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Diesel Engines are widely used in transportation, industrial and agriculture sectors worldwide due to their versatility and ruggedness. However, they also emit harmful emissions detrimental to human health and environment. Apart from environmental degradation, the perturbation in international crude oil prices is also mandating use of renewable fuels. In this context, vegetable oils such as Jatropha Curcas due to their carbon neutral nature and widespread availability, seems to present a promising alternative to the mineral diesel. Straight vegetable oils (SVO) are not recommended for direct diesel engine application due to their higher viscosity, poor volatility etc. and dilution of straight vegetable oil may effectively enable its direct application in unmodified diesel engines. In the present study, Jatropha oil was diluted with n-Butanol to improve the fuel properties of the blend.

Diesel engine widely uses in India in farming, transportation, and industrial sectors due to higher thermal efficiency, robust construction and heavy load carrying capacity. However, diesel engine emits a large number of gaseous emissions and particulate matter which caused serious detrimental environmental consequences and health hazards. The use of biofuel has shown a positive impact in resolving these issues of environmental degradation. India is also a net importer of petroleum-derived fuels and a substantial amount in precious foreign exchange is spent for this. In the last three decades in India, a lot of research work on renewable diesel-like fuels have been carried out, and the most promising of them is biodiesel. However,Biodiesel suffers from the drawback of relatively higher kinematic viscosity. But higher alcohols such as n-butanol and n-octanol could be blended with the biodiesel to bring its properties similar to diesel fuel.

Over the past several years, there has been increased interest in reformulated and alternative diesel fuel to control emissions and provide energy independence. As public concern about environmental pollution and energy security increases, alternative transportation fuels, such as compressed natural gas (CNG), liquefied natural gas (LNG), and bio-fuels are receiving more and more attention. Oil seed plants have been one of the biomass sources of fuel. In this study, use of macro- emulsion of vegetable oil in compression ignition engine as an alternative diesel fuel is carried out. The emphasize in this study is on non- edible vegetable oil as they are not used in house hold purposes. The macro-emulsion of linseed oil and mahua oil with neat diesel and alcohol in varying proportion were prepared and their properties in view of their suitability as a diesel fuel were evaluated. Also their performance and emission characteristics were tested in the C.I. engine.

The use of alternative fuel has many advantages and the main ones are its renewability, biodegradability with better quality exhaust gas emission, which do not contribute to raise the level of carbon dioxide in the atmosphere. The use of non-edible vegetables oils as an alternative fuels for diesel engine is accelerated by the energy crisis due to depletion of resources and increase in environmental problems. In Asian countries like India, great need of edible oil as a food so cannot use these oils as alternative fuels for diesel engine. However there are many issues related to the use of vegetable oils in diesel engine that is high viscosity, low calorific value, high self-ignition temperature etc. Jatropha curcas has been promoted in India as a sustainable substitute to diesel fuel. This research prepared micro emulsions of ethanol and Jatropha vegetable oil in different ratio and find out the physico-chemical parameters to compare with mineral diesel oil.

Globally, the demand for energy is increasing due to both increase in population and enhancement in the lifestyle of people. Most of the energy demand at present is met from fossil fuels, which are not only exhaustible but also a threat to the environment. Various routes of sustainable energy resources are being explored to address the above-mentioned issues and fuel made from used tyre may be one of the promising options. India is one of the fastest growing economies and every year 10 million new vehicles are registered. Due to poor road conditions, nearly fourfold tyres of this number are dumped as waste. This large stock of dumped tyres are non-biodegradable and creates other problems like a breeding site for mosquitos, or source of pollution in case of accidental fire. In order to cope with the large pile-up of used tyres, pyrolysis of these tyres could be a sustainable route.

The present consumption rates and heavy dependence on fossil fuels pose a humongous threat to the environment. The increased pollution in urban areas is already causing serious sociological, ecological and economic implications. The issue of energy security led governments and researchers to look for alternate means of renewable and environment friendly fuels. Biodiesel has been one of the promising, and economically viable alternatives. The biodiesels are reported to cause reduction in CO, HC and PM emissions. However, NOx emissions are increased in case of biodiesel in CI engine. Therefore, a Urea-SCR over Fe-ZSM5 honeycomb substrate (400cpsi) zeolite catalyst after treatment system is an effective technology to reduce emissions for biodiesel applications. Exhaust gases pass through the catalyst and reactions take place along its surface, consequently converting NOx into nitrogen and H2O.

Diesel engines are employed particularly in the field of heavy transportation and agriculture on account of their higher thermal efficiency and durability. As these engines, are the backbones of contemporary global transportation and accounts a 30% of world's energy consumption, which is second highest after the industrial sector. Therefore, the fossil fuel consumption becomes the prime concern. Following the global energy crisis and the increasingly stringent emission norms, the search for alternative renewable fuels has intensified. Currently, biodiesel (BD) has been identified as the most attractive and practical choice to replace fossil fuel as the main source of energy, due to the similarity in the properties with conventional diesel. However, its development and application have been hindered by the high cost of required feedstock. Therefore, in recent years, researchers have been seeking the alternative sources of non-edible oil which are economical.

