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Time series analysis of diesel exhaust gas emissions under transient operation was carried out using a uniquely developed gas sampling system to efficiently collect all exhaust gas throughout transient cycles. The effects of fuel properties and other engine operation parameters on the exhaust emissions under transient runs when fuel amounts abruptly increase were analyzed. The results showed that THC increased abruptly to 2 or 6 times the final steady-state concentration immediately after the start of acceleration and then decreased to the steady-state values after 70∼200 cycles. At acceleration, NOx increased abruptly to about 80 % of the final NOx concentration, and then increased gradually to reach the final values after 60∼500 cycles. The behaviors of THC and NOx during transient operation can be described by exponential functions of the elapsed cycle numbers and the final emission concentrations.

Diesel soot suppression effects of catalytic fuel additives for a range of fuels with different properties were investigated with calcium naphthenate. A single cylinder DI diesel engine and a thermobalance were used to determine the soot reduction and its mechanism for seven kinds of fuels. Experimental results showed that the catalytic effect of the fuel additive was different for the different fuels, and could be described by a parameter considering cetane number and kinematic viscosity. The fuel additives reduced soot more effectively for fuels with higher cetane number and lower kinematic viscosity. This result was explained by soot oxidation characteristics for the different fuels. Oxidation of soot with the metallic additive proceeds in two stages: stage I, a very rapid oxidation stage; and stage II, a following slow or ordinary oxidation stage.

Diesel emissions are significant issue worldwide, and emissions requirements have become so tough that. the application of after-treatment systems is now indispensable in many countries To meet even more stringent future emissions requirements, it has become apparent that the improvement of market fuel quality is essential as well as the development in engine and exhaust after-treatment technology. Japan Clean Air Program II (JCAP II) is being conducted to assess the direction of future technologies through the evaluation of current automobile and fuel technologies and consequently to realize near zero emissions and carbon dioxide (CO2) emission reduction. In this program, effects of fuel properties on the performance of diesel engines and a vehicle equipped with two types of diesel NOx emission after-treatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. This report is designed to determine how high biodiesel blends affect oil quality through testing on 2005 regulations engines with DPFs. When blends of 10-20% rapeseed methyl ester (RME) with diesel fuel are employed with 10W-30 engine oil, the oil change interval is reduced to about a half due to a drop in oil pressure. The oil pressure drop occurs because of the reduced kinematic viscosity of engine oil, which resulting from dilution of poorly evaporated RME with engine oil and its accumulation, however, leading to increased wear of piston top rings and cylinder liners.

The effects of lubricant oil and fuel properties on low speed pre-ignition (LSPI) occurrence in boosted S.I. engines were experimentally evaluated with multi-cylinder engine and de-correlated oil and fuel matrices. Further, the auto-ignitability of fuel spray droplets and evaporated homogeneous fuel/oil mixtures were evaluated in a combustion bomb and pressure differential scanning calorimetry (PDSC) tests to analyze the fundamental ignition process. The work investigated the effect of engine conditions, fuel volatility and various lubricant additives on LSPI occurrence. The results support the validity of aspects of the LSPI mechanism hypothesis based on the phenomenon of droplets of lubricant oil/fuel mixture (caused by adhesion of fuel spray on the liner wall) flying into the chamber and autoigniting before spark ignition.

Quality control of gasoline constituents and its effect on the Intake Valve Deposits (IVD) has become a recent issue. In this paper, the effects of gasoline and oil quality on intake valve deposits were investigated using an Intake Valve Deposit Test Bench and a Sludge Simulator. The deposit formation from the gasoline maximized at an intake valve temperature of approximately 160 °C, and the deposits formed from the engine oil were maximum at approximately 250 °C. Therefore, the contribution of the gasoline or the engine oil appears to depend on the engine conditions. The gasoline which contains MTBE or ethanol with no detergent additive slightly increases the deposition amount. The gasoline with a superior detergent significantly decreases the deposition amount even when MTBE or ethanol is blended in the gasoline. Appropriate detergent fuel additive retards the oil deterioration.

In recent years, boosted and downsized engines have gained much attention as a promising technology to improve fuel economy; however, knocking is a common issue of such engines that requires attention. To understand the knocking phenomenon under downsized and boosted engine conditions deeply, fuels with different Research Octane Number (RON) and Motor Octane Number (MON) were prepared, and the knocking performances of these fuels were evaluated using a single cylinder engine, operated under a variety of conditions. Experimental results showed that the knocking performance at boosted conditions depend on both RON and MON. While higher RON showed better anti-knocking performance, lower MON showed better anti-knocking performance. Furthermore, the tendency for a reduced MON to be beneficial became stronger at lower engine speeds and higher boost pressures, in agreement with previously published modelling work.

