature oxidation reaction process is indispensable to ignition timing control. In the experiments, spectroscopic measurement methods were applied to investigate the reaction behavior in the process leading to autoignition.

Attention has recently been focused on homogeneous charge compression ignition (HCCI) as an effective combustion process for resolving issues inherent to the nature of combustion. Dimethyl ether (DME; CH3OCH3) has attracted interest as a potential alternative fuel for compression ignition engines. We measured the HCCI process of DME in a test diesel engine by using a spectroscopic method. Simultaneous measurements were also done on exhaust emissions of hydrocarbons (HC), carbon monoxide (CO) and nitrogen oxides (NOx). Based on the experimental data, this paper discusses the relationship between the equivalence ratio and the observed tendencies.

Knocking is one phenomenon that can be cited as a factor impeding efforts to improve the efficiency of spark-ignition engines. With the aim of understanding knocking better, light emission spectroscopy was applied in this study to examine preflame reactions that can be observed prior to autoignition. Light emission intensity was measured at wavelengths of 306.4 nm (characteristic spectrum of OH), 329.8 nm (HCO), 395.2 nm (HCHO). A four-cycle, air-cooled, single-cylinder gasoline engine with a side valve arrangement was used as the test engine. Light emission behavior was simultaneously observed at two positions (the end zone and the center zone) in the combustion chamber. The test fuel used was n-heptane (0 RON). The test engine was operated at three speed levels (1400, 1800 and 2200 rpm). As a result, preflame reactions were observed. It was also observed that the tendencies seen for the preflame reaction interval varied depending on the engine speed.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest as a combustion system that offers the advantages of high efficiency and low exhaust emissions. However, it is difficult to control the ignition timing in an HCCI combustion system owing to the lack of a physical means of initiating ignition like the spark plug in a gasoline engine or fuel injection in a diesel engine. Moreover, because the mixture ignites simultaneously at multiple locations in the cylinder, it produces an enormous amount of heat in a short period of time, which causes greater engine noise, abnormal combustion and other problems in the high load region. The purpose of this study was to expand the region of stable HCCI engine operation by finding a solution to these issues of HCCI combustion.

Homogeneous Charge Compression Ignition (HCCI) engines have attracted much attention and are being widely researched as engines characterized by low emissions and high efficiency. However, one issue of HCCI engines is their limited operating range because of the occurrence of rapid combustion at high loads and misfiring at low loads. It is known that knocking accompanied by in-cylinder pressure oscillations also occurs in HCCI engines at high loads, similar to knocking seen in spark-ignition engines. In this study, HCCI combustion accompanied by in-cylinder pressure oscillations was visualized by taking high-speed photographs of the entire bore area. In addition, the influence of internal exhaust gas circulation (EGR) on HCCI knocking was also investigated. The visualized combustion images revealed that rapid autoignition occurred in the end-gas region during the latter half of the HCCI combustion process when accompanied by in-cylinder pressure oscillations.

Homogeneous Charge Compression Ignition (HCCI) combustion has attracted widespread interest because it achieves high efficiency and can reduce particulate matter (PM) and nitrogen oxide (NOx) emissions simultaneously. However, because HCCI engines lack a physical means of initiating ignition, it is difficult to control the ignition timing. Another issue of HCCI engines is that the combustion process causes the cylinder pressure to rise rapidly. The time scale is also important in HCCI combustion because ignition depends on the chemical reactions of the mixture. Therefore, we investigated the influence of the engine speed on autoignition and combustion characteristics in an HCCI engine. A four-stroke single-cylinder engine equipped with a mechanically driven supercharger was used in this study to examine HCCI combustion characteristics under different engine speeds and boost pressures.

Internal combustion engines today are required to achieve even higher efficiency and cleaner exhaust emissions. Currently, research interest is focused on premixed compression ignition (Homogeneous Charge Compression Ignition, HCCI) combustion. However, HCCI engines have no physical means of initiating ignition such as a spark plug or the fuel injection timing and quantity. Therefore, it is difficult to control the ignition timing. In addition, combustion occurs simultaneously at multiple sites in the combustion chamber. As a result, combustion takes place extremely rapidly especially in the high load region. That makes it difficult for the engine to operate stably at high loads. This study focused on the fuel composition as a possible means to solve these problems. The effect of using fuel blends on the HCCI operating region and combustion characteristics was investigated using a single-cylinder test engine.

