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Three synthetic fuels, derived from coal, were compared to a Phillips DF-2 control fuel. These fuels were tested in a single-cylinder, direct-injected, Diesel engine. Comparisons were made on the basis of performance, combustion characteristics, gas-phase emissions including aldehydes, and particulate emissions. In addition, the mutagenic activity of the soluble organic compounds from the particulates were analyzed using the Ames test. The objective of these experiments was to determine how well the synthetic fuels would perform as direct replacements for DF-2. All three synthetic fuels were manufactured from an initial batch of middle distillates produced by the Exxon Donor Solvent (EDS) process. The first fuel was a blend of the EDS middle distillate and the baseline DF-2 with a cetane number of 35.

Two fundamental aspects of HCCI engine combustion have been investigated using a single-zone model with time-varying compression and the full chemical-kinetic mechanisms for iso-octane, a representative liquid-phase fuel. This approach allows effects of the kinetics and thermodynamics to be isolated and evaluated in a well-characterized manner, providing an understanding of the selected fundamental processes. The computations were made using the CHEMKIN-III kinetic-rate code for an 1800 rpm operating condition. The study consists of two parts. First, low-load HCCI operation was investigated to determine the role of bulk-gas reactions as a source for HC and CO emissions. The computations show that as fueling is reduced to equivalence ratios of 0.15 and lower (very light load and idle), the bulk-gas reactions do not go to completion, leading to inefficient combustion and high emissions of HC and CO.

A phenomenological description, or “conceptual model,” of how direct-injection (DI) diesel combustion occurs has been derived from laser-sheet imaging and other recent optical data. To provide background, the most relevant of the recent imaging data of the author and co-workers are presented and discussed, as are the relationships between the various imaging measurements. Where appropriate, other supporting data from the literature is also discussed. Then, this combined information is summarized in a series of idealized schematics that depict the combustion process for a typical, modern-diesel-engine condition. The schematics incorporate virtually all of the information provided by our recent imaging data including: liquid- and vapor-fuel zones, fuel/air mixing, autoignition, reaction zones, and soot distributions.

A