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Under the borderline autoignition conditions experienced during cold-starting of diesel engines, the amount and composition of residual gases may play a deterministic role. Among the intermediate species produced by misfiring and partially firing cycles, formaldehyde (HCHO) is produced in significant enough amounts and is sufficiently stable to persist through the exhaust and intake strokes to kinetically affect autoignition of the following engine cycle. In this work, the effect of HCHO addition at various phases of autoignition of n-heptane-air mixtures is kinetically modeled. Results show that HCHO has a retarding effect on the earliest low-temperature heat release (LTHR) phase, largely by competition for hydroxyl (OH) radicals which inhibits fuel decomposition. Conversely, post-LTHR, the presence of HCHO accelerates the occurrence of high-temperature ignition.

Misfiring or partial combustion during diesel engine operation results in the production of partial oxidation products such as ethylene (C₂H₄), carbon monoxide and aldehydes, in particular formaldehyde (HCHO). These compounds remain in the cylinder as residual gases to participate in the following engine cycle. Carbon monoxide and formaldehyde have been shown to exhibit a dual nature, retarding ignition in one temperature regime, yet decreasing ignition delay periods of hydrocarbon mixtures as temperatures exceed 1000°K. Largely unknown is the synergistic effects of such species. In this work, varying amounts of C₂H₄ and HCHO are added to the intake air of a naturally aspirated optical diesel engine and their combined effect on autoignition and subsequent combustion is examined. To observe the effect of these dopants on the low-temperature heat release (LTHR), ultraviolet chemiluminescent images are recorded using intensified CCD cameras.

As engine efficiency targets continue to rise, additional improvements must consider reduction of heat transfer losses. The development of advanced heat transfer models and realistic boundary conditions for simulation based engine design both require accurate in-cylinder wall temperature measurements. A novel dual wavelength infrared diagnostic has been developed to measure in-cylinder surface temperatures with high temporal resolution. The diagnostic has the capability to measure low amplitude, high frequency temperature variations, such as those occurring during the gas exchange process. The dual wavelength ratio method has the benefit of correcting for background scattering reflections and the emission from the optical window itself. The assumption that background effects are relatively constant during an engine cycle is shown to be valid over a range of intake conditions during motoring.

With increasing interest to reduce the dependency on gasoline and diesel, alternative energy source like compressed natural gas (CNG) is a viable option for internal combustion engines. Spark-ignited (SI) CNG engine is the simplest way to utilize CNG in engines, but direct injection (DI) Diesel-CNG dual-fuel engine is known to offer improvement in combustion efficiency and reduction in exhaust gases. Dual-fuel engine has characteristics similar to both SI engine and diesel engine which makes the combustion process more complex. This paper reports the computational fluid dynamics simulation of both DI dual-fuel compression ignition (CI) and SI CNG engines. In diesel-CNG dual-fuel engine simulations and comparison to experiments, attention was on ignition delay, transition from auto-ignition to flame propagation and heat released from the combustion of diesel and gaseous fuel, as well as relevant pollutants emissions.

A means of validating numerical simulations has been developed which utilizes chemiluminescence measurements from an internal combustion engine. By incorporating OH*, CH2O* and CO2* chemiluminescence sub-mechanisms into a detailed n-heptane reaction mechanism, excited species concentration and chemiluminescence light emission were calculated. The modeled line-of-sight chemiluminescence emission allows a direct comparison of simulation results to experimentally measured chemiluminescence images obtained during combustion in an optically accessible compression ignition engine using neat n-heptane fuel. The spray model was calibrated using in-cylinder liquid penetration length Mie scattering measurements taken from the jets of the high-pressure piezo injector.

Recent legislation entitled “The Single Fuel Forward Policy” mandates that all vehicles deployed by the US military be operable with aviation fuel (JP-8). Therefore, the authors are conducting an investigation into the influence of JP-8 on a diesel engine's performance. The injection, combustion, and performance of JP-8, 20-50% by weight in ULSD (diesel no.2) mixtures (J20-J50) produced at room temperature, were investigated in a small indirect injection, high compression ratio (24.5), 77mm separate combustion chamber diesel engine. The effectiveness of JP8 for application in an auxiliary power unit (APU) at continuous operation (100% load) of 4.78bar bmep/2400rpm was investigated. The blends had an ignition delay of approximately 1.02ms that increased slightly in relation to the amount of JP-8 introduced. J50 and diesel no.2 exhibited similar characteristics of heat release, the premixed phase being combined with the diffusion combustion.

