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This paper presents the results of an experimental investigation with five fuels (distillates, catalytically cracked, and vegetable oil blends - Cetane ratings from 20 to 70), which assessed: the accuracy of the ignition delay value displayed by the ignition delay meter specified by the ASTM D-613 Cetane rating method; the extent to which the accuracy of the meter is dependent on fuel type; the effect on Cetane Number value of errors in ignition delay introduced by the meter; ways in which the meter accuracy could be improved. The paper concludes that the major error in ignition delay displayed by the meter is fuel dependent, and can be ascribed to a particular part of the meter circuit. A way in which this weakness could be eliminated is described.

The measurement of the instantaneous flame temperature and soot concentration in the combustion chamber of a running diesel engine can provide useful information relating to the formation of two important exhaust pollutants, NOx and particulates. The two-colour method is based on optical pyrometry and it can provide estimates of the instantaneous flame temperature and soot concentration. The theoretical basis of the method is outlined in a companion paper. This paper deals with the practical problems involved in the construction of a working system, including suitable calibration techniques. The accuracy of the measurements of flame temperature and soot concentration is also discussed using results from a various sources.

The two-colour method is based on optical pyrometry and can readily be implemented at a modest cost for the measurement of the instantaneous flame temperature and soot concentration in the cylinders of diesel engines. With appropriate modification, this method can be applied to other continuous and intermittent combustion systems, such as those for gas turbine and boiler burners. This paper outlines the theoretical basis of the method, with particular attention being paid to the assumptions relating to the evaluation of the flame temperature and soot concentration. A companion paper deals with the practical problems involved in constructing a working system, including suitable calibration techniques, and assessment of the method accuracy.

A mathematical model has been developed which describes the evaporation and trajectories of fuel droplets during their flight in the inlet manifold of port-injected gasoline engines. Based on the model, a computer simulation program was developed, and sample results of this program are given in this paper. Extensive results obtained using the simulation program are described in a companion paper. The simulation program can be used as a tool to improve understanding of mixture preparation in port injected engines. Such effects as: engine load and speed, air and fuel temperature, fuel type, fuel injection velocity, injection timing, and spray droplet size can be investigated.

The fuel economy and emissions performance of a Diesel engine is strongly influenced by the fuel injection process. This paper presents early results of an experimental investigation into diesel spray development carried out in a novel in-house developed optical pressure chamber capable of operating at pressure up to 50 bar and temperatures up to 900 K. The spatial evolution of a diesel spray tends to experience many transitory macroscopic phenomena that directly influence the mixing process. These phenomena are not considered highly reproducible and are extremely short lived, hence recording and understanding these transient effects is difficult. In this study, high-speed backlight-illuminated imaging has been employed in order to capture the transient dynamics of a short signal duration diesel spray injected into incremental back pressures and temperatures reaching a maximum of 10 bar and 473 K respectively.

The paper first describes three linked computational models which allow the estimation of: swirl generated during the induction process; the modification of swirl with bowl-in-piston combustion chambers during compression as the piston approaches top dead centre; the interaction of the fuel sprays with swirl including relative crosswind velocities between the air and the fuel sprays and spray impingement velocities. The paper then presents experimental results from a single-cylinder direct injection diesel engine, during which both the fuel spray and swirl parameters were changed systematically. Finally, the predicted spray impingement and crosswind velocities for this engine are correlated with the engine performance obtained experimentally, in particular, with fuel economy and smoke emission.

Tumble and swirl motions in the cylinder of a four-valve SI engine with production type cylinder head were investigated using a cross-correlation digital Particle Image Velocimetry (PIV). Tumble motion was measured on the vertical symmetric plane of the combustion chamber. Swirl motion was measured on a plane parallel to the piston crown with one of intake ports blocked. Large-scale flow behaviours and their cyclic variations were analysed from the measured two-dimensional velocity data. Results show that swirl motion is generated at the end of the intake stroke and persists to the end of the compression stroke. Tumble vortex is produced in the early stage of the compression stroke and distorted in the late stage of the stroke. The cyclic variation of swirl motion is noticeable. The cyclic variation in tumble dominated flow field is much greater.

This paper is concerned with the performance of the sensors and associated instrumentation used for the standard cetane tests for diesel fuels according to the ASTM D-613 procedure. The two primary sensors are replaced by modern units, and the analogue monitoring system is replaced by a digital one; the changes in the performance of the instrumentation system are then assessed. It is shown that the main source of inaccuracy in the measurement of ignition delay (on which the cetane test is based) is cyclic instability in the start of combustion, and that the current instrumentation and monitoring methods do not cope well with this instability. Although some of the cyclic variation can be ascribed to the instrumentation system, a large part is contributed by variability in the fuel ignition and injection processes. Improvements to the instrumentation and monitoring systems are presented and assessed.

