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When the alkali metal-supported catalyst was treated at 830°C, the NOx conversion decreased because the alkali metals in the catalyst layer gradually moved to the cordierite honeycomb layer and reacted with the cordierite elements. This phenomena decreased to be added the basic metal oxide (α) in the catalyst layer. The improved catalyst with α 2 showed higher performance than the conventional catalyst in the model gas test. Moreover, the emission values of NOx, HC, and CO were 50% or less than Japanese domestic regulation values even after 830°C×60h heat treatment in a vehicle test.

A catalyzed hydrocarbon (HC) trap aiming at the super-ultra low emission vehicle (SULEV) regulation was developed using a metal-impregnated zeolite. To enhance the adsorption and to raise the desorption temperature for a wide range of HC species, the modification of zeolite with certain metals was needed and Ag was found to be the most promising. Using a Ag impregnated zeolite, a three way catalyst was prepared, and its HC purification ability for a model gas simulating cold-start HCs was studied. Its heat resistance was also examined. A vehicle test for a fresh catalyzed HC trap showed that the cold-start HC after the newly developed trap almost reached the SULEV regulation level.