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One type of TiO2 nanoparticles modified by stearic acid was prepared by sol-gel method and its structure was characterized using Laser Particle Analyzer (LPA) and Freeze-Etching Electron Microscopy (FEEM). To evaluate the benefits of the nanoparticles used as substitute for sulfurized olefins in gear oils, the tribological properties of a mixture of TiO2 nanoparticles with a S-containing additive in base oil were investigated using four-ball tribotester. The experimental results show that there are some synergistic effects between the two additives. In addition, the function mechanism of TiO2 nanoparticles in the tribological process was elucidated by the use of X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM).

Thermal efficiency comparisons are made between the low temperature combustion and the conventional diesel cycles on a common-rail diesel engine with a conventional diesel fuel. Empirical studies have been conducted under independently controlled exhaust gas recirculation, intake boost, and exhaust backpressure. Up to 8 fuel injection pulses per cylinder per cycle have been applied to modulate the homogeneity history of the early injection diesel low temperature combustion operations in order to improve the phasing of the combustion process. The impact of heat release phasing, duration, shaping, and splitting on the thermal efficiency has been analyzed with zero-dimensional engine cycle simulations. This paper intends to identify the major parameters that affect diesel low temperature combustion engine thermal efficiency.

The effects of hydrogen peroxide addition on iso-octane/air Homogeneous Charge Compression Ignition (HCCI) combustion have been investigated analytically. Particular attention was focused on the predications involving homogeneous gas-phase kinetics. Use was made of Peters' iso-octane mechanism in CHEMKIN and convective heat transfer was included in the analyses. This enabled the influences that H2O2 addition has on species concentration and ignition promotion and hence exhaust emissions to be determined. It was found that both CO and NOx emission levels could be ameliorated. The former effect is considered to be a result of the decomposition of H2O2 into OH intermediate species and hence reducing the time to ignition and the onset of combustion.

Conventionally, the diesel fuel ignites spontaneously following the injection event. The combustion and injection often overlap with a very short ignition delay. Diesel engines therefore offer superior combustion stability characterized by the low cycle-to-cycle variations. However, the enforcement of the stringent emission regulations necessitates the implementation of innovative diesel combustion concepts such as the low temperature combustion (LTC) to achieve ultra-low engine-out pollutants. In stark contrast to the conventional diesel combustion, the enabling of LTC requires enhanced air fuel mixing and hence a longer ignition delay is desired. Such a decoupling of the combustion events from the fuel injection can potentially cause ignition discrepancy and ultimately lead to combustion cyclic variations.

This work investigates the suitability of n-butanol for enabling PCCI, HCCI, and RCCI combustion modes to achieve clean and efficient combustion on a high compression ratio (18.2:1) diesel engine. Systematic engine tests are conducted at low and medium engine loads (6∼8 bar IMEP) and at a medium engine speed of 1500 rpm. Test results indicate that n-butanol is more suitable than diesel to enable PCCI and HCCI combustion with the same engine hardware. However, the combustion phasing control for n-butanol is demanding due to the high combustion sensitivity to variations in engine operating conditions where engine safety concerns (e.g. excessive pressure rise rates) potentially arise. While EGR is the primary measure to control the combustion phasing of n-butanol HCCI, the timing control of n-butanol direct injection in PCCI provides an additional leverage to properly phase the n-butanol combustion.

This study investigates neat n-butanol, as a cleaner power source, to directly replace conventional diesel fuels for enabling low temperature combustion on a modern common-rail diesel engine. Engine tests are performed at medium engine loads (6∼8 bar IMEP) with the single-shot injection strategy for both n-butanol and diesel fuels. As indicated by the experimental results, the combustion of neat n-butanol offers comparable engine efficiency to that of diesel while producing substantially lower NOx emissions even without the use of exhaust gas recirculation. The greater resistance to auto-ignition allows n-butanol to undergo a prolonged ignition delay for air-fuel mixing; the high volatility helps to enhance the cylinder charge homogeneity; the fuel-borne oxygen contributes to smoke reduction and, as a result, the smoke emissions of n-butanol combustion are generally at a near-zero level under the tested engine operating conditions.

In this work, an innovative piston bowl design that physically divides the combustion chamber into a central zone and a peripheral zone is employed to assist the control of the ethanol-diesel combustion process via heat release shaping. The spatial combustion zone partition divides the premixed ethanol-air mixture into two portions, and the combustion event (timing and extent) of each portion can be controlled by the temporal diesel injection scheduling. As a result, the heat release profile of ethanol-diesel dual-fuel combustion is properly shaped to avoid excessive pressure rise rates and thus to improve the engine performance. The investigation is carried out through theoretical simulation study and empirical engine tests. Parametric simulation is first performed to evaluate the effects of heat release shaping on combustion noise and engine efficiency and to provide boundary conditions for subsequent engine tests.