Internal combustion engines are extensively used in every field of life in today's world. Diesel engines being more efficient are preferred in the industrial and transportation sector in comparison to spark ignition engines for their higher efficiency, versatility and ruggedness. The major emissions of diesel engines are oxides of nitrogen (NOx), particulate matter (PM), carbon dioxide (CO2), carbon monoxide (CO). Among these emissions, oxides of nitrogen (NOx) and the particulate matter are the reasons of serious concern. For reduction of oxides of nitrogen (NOx) and particulate matter simultaneously, the use of Homogeneous Charge Compression Ignition (HCCI) have provided a sustainable solution in the present scenario. Further, the use of CNG in HCCI engine along with pilot diesel injection; the emissions have been decreased drastically. Homogeneous mixing of fuel and air leads to cleaner combustion and lower emissions.

The rising cost and limited availability of crude oil in international market has provided an opportunity to look for substitute of fossil fuel. Scientists all over the world are experimenting on variety of renewable fuels for meeting the future energy demands. Bio origin fuels are fast becoming potential alternative resources to replace the fossil fuels. The vegetable oils, derived from oil seed crops have got 90 to 95% energy value of diesel on volume basis, comparable cetane number and can substitute upto 20% (v/v) of diesel fuel. Mahua seed oil is common ingredient of hydrogenated fat. Two-step transesterification process was employed to synthesize biodiesel from Mahua Oil (Madhuca-indica) and analysis of Physico-chemical properties as well as the combustion, performance and emission characteristics was done by taking 10, 20 and 100 % blend with diesel. The physico-chemical properties of the blends were found to be comparable to diesel.

In the past few decades, use of energy resources in industrial and transportation sector have reached to its peak resulting in depleting resources and environment squalor. Vegetable oils, which have properties comparable to diesel fuel, are considered promising alternative fuels for unmodified diesel engines. However, high viscosity of vegetable oils is a major challenge which could be reduced by blending with alcohols. The aim of the present study was to investigate the suitability of orange peel oil and n-butanol blends as an alternative fuel for CI engine. Various blends of butanol with orange peel oil were prepared on volumetric basis and named as B10OPO90 (10% n-butanol and 90% orange peel oil), B20OPO80 (20% n-butanol and 80% orange peel oil), B30OPO70 (30% n-butanol and 70% orange peel oil) and B40OPO60 (40% n-butanol and 60% orange peel oil). All blends were found homogenous and various physico-chemical properties were evaluated in accordance to relevant standards.

The growing energy demand and limited petroleum resources in the world have guided researchers towards the use of clean alternative fuels like alcohols for their better tendency to decrease the engine emissions. To comply with the future stringent emission standards, innovative diesel engine technology, exhaust gas after-treatment, and clean alternative fuels are required. The use of alcohols as a blending agent in diesel fuel is rising, because of its benefits like enrichment of oxygen, premixed low temperature combustion (LTC) and enhancement of the diffusive combustion phase. Several researchers have investigated the relationship between LTC operational range and cetane number. In a light-duty diesel engine working at high loads, a low-cetane fuel allowed a homogeneous lean mixture with improved NOx and smoke emissions joint to a good thermal efficiency.

Ever increasing consumption of fossil fuel and large scale deterioration of environment are mandating employment of renewable fuels. Researchers all over the world are experimenting on variety of alternative fuels for meeting future energy demands. Biodiesel is one of the most promising alternative fuels due to lower CO, HC and PM emissions. However, NOx emissions are increased in case of biodiesel in CI engine. The present study focuses on evaluation of performance and emission characteristics of a medium capacity diesel engine on blends of fish oil biodiesel and diesel blends employing EGR. Fish oil was transesterified with methyl alcohol to produce methyl ester. B20 blend of biodiesel was used since it balances the property differences with conventional diesel, e.g., performance, emission benefits and cost. Further, B20 blend can be used in automotive engines with no major modification. NOx formation takes place when combustion temperature is more than 2000K.

Rapid depletion of fossil fuels is urgently demanding an extensive research work to find out the viable alternative fuel for meeting sustainable energy demand without any environmental impact. In the future, our energy systems will need to be renewable, sustainable, efficient, cost-effective, convenient and safe. Therefore, researchers has shown interest towards alternative fuels like vegetable oils, alcohols, LPG, CNG, Producer gas, biogas in order to substitute conventional fuel i.e. diesel used in compression ignition (CI) engine. However, studies have suggested that trans-esterified vegetable oils retain quite similar physico-chemical properties comparable to diesel. Besides having several advantages, its use is restricted due to higher emissions i.e. NOx, CO, HC and deposits due to improper combustion. Hence, there is a need of cleaner fuel for diesel engines for the forthcoming stringent emissions norms and the fossil depletion.