Comparisons have been made between the ignition delay and combustion performance of sunflower oil and diesel fuel. The experimental results have been obtained in a naturally aspirated direct injection diesel engine, and particular attention has been given to the heat release analysis, ignition delay, combustion noise and lubricant degradation. The anomalous behaviour of sunflower oil is explained by reference to its physical properties and ignition quality, as reported in the literature from bomb tests. It is concluded that the power output and brake efficiency are largely unaffected by the use of the sunflower oil, and that lubricant degradation is not likely to be significant. However, the build up of combustion deposits already widely reported in the literature was observed. Suggestions are made as to how this might be ameliorated through modifications to the injection system.

For a spark-ignition engine, the parasitic loss suffered as a result of conventional throttling has long been recognised as a major reason for poor part-load fuel efficiency. While lean, stratified charge, operation addresses this issue, exhaust gas aftertreatment is more challenging compared with homogeneous operation and three-way catalyst after-treatment. This paper adopts a different approach: homogeneous charge direct injection (DI) operation with variable valve actuations which reduce throttling losses. In particular, low-lift and early inlet valve closing (EIVC) strategies are investigated. Results from a thermodynamic single cylinder engine are presented that quantify the effect of two low-lift camshafts and one standard high-lift camshaft operating EIVC strategies at four engine running conditions; both, two- and single-inlet valve operation were investigated. Tests were conducted for both port and DI fuelling, under stoichiometric conditions.

A Waukesha VR 220 naturally aspirated Diesel Engine has been modified to operate with a high compression ratio fast-burn spark-ignition combustion system. Since the application of greatest interest is for Combined Heat and Power (CHP), the majority of data have been obtained with the engine operating at full throttle and 1500 rpm. The philosophy of the open chamber combustion system design is described, and this includes a discussion on the selection of the compression ratio. Results are presented for the energy balance and the emissions, for a wide range of air fuel ratios. The experiments have been conducted with natural gas and natural gas/carbon dioxide mixtures (to simulate bio-gas). Comparisons are made with the baseline engine performance data, some of which has been published earlier(1)*.

Development of new fuels and engine combustion strategies for future ultra-low emission engines requires a greater level of insight into the process of emissions formation than is afforded by the approach of engine exhaust measurement. The paper describes the development of an in-cylinder gas sampling system consisting of a fast-acting, percussion-based, poppet-type sampling valve, and a heated dilution tunnel; and the deployment of the system in a single cylinder engine. A control system was also developed for the sampling valve to allow gas samples to be extracted from the engine cylinder during combustion, at any desired crank angle in the engine cycle, while the valve motion was continuously monitored using a proximity sensor. The gas sampling system was utilised on a direct injection diesel engine co-combusting a range of hydrogen-diesel fuel and methane-diesel fuel mixtures.

Biodiesel is a renewable fuel which can be used as a direct replacement for fossil Diesel fuel as a calorific source in Diesel Engines. It consists of fatty acid mono-alkyl esters, which are produced by the trans-esterification reaction of plant oils with monohydric alcohols. The Plant oils and alcohols can both be derived from biomass, giving this fuel the potential for a sustainable carbon dioxide neutral life-cycle, which is an important quality with regard to avoiding the net emission of anthropogenic greenhouse gases. Depending on its fatty ester composition, Biodiesel can have varying physical and chemical properties which influence its combustion behaviour in a Diesel engine. It has been observed by many researchers that Biodiesel can sometimes lead to an increase in emissions of oxides of nitrogen (NOx) compared to fossil Diesel fuel, while emitting a lower amount of particulate mass.

The effects of Air/Fuel (A/F) ratios and Exhaust Gas Re-Circulation (EGR) rates on Homogeneous Charge Compression Ignition (HCCI) combustion of n-heptane have been experimentally investigated. The experiments were carried out in a single-cylinder, 4-stroke and variable compression-ratio engine equipped with a port fuel injector. Investigations concentrate on the HCCI combustion of n-heptane at different A/F ratios, EGR rates and their effects on knock limit, engine load, combustion variability, and engine-out emissions such as NOx, CO, and unburned HC. Variations of auto-ignition timings and combustion durations in the two-stage combustion process are analyzed in detail. Results show that HCCI combustion with a diesel type fuel can be implemented at room temperature with a conventional diesel engine compression-ratio. However, its knock limit occurs at very high A/F ratios, although high EGR rates can be tolerated.