The majority of transportation systems have continued to be powered by the internal combustion engine and fossil fuels. Heavy-duty applications especially are reliant on diesel engines for their high brake efficiency, power density, and robustness. Although engineering developments have advanced engines towards significantly fewer emissions and higher efficiency, the use of fossil-derived diesel as fuel sets a fundamental threshold in the achievable total net carbon reduction. Dimethyl ether can be produced from various renewable feedstocks and has a high chemical reactivity making it suitable for heavy-duty applications, namely compression ignition direct injection engines. Literature shows the successful use of DME fuels in diesel engines without significant hardware modifications.

Extensive experiments were conducted on a low emission DI diesel engine by using Dimethyl Carbonate (DMC) as an oxygenate fuel additive. The results indicated that smoke reduced almost linearly with fuel oxygen content. Accompanying noticeable reductions of HC and CO were attained, while a small increase in NOx was encountered. The effective reduction in smoke with DMC was maintained with intake charge CO2, which led to low NOx and smoke emissions by the combined use of oxygenated fuel and exhaust gas recirculation (EGR). Further experiments were conducted on an optically accessible combustion bomb and a thermal cracking set-up to study the mechanisms of DMC addition on smoke reduction.

As a renewable energy source, the ethanol fuel was employed with a diesel fuel in this study to improve the cylinder charge homogeneity for high load operations, targeting on ultra-low nitrogen oxides (NOx) and smoke emissions. A light-duty diesel engine is configured to adapt intake port fuelling of the ethanol fuel while keeping all other original engine components intact. High load experiments are performed to investigate the combustion control and low emission enabling without sacrificing the high compression ratio (18.2:1). The intake boost, exhaust gas recirculation (EGR) and injection pressure are independently controlled, and thus their effects on combustion and emission characteristics of the high load operation are investigated individually. The low temperature combustion is accomplished at high engine load (16~17 bar IMEP) with regulation compatible NOx and soot emissions.

A number of cylinder-pressure derived parameters including the crank angles of maximum pressure, maximum rate of pressure rise, and 50% heat released are considered as among the desired feedback for cycle-by-cycle adaptive control of diesel combustion. For real-time computation of these parameters, the heat release analyses based on the first law of thermodynamics are used. This paper intends to identify the operating regions where the simplified heat release approach provides sufficient accuracy for control applications and also highlights those regions where its use can lead to significant errors in the calculated parameters. The effects of the cylinder charge-to-wall heat transfer and the temperature dependence of the specific heat ratio on the model performance are reported. A new computationally efficient algorithm for estimating the crank angle of 50% heat released with adequate accuracy is proposed for computation in real-time.

Diesel engines operating in the low-temperature combustion (LTC) mode generally tend to produce very low levels of NOx and soot. However, the implementation of LTC is challenged by the higher cycle-to-cycle variation with heavy EGR operation and the narrower operating corridors. The robustness and efficiency of LTC operation in diesel engines can be enhanced with improvements in the promptness and accuracy of combustion control. A set of field programmable gate array (FPGA) modules were coded and interlaced to suffice on-the-fly combustion event modulations. The cylinder pressure traces were analyzed to update the heat release rate concurrently as the combustion process proceeds prior to completing an engine cycle. Engine dynamometer tests demonstrated that such prompt heat release analysis was effective to optimize the LTC and the split combustion events for better fuel efficiency and exhaust emissions.

The pressure wave actions were investigated in the exhaust system of a single cylinder diesel engine through both experimental and simulation methods. The characteristics of the exhaust pressure waves under different engine operating conditions, such as engine load and exhaust backpressure, were examined. The results showed that the strength of the exhaust pressure wave was affected by both the in-cylinder pressure and the exhaust backpressure in the exhaust system during the period when the exhaust valves were open. The exhaust gas flow velocity was also estimated by the one dimensional simulation tool AVL BOOST™. The results suggested that the velocity of the exhaust gas fluctuated during the engine cycle, and followed trends similar to the exhaust pressure wave. The transient gas flow velocity was high when there was a strong compression wave, and it was reduced when the pressure fluctuations in the exhaust manifold were small.