Technologies for further improving vehicle fuel economy have attracted widespread attention in recent years. However, one problem with some approaches is the occurrence of abnormal combustion such as low-speed pre-ignition (LSPI) that occurs under low-speed, high-load operating conditions. One proposed cause of LSPI is that oil droplets diluted by the fuel enter the combustion chamber and become a source of ignition. Another proposed cause is that deposits peel off and become a source of ignition. A four-stroke air-cooled single-cylinder engine was used in this study to investigate the influence of Ca-based additives having different properties on abnormal combustion by means of in-cylinder visualization and absorption spectroscopic measurements. The results obtained for neutral and basic Ca-based additives revealed that the former had an effect on advancing the time of autoignition.

One issue of downsized and supercharged engines is low-speed pre-ignition (LSPI) that occurs in the low-speed and high-load operating region. One proposed cause of LSPI is the influence of the engine oil and its additives. However, the effect of engine oil additives on pre-ignition and the mechanism involved are still not fully understood. This study investigated the influence of engine oil additives on abnormal combustion in a spark-ignition engine. A four-stroke air-cooled single-cylinder engine with a side valve arrangement was used in conducting combustion experiments. The research methods used were in-cylinder pressure analysis, in-cylinder visualization and absorption spectroscopic analysis. Engine oil additives were mixed individually at a fixed concentration into a primary reference fuel with an octane number of 50 and their effect on knocking was investigated.

Unresolved issues of Homogeneous Charge Compression Ignition (HCCI) combustion include an extremely rapid pressure rise on the high load side and resultant knocking. Studies conducted to date have examined ways of expanding the region of stable HCCI combustion on the high load side such as by applying supercharging or recirculating exhaust gas (EGR). However, the effect of applying EGR gas to supercharged HCCI combustion and the mechanisms involved are not fully understood. In this study, the effect of EGR gas components on HCCI combustion was investigated by conducting experiments in which external EGR gas was applied to supercharged HCCI combustion and also experiments in which nitrogen (N2) and carbon dioxide (CO2) were individually injected into the intake air pipe to simulate EGR gas components. In addition, HCCI combustion reactions were analyzed by conducting chemical kinetic simulations under the same conditions as those of the experiments.

A new bio-fuel i.e. the cellulosic liquefaction fuel (CLF) was developed for diesel engines. CLF was made from woods by direct liquefaction process. When neat CLF was supplied to diesel engine, the compression ignition did not occur, so that blend of CLF and diesel fuel was used. The engine could be operated when the mixing ratio of CLF was up to 35 wt%. CO, HC and NOx emissions were almost the same as those of diesel fuel when the mixing ratio of CLF was less than 20 wt% whereas the thermal efficiency slightly decreases with increase in CLF mixing ratio.

There are strong demands today to further improve the thermal efficiency of internal combustion engines against a backdrop of various environmental issues, including rising carbon dioxide (CO2) emissions and global warming. One factor that impedes efforts to improve the thermal efficiency of spark ignition engines is the occurrence of knocking. The aim of this study was to elucidate the details of knocking based on spectroscopic measurements and visualization of phenomena in the combustion chamber of a test engine that was operated on three primary reference fuels with different octane ratings (0 RON, 30 RON, and 50 RON). The ignition timing was retarded in the experiments to delay the progress of flame propagation, making it easier to capture the behavior of low-temperature oxidation reactions at the time knocking occurred.

The use of a higher compression ratio is desirable for improving the thermal efficiency and specific power of spark-ignition engines, but it gives rise to a problem of engine knock. In the present research, an investigation was made of the role of the preflame reaction region of a spark-ignition engine in the occurrence of autoignition. Emission spectroscopy was used to measure the behavior of formaldehyde (HCHO) in a cool flame. In addition, measure the behavior of the faint light attributed to the HCO radical in a blue flame with the concurrent measurement of the OH radical. The emission waveforms measurements obtained for HCHO when n-heptane (ORON) was used as the fuel, It is thought that these tendencies correspond to the passage and degeneracy of a cool flame. Further, the emission waveforms measured for the HCO radical when blended fuels (6ORON, 8ORON) were correspond to that of a blue flame.