Synthetic bio-fuels, which can be obtained through the gasification of biomass into synthesis gas and the subsequent catalytic reaction of the synthesis gas into liquid fuel molecules, could play a key-role in providing a sustainable source of automotive fuels during the coming decades. This paper presents an attempt to understand the effect of molecular structure of potential oxygenated synthetic bio-fuel molecules of different structure on the diesel combustion process in both stratified and homogeneous combustion modes. Specifically, the effects of molecular structure on the energy release rates, gaseous exhaust emissions and the sub-micron particulate matter distribution were examined. The experiments were carried out on a single-cylinder direct-injection diesel engine using a specially adapted common-rail fuel-system which allowed the injection of small single-molecule fuel samples at high pressure.

Improvements in the efficiency of internal combustion engines and the development of renewable liquid fuels have both been deployed to reduce exhaust emissions of CO2. An additional approach is to scrub CO2 from the combustion gases, and one potential means by which this might be achieved is the reaction of combustions gases with sodium borohydride to form sodium carbonate. This paper presents experimental studies carried out on a modern direct injection diesel engine supplied with a solution of dissolved sodium borohydride so as to investigate the effects of sodium borohydride on combustion and emissions. Sodium borohydride was dissolved in the ether diglyme at concentrations of 0.1 and 2 % (wt/wt), and tested alongside pure diglyme and a reference fossil diesel. The sodium borohydride solutions and pure diglyme were supplied to the fuel injector under an inert atmosphere and tested at a constant injection timing and constant engine indicated mean effective pressure (IMEP).

A novel approach was proposed and investigated to reduce unburned hydrocarbon emissions from spark-ignition engines using in-cylinder catalysts. The unburned hydrocarbons in spark-ignition engines arise primarily from sources near the combustion chamber walls, such as flame quenching at the entrance of crevice volumes and at the combustion chamber wall, and the absorption and desorption of fuel vapour into oil layers on the cylinder wall. The proximity of these sources of unburned hydrocarbons to the wall means that they can be reduced significantly by simply using in-cylinder catalysts on the combustion chamber walls, in particular on the surfaces of the crevice volumes. A platinum-rhodium coating was deposited on the top and side surfaces of the piston crown, and its effects on the engine combustion and emission characteristics were examined in this experimental investigation.

In order to take advantage of different properties of fuel components or fractions, a new concept of fuel stratification has been proposed by the authors. This concept requires that two fractions of standard gasoline (e.g., light and heavy fractions) or two different fuels in a specially formulated composite be introduced into the cylinder separately through two separate intake ports. The two fuels will be stratified into two regions in the cylinder by means of strong tumble flows. In order to verify and optimize the fuel stratification, a two-tracer Laser Induced Fluorescence (LIF) technique was developed and applied to visualize fuel stratification in a three-valve twin-spark SI engine. This was realized by detecting simultaneously fluorescence emissions from 3-pentanone in one fuel (hexane) and from N,N-dimethylaniline (DMA) in the other fuel (iso-octane).

Fast throttle opening in port-injected gasoline engines often results in a lean air-fuel ratio excursion lasting several engine cycles. Even when the engine is equipped with a three-way catalyst this lean excursion can lead to high tailpipe emissions. This paper will describe an in-cylinder method of measuring these air-fuel ratio excursions, using a fast flame ionisation detector. Examples will be given of air-fuel ratio excursions obtained on a four-valve-per-cylinder sequentially-injected gasoline engine equipped with a lambda sensor. The air-fuel ratio excursions together with measurements of the engine air flow are used to estimate me build up of the fuel film on the inlet manifold walls. Whilst air-fuel ratio excursions have been recorded previously by other investigators, their results were obtained from exhaust gas analysis using fast oxygen sensors.

A novel experimental technique was used to investigate the in-cylinder air-fuel ratio excursions of a port-injected spark-ignition engine during load and fuel transients. This involved sampling directly from the engine cylinder using a fast flame ionisation detector (FID) system throughout an engine transient test. All tests were conducted with the coolant at the normal operating temperature of 90°C. The research engine used was a 1.6ltr four-cylinder multi-point fuel injection spark-ignition (SI) engine with four-valves-per-cylinder, with sequential injection and an electronic management system. The engine transient involved a rapid throttle opening within about 15msec. Various load steps were investigated at 2000rev/min along with the effect of altering the type of fuel injector.