Phenomenal industrial activities worldwide in the last couple of centuries have resulted in indiscriminate use of conventional energy resources and environmental degradation. The consumption of petroleum-derived fuels has increased exponentially due to enhanced mobility and also caused serious threat to earth's eco-system. The need to explore variety of alternative fuels in transportation sector has been the subject of research all over the world. In this context, alcohols like butanol and isopropyl alcohol seem to present a viable option for potential application in diesel engines. In the present investigation, 5%, 10%, 15%, 20% (v/v) blends of isopropyl alcohol and diesel was prepared. The various blends were found to be homogenous and stable. The exhaustive engine trials were carried out on a single-cylinder unmodified diesel engine. The results suggest significant reduction in emission of oxides of nitrogen (NOx for various blends as compared to baseline data of diesel.

The diesel engine has for many decades now assumed a leading role in both the medium and medium-large transport sector due to their high efficiency and ability to produce high torque at low RPM. Furthermore, energy diversification and petroleum independence are also required by each country. In response to this, biodiesel is being considered as a promising solution due to its high calorific value and lubricity conventional petroleum diesel. However, commercial use of biodiesel has been limited because of some drawbacks including corrosivity, instability of fuel properties, higher viscosity, etc. Biodiesel are known for lower CO, HC and PM emissions. But, on the flip side they produce higher NOx emissions. The addition of alcohol to biodiesel diesel blend can help in reducing high NOx produced by the biodiesel while improving some physical fuel properties.

Globally, transportation is the second largest energy consuming sector after the industrial sector and is completely dependent on petroleum products and alternative technologies. So, fossil fuel consumption for energy requirement is a primary concern and can be addressed with the fuel consumption reduction technologies. Transportation sector is mainly using diesel engines because of production of high thermal efficiency and higher torque at lower RPM. Therefore, diesel consumption should be targeted for future energy security and this can be primarily controlled by the petroleum fuel substitution techniques for existing diesel engines. Some of the fuel, which includes biodiesel, alcohol-diesel emulsions and diesel water emulsions etc. Among which the diesel water emulsion (DWE) is found to be most suitable fuel due to reduction in particulate matter and NOx emission, besides that it also improves the brake thermal efficiency.

In the present investigation AA6082/ SiC MMC composite is fabricated using electromagnetic stir casting technique. Silicon carbide (SiC) of 40 μm size is used as reinforcement and is varied by weight percentage as 0%, 2.5%, 5%, 7.5%, 10% in alloy AA6082. The microstructure of the fabricated composite is studied by scanning electron microscopy (SEM) which shows even distribution of the reinforcement. The mechanical properties improve with SiCp till 7.5%, after that the properties decreases which may be due to presence of porosity during the composite manufacturing. A comparative study of mechanical properties such as tensile strength, hardness and toughness has been done between the composite and base aluminium alloy. After the comparative study it was found that the composite having AA6082/SiC-92.5%/7.5% is best suited. So, it is used for optimization of Electrical Discharge Machining (EDM) process parameters using Taguchi’s design of experiment.

As neat crude palm oil is not ideally suitable as a fuel for diesel engines because of its high viscosity; process of transesterification was adopted to develop methyl ester of palm oil that approximate the properties and performance of hydrocarbon-based diesel fuel. Various properties of the methyl ester of palm oil were evaluated and compared in relation with that of neat diesel. The prepared methyl ester of palm oil, blended in different concentrations with neat diesel was then subjected to performance and emission tests in order to evaluate its suitability in diesel engine. The data thus generated were compared with base line data generated from neat diesel. An optimal blend of 10-20% methyl ester of palm oil with neat diesel exhibited best performance and smooth engine operation without any symptoms of undesired combustion phenomenon. This suggests use of 10-20% of biodiesel developed from palm oil in diesel engine with out any difficulty.

Biodiesel is a potential substitute for diesel and extensive research is carried in India on production and utilization of biodiesel from a variety of edible/non-edible, animal fat and waste oils. However, issues like stability, clogging, increased NOx, and high consumption rate etc. are some of the critical issues which are associated with long-term use of these alternative fuels in a diesel engine. The recent developments in science and technology may have concreted a method to create nano measure vigorous resources that have incredible benefits to micron sized constituents. Nano liquids may be a fresh period of compact-fluid complex constituents comprising of nano sized concrete elements disseminated into a base liquid. The present study investigates the effect of doping metal oxides nanoparticles with waste fish oil-based biodiesel. For the present study, the blends of fuel are prepared by using 30ppm each of titanium dioxide and alumina nanoparticles respectively.

Biodiesel in has gained great momentum in last few years and has been a subject of vast research all around the globe. Bulk of the research work carried out so far has been confined to production of methyl esters of vegetable oil that is known as biodiesel in the transesterification process. In the present study, jatropha oil ethyl ester (JOEE) was prepared using transesterification process with ethanol and KOH as a catalyst. The evaluation of important physico-chemical properties was carried and the properties were found within acceptable limits of ASTM/EN standards. A small capacity diesel engine was fuelled with different blends of JOEE and diesel and various performances, emission and combustion characteristics were evaluated. The results suggested that brake thermal efficiency was increased and emissions of carbon monoxide, hydrocarbons and smoke opacity were found lower for JOEE blend confirming better combustion due to the oxygenated fuel and higher cetane rating.