The octane appetite of an engine is frequently characterised by the so-called K value. It is usually assumed that K is dependent only on the thermodynamic conditions in the engine when knock occurs. In this work we test this hypothesis: further analysis was conducted on experimental results from SAE 2019-01-0035 in which a matrix of fuels was tested in a single cylinder engine. The fuels consisted of a relatively small number of components, thereby simplifying the analysis of the chemical kinetic proprieties. Through dividing the original fuel matrix into subsets, it was possible to explore the variation of K value with fuel properties. It was found that K value tends to increase slightly with RON. The explanation for this finding is that higher RON leads to advanced ignition timing (i.e. closer to MBT conditions) and advanced ignition timing results in faster combustion because of the higher pressures and temperatures reached in the thermodynamic trajectory.

JCAPII gasoline workgroup reported vehicle emission study to comprehend the impact of ETBE blending. In previous study, we focused on the compatibility of ETBE blended gasoline with Japanese current gasoline vehicles in-use. Based on recent discussion with ETBE 8% blended gasoline into the market, more information becomes necessary. In this second report, we studied to comprehend the actual emission impact using realistic model fuels using several base stocks. Fuel properties of T50, T90 and aromatic compound content were selected through discussions. Specifications were changed within the range of the market. Both ETBE 0% and 8% were combined for these fuel matrixes. In total, eight fuels and two reference fuels were tested. Two J-ULEV vehicles (one MPI, and a stoichiometric-SIDI) were procured as representatives. We discussed quantitative and qualitative impact toward emissions. Data regarding CO2 and fuel economy change were also reported.

The influence of the molecular structure of hydrocarbon fuels on soot, SOF, and NOx emissions from a diesel engine was analyzed while ignition delay and other physical fuel properties were kept constant. Mixtures of normal paraffin (n-tetradecane) and iso-paraffin (heptamethylnonane) were used as a base fuel and one of 5 kinds of hydrocarbons including mono-aromatic, di-aromatic, and non-aromatic was added. The aromatic content varied in the range of 0-60 vol % for the mono-aromatic fuels and 0-40 vol % for the di-aromatic fuels. The experimental results showed that regardless of the molecular structure of the fuel, both particulate and NOx emissions increased linearly with the C/H atomic ratio of the fuels under constant ignition lag. The increase in particulate emissions with C/H atomic ratio was caused by increases in dry soot. The SOF, THC, and BSEC were little affected by the C/H atomic ratio and molecular structure of the fuels.

Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.

In Biodiesel Fuel Research Working Group(WG) of Japan Auto-Oil Program(JATOP), some impacts of high biodiesel blends have been investigated from the viewpoints of fuel properties, stability, emissions, exhaust aftertreatment systems, cold driveability, mixing in engine oils, durability/reliability and so on. In the impact on exhaust emissions, the impact of high biodiesel blends into diesel fuel on diesel emissions was evaluated. The wide variety of biodiesel blendstock, which included not only some kinds of fatty acid methyl esters(FAME) but also hydrofined biodiesel(HBD) and Fischer-Tropsch diesel fuel(FTD), were selected to evaluate. The main blend level evaluated was 5, 10 and 20% and the higher blend level over 20% was also evaluated in some tests. The main advanced technologies for exhaust aftertreatment systems were diesel particulate filter(DPF), Urea selective catalytic reduction (Urea-SCR) and the combination of DPF and NOx storage reduction catalyst(NSR).

The effects of gasoline fuel properties on exhaust emissions were investigated. Port injection LEVs, a ULEV, a prototype SULEV which were equipped with three–way (3–way) catalysts and also two vehicles with direct injection spark ignition (DISI) engines equipped with NOx storage reduction (NSR) catalysts were tested. Fuel sulfur showed a large effect on exhaust emissions in all the systems. In the case of the DISI engine with the NSR catalyst, NOx conversion efficiency and also regeneration from sulfur poisoning were dramatically improved by reducing sulfur from 30ppm to 8ppm. Distillation properties also affected the HC emissions significantly. The HC emissions increased in both the LEV and the ULEV with a driveability index (DI) higher than about 1150 (deg.F). The ULEV was more sensitive than the LEV. These results show that fuel properties will be important for future technologies required to meet stringent emission regulations.

Precise analytical methods for characterizing diesel fuel yielding the lowest particulate emissions were developed. The methods consist of preparative-scale high pressure liquid chromatography (HPLC), field ionization mass spectrometry (FIMS), analytical-scale HPLC, and carbon-13 nuclear magnetic resonance spectrometry (13C-NMR). A diesel fuel was first separated into an aliphatic fraction and an aromatic fraction by semipreparative-scale HPLC. Then, the aliphatic fraction was analyzed by FIMS and the spectrum was compared with that of the whole fuel. The aromatic fraction was analyzed by analytical-scale HPLC to obtain the chromatogram of the aromatic hydrocarbons with a high S/N. In addition to these analyses, the fuel was analyzed by 13C-NMR to obtain the concentration of the carbon atoms of the straight chain, branched chain and aromatic-ring in hydrocarbons.