Ultraviolet chemiluminescence has been observed in a diesel engine cyclinder during compression, but prior to fuel injection under engine starting conditions. During a portion of the warm-up sequence, the intensity of this emission exhibits a strong correlation to the phasing of the subsequent combustion. Engine exhaust measurements taken from a continuously misfiring, motored engine confirm the generation of formaldehyde (HCHO) in such processes. Fractions of this compound are expected to be recycled as residual to participate in the following combustion cycle. Spectral measurements taken during the compression period prior to fuel injection match the features of Emeleus' cool flame HCHO bands that have been observed during low temperature heat release reactions occurring in lean HCCI combustion. That the signal from the OH* bands is weak implies a buildup of HCHO during compression.

Low cetane JP-8 fuels have been identified as being difficult to use under conventional diesel operation. However, recent focus on low-temperature combustion (LTC) modes has led to an interest in distillate hydrocarbon fuels having high volatility and low autoignition tendency. An experimental study is performed to evaluate low-temperature combustion processes in a small-bore optically-accessible diesel engine operated in a partially-premixed combustion mode using low-cetane Sasol JP-8 fuel. This particular fuel has a cetane number of 25. Both single and dual injection strategies are tested. Since long ignition delay is a consequence of strong autoignition resistance, under the conditions examined, low cetane Sasol JP-8 combustion can only take place with a double injection strategy: one pilot injection event in the vicinity of exhaust TDC and one main injection event near firing TDC.

Emissions of Unburned Hydrocarbons (UHC) from diesel engines are a particular concern during the starting process, when after-treatment devices are typically below optimal operating temperatures. Drivability in the subsequent warm-up phase is also impaired by large cyclic fluctuations in mean effective pressure (MEP). This paper discusses in-cylinder wall temperature influence on unburned hydrocarbon emissions and combustion stability during the starting and warm-up process in an optical engine. A laser-induced phosphorescence technique is used for quantitative measurements of in-cylinder wall temperatures just prior to start of injection (SOI), which are correlated to engine out UHC emission mole fractions and combustion phasing during starting sequences over a range of charge densities, at a fixed fueling rate. Squish zone cylinder wall temperature shows significant influence on engine out UHC emissions during the warm-up process.

Biodiesel is a desirable alternative fuel for the diesel engine due to its low engine-out soot emission tendency. When blended with petroleum-based diesel fuels, soot emissions generally decrease in proportion to the volume fraction of biodiesel in the mixture. This paper presents an experimental investigation of biodiesel impact on in-cylinder soot temperature and concentrations in a single-cylinder, small-bore, optical access, compression ignition engine. While in-cylinder soot measurements have been widely performed with two-color thermometry implemented on digital cameras, their finite dynamic range limits the observation of soot due to its dramatically different radiation intensities. To expand the dynamic range of two-color measurements, this investigation utilizes three cameras. A high-speed CMOS color camera with a wide-band Bayer filter is used to obtain simultaneous measurements of soot temperature and KL factor for high intensity soot clouds within one cycle.

Three jet fuel surrogates were compared against their target fuels in a compression ignited optical engine under a range of start-of-injection temperatures and densities. The jet fuel surrogates are representative of petroleum-based Jet-A POSF-4658, natural gas-derived S-8 POSF-4734 and coal-derived Sasol IPK POSF-5642, and were prepared from a palette of n-dodecane, n-decane, decalin, toluene, iso-octane and iso-cetane. Optical chemiluminescence and liquid penetration length measurements as well as cylinder pressure-based combustion analyses were applied to examine fuel behavior during the injection and combustion process. HCHO* emissions obtained from broadband UV imaging were used as a marker for low temperature reactivity, while 309 nm narrow band filtered imaging was applied to identify the occurrence of OH*, autoignition and high temperature reactivity.

This paper presents an experimental investigation conducted to determine the parameters that control the behavior of autoignition in a small-bore, single-cylinder, optically-accessible diesel engine. Depending on operating conditions, three types of autoignition are observed: a single ignition, a two-stage process where a low temperature heat release (LTHR) or cool flame precedes the main premixed combustion, and a two-stage process where the LTHR or cool flame is separated from the main heat release by an apparent negative temperature coefficient (NTC) region. Experiments were conducted using commercial grade low-sulfur diesel fuel with a common-rail injection system. An intensified CCD camera was used for ultraviolet imaging and spectroscopy of chemiluminescent autoignition reactions under various operating conditions including fuel injection pressures, engine temperatures and equivalence ratios.