Diesel engine exhausts commonly contain a high level of surplus oxygen and a significant amount of thermal energy. In this study the authors have theoretically investigated a way of utilizing the thermal energy and the surplus oxygen of exhaust gases to produce gaseous fuel in a rich combustor placed in an exhaust gas recirculation (EGR) loop. In the rich combustor, a small amount of diesel fuel will be catalytically reformed on a palladium/platinum based catalyst to produce hydrogen and carbon monoxide. Since the catalytic EGR reformer is incorporated in the EGR loop, it enables the partial recovery of exhaust heat. The gaseous fuel produced in the rich combustor can be brought back into the engine in a pre-mixed condition, potentially reducing soot formation. The preliminary energy efficiency analysis has been performed by using CHEMKIN and an in-house engine simulation software SAES.

The diesel fuel reforming process in an exhaust gas recirculation (EGR) loop of a diesel engine is capable of utilizing the engine exhaust energy to support the endothermic process of hydrogen gas generation. However, the EGR stream commonly needs to be heated to enable the operation of the reformer and thus to sustain higher yield of hydrogen. A central-fuelling and flow-reversal embedment that is energy-efficient to raise the central temperatures of the catalytic flow-bed is therefore devised and tested to drastically reduce the supplemental heating to the EGR reformer. One-dimensional modeling analyses are conducted to evaluate the fuel delivery strategies and temperature profiles of the reformer at various reforming gas flow rates and engine-out exhaust temperatures and compositions. This research attempts to quantify the energy saving by the catalytic flow-reversal and central-fuelling embedment in comparison to a unidirectional flow EGR reformer.

In order to improve the fuel economy for future high-efficiency spark ignition engines, the applications of advanced combustion strategies are considered to be beneficial with an overall lean and/or exhaust gas recirculation diluted cylinder charge. Stronger and more reliable ignition sources become more favorable under extreme lean/EGR conditions. Existing research indicates that the frequency of plasma restrikes increases with increased flow velocity and decreased discharge current level, and a higher discharge current can reduce the gap resistance and maintain the stretched plasma for a longer duration under flow conditions. An in-house developed current boost control system provides flexible control of the discharge current level and discharge duration. The current boost ignition system is based on a multi-coil system with a discharge current level of 180mA.

Compression ignition internal combustion engines provide unmatched power density levels, making them suitable for numerous applications including heavy-duty freight trucks, marine shipping, and off-road construction vehicles. Fossil-derived diesel fuel has dominated the energy source for CI engines over the last century. To mitigate the dependency on fossil fuels and lessen anthropogenic carbon released into the atmosphere within the transportation sector, it is critical to establish a fuel source which is produced from renewable energy sources, all the while matching the high-power density demands of various applications. Dimethyl ether (DME) has been used in non-combustion applications for several decades and is an attractive fuel for CI engines because of its high reactivity, superior volatility to diesel, and low soot tendency. A range of feedstock sources can produce DME via the catalysis of syngas.

The push for environmental protection and sustainability has led to strict emission regulations for automotive manufacturers as evident in EURO VII and 2026 EPA requirements. The challenge lies in maintaining fuel efficiency and simultaneously reducing the carbon footprint while meeting future emission regulations. Alcohol (primarily methanol, ethanol, and butanol) and ether (dimethyl ether) fuels, owing to their comparable energy density to existing fuels, the comparative ease of handling, renewable production, and suitable emission characteristics may present an attractive drop-in replacement, fully or in part as an additive, to the gasoline/diesel fuels, without extensive modifications to the engine geometry. Additionally, lean and diluted combustion are well-researched pathways for efficiency improvement and reduction of engine-out emissions of modern engines.

Low temperature combustion (LTC) has been proved to overcome the trade-off between NOx and soot emissions in direct injection compression ignition engines. However, the lowered NOx emissions are accompanied by high hydrocarbon and CO emissions. Moreover, the NOx emissions under LTC has much higher NO2 concentrations compared with traditional high temperature combustion conditions. Experimental investigations have been carried out to show the hydrocarbon impact on NOx emissions and NO-NO2 conversion under various engine operation conditions, but the mechanism is less understood. The article includes numerical studies of the impact of hydrocarbons in the in-cylinder conversion of NO to NO2 during low temperature conditions in a compression ignition engine. In the present work, a stochastic reactor model with detailed chemical kinetics is utilized to investigate the reaction pathways during the NOx reduction and NO2 conversion processes.

A novel catalytic converter technology, employing periodical reversal of gas flow through the oxidation catalyst monolith, is being developed for treatment of exhaust gas from diesel engines fueled by natural gas in combination with diesel fuel. This technology allows to trap heat energy inside the monolith and thus efficiently destroy methane at converter inlet temperature as low as ambient. This paper describes the results of the initial stage of the converter development, including development of the mathematical model, computer simulation, and prototype testing. Simulation results indicate that dual fuel engine equipped with the reverse-flow converter could exceed the required destruction standards for hydrocarbons, including methane.