The compositions of hydrocarbons in diesel fuel, exhaust gas and particulates were analyzed and the relationships among them were determined. It was found that the compositions of the hydrocarbons in the exhaust gas were almost the same as that of the fuel, and that the hydrocarbons in the particulates corresponded to their heavy fractions. When the engine condition was fixed, both the soluble organic fraction (SOF) and insoluble fraction ( ISF) showed positive correlation coefficients versus HC×R310, where HC denotes the hydrocarbon emission and R310 denotes the backend fraction, as measured by the fraction of fuel boiling above 310°C. On the other hand, when the engine condition was varied, ISF had negative correlation coefficients versus HC×R310, while SOF showed positive correlation coefficients.

The properties of diesel fuels were investigated in terms of particulate emissions to clarify the specification of such a diesel fuel for minimizing particulate emissions. Diesel fuels were analyzed using thin layer chromatography (TLC), and gas chromatography/mass spectrometry (GC/MS). These analysis revealed the entire composition of hydrocarbons in diesel fuels according to molecular formula. The entire composition of hydrocarbons in diesel fuels could be expressd on a three-dimensional graph: the X-axis as carbon number, the Y-axis as H/C ratio and the Z-axis as the amount of hydrocarbons of identical molecular formula. By using the graph, the properties reported so far were investigated. Also, simplified images of the fuel sprayed into a cylinder and its flame were derived from the observational results previously reported.

Engine dynamometer tests were conducted to evaluate the effect of detergent additives and gasoline components on Combustion Chamber Deposits (CCD). Additives with polyether amine (PEA) and with polyolefin amine (POA) chemicals were used. Three kinds of POA additives were used. Our results show that some kinds of additives and aromatics in gasoline increase CCD formation. Different polyolefin detergents show different tendency of CCD formation. The amount of CCD showed good relationship with the unwashed gum level of the gasoline. In general, smaller dosages produce less CCD. This means that detergents which have good IVD and PFID effectiveness at smaller dosage are better with regard to CCD. We analyzed the CCD by C13-NMR, GPC and IR method. The detergent contributes to CCD. Vehicle emissions tests were carried out to evaluate the effects of CCD on exhaust emissions.

In the Japan Clean Air Program II (JCAP II) Diesel WG, effects of fuel properties on the performance of two types of diesel NOx emission aftertreatment devices, a Urea-SCR system and a NOx storage reduction (NSR) catalyst system, were examined. For a Urea-SCR system, the NOx emission reduction performance with and without an oxidation catalyst installed in front of the SCR catalyst at low exhaust gas temperature operation was compared. For an NSR catalyst system, the effect of fuel sulfur on both emissions and fuel economy during 50,000 km driving was examined. Furthermore, effects of other fuel properties such as distillation on exhaust emissions were investigated. The results show that sulfur is the influential factor for both devices. Namely, high NOx emission reduction performance of the Urea-SCR system with the oxidation catalyst at low exhaust gas temperature operation is influenced by sulfur.

In response to various reformulated gasoline regulations, several studies have been conducted to evaluate the relationship between fuel properties and vehicle exhaust emissions. These studies, however, have focused on the fuel effect and have not examined the most promising advanced technology emission control systems on low emission vehicles. Toyota's reformulated gasoline research first set out to study the effect fuel compositions has on 2 different emission control systems. On both systems, non-methane hydrocarbon (NMHC) emissions were significantly affected by the 50% and 90% distillation temperature (T50 and T90). A correlation was also found exhaust olefine content and the amount of MTBE contained in the fuel. Research was also conducted on the specific ozone reactivity (SOR) of exhaust hydrocarbons. Various fuels with similar specifications but blended from different feedstocks were evaluated.

The 50% and 90% distillation temperature (T50 & T90), aromatics, olefins and sulfur content are regulated in California Phase2 Reformulated Gasoline. The effects of these properties on the exhaust emissions were investigated. Twelve test fuels with little interaction between T50, T90, aromatics and olefins were prepared. Exhaust emissions were measured using a TLEV according to 1975 Federal Test Procedure (75 FTP). T50 had a large effect on exhaust HC emissions. T90 also affected HC emissions. Both increasing and decreasing T50, T90 showed increasing exhaust HC emissions. These results suggest that an optimum range of T50 and T90 exist for lowering exhaust HC emissions. The effects of sulfur on exhaust emissions were also investigated. A Pt/Rh type catalyst (production type) and a Pd type catalyst (prototype) were prepared. These catalysts were put on a 94MY TLEV. Increase of sulfur lead to increase of the exhaust emissions with both catalysts.