As a result of recent focus on the control of Low Temperature Combustion (LTC) modes, dual-fuel combustion strategies such as Reactivity Controlled Compression Ignition (RCCI) have been developed. Reactivity stratification of the auto-igniting mixture is thought to be responsible for the increase in allowable engine load compared to other LTC combustion modes such as Homogenous Charge Compression Ignition (HCCI). The current study investigates the effect of ethanol intake fuel injection on in-cylinder formaldehyde formation and stratification within an optically accessible engine operated with n-heptane direct injection using optical measurements and zero-dimensional chemical kinetic models. Images obtained by Planar Laser Induced Fluorescence (PLIF) of formaldehyde using the third harmonic of a pulsed Nd:YAG laser indicate an increase in formaldehyde heterogeneity as measured by the fluorescence signal standard deviation.

Fuel wall impingement commonly occurs in small-bore diesel engines. Particularly during engine starting, when wall temperatures are low, the evaporation rate of fuel film remaining from previous cycles plays a significant role in the autoignition process that is not fully understood. Pre-injection chemiluminescence (PIC), resulting from low-temperature oxidation of evaporating fuel film and residual gases, was measured over 3200 μsec intervals at the end of the compression strokes, but prior to fuel injection during a series of starting sequences in an optical diesel engine. These experiments were conducted to determine the effect of this parameter on combustion phasing and were conducted at initial engine temperatures of 30, 40, 50 and 60°C, at swirl ratios of 2.0 and 4.5 at 1000 RPM. PIC was determined to increase and be highly correlated with combustion phasing during initial cycles of the starting sequence.

The presence of OH radicals as a marker of the high temperature reaction region usually has been used to determine the lift-off length (LOL) in diesel engines. Both OH Laser Induced Fluorescence (LIF) and OH* chemiluminescence diagnostics have been widely used in optical engines for measuring the LOL. OH* chemiluminescence is radiation from OH being formed in the exited states (OH*). As a consequence OH* chemiluminescence imaging provides line-of-sight information across the imaged volume. In contrast, OH-LIF provides information on the distribution of radicals present in the energy ground state. The OH-LIF images only show OH distribution in the thin cross-section illuminated by the laser. When both these techniques have been applied in earlier work, it has often been reported that the chemiluminescence measurements result in shorter lift-off lengths than the LIF approach.

Due to the single fuel concept implemented by the US military, the soot production of diesel engines fueled with JP-8 has important implications for military vehicle visual signature and survivability. This work compares in-cylinder soot formation and oxidation of JP-8 and ULSD in a small-bore, optical diesel engine. Experimental engine-out soot emission measurements are compared to crank-angle resolved two-color measurements of soot temperature and optical thickness, KL. A 3-D chemical kinetic-coupled CFD model with line of sight integration is employed in order to investigate the soot distribution in a 2-D projection associated with the imaging plane, as well as to aid in interpreting the third dimension along the optical depth which is not available within the experimental work. The study also examines the effect of volatility on soot emission characteristics by CFD simulation.

"The Single Fuel Forward Policy" legislation enacted in the United States mandates that deployed U.S. military ground vehicles must be operable with aviation fuel (JP-8). This substitution of JP-8 for diesel raises concerns about the compatibility of this fuel with existing reciprocating piston engine systems. This study investigates the combustion, emissions, and performance characteristics of blends of JP-8 and Ultra Low Sulfur Diesel (ULSD) fuels with similar cetane numbers (CN), 48 (JP-8) and 47(ULSD), respectively, in a direct injection (DI) compression ignition engine over the load range of 3-8 bar imep at 1400 rpm. The results showed that JP-8 blends and ULSD had ignition delays ranging from approximately 1.0-1.4 ms and an average combustion duration time in the range of 47-65 CAD. Cylinder maximum heat flux values were found to be between 2.0 and 4.4 MW/m₂, with radiation flux increasing much faster than convection flux while increasing the imep.

An experimental fuel surrogate validation approach is proposed for a compression ignition application, and applied to validate a Jet-A POSF 4658 fuel surrogate. The approach examines the agreement of both physical and chemical properties of surrogate and target fuels during validation within a real compression-ignition engine environment during four sequential but distinct combustion phases. In-cylinder Mie Scattering measurements are applied to evaporating sprays to compare the behavior of the surrogate, its target fuel, and for reference, n-heptane. Early mixture formation and low temperature reaction behavior were investigated using 2-D broadband chemiluminescence imaging, while high temperature ignition and combustion chemistry were studied using OH chemiluminescence imaging. The optical measurements were combined with cylinder pressure-based combustion analysis, including ignition delay and premixed burn duration, to validate the global behavior of the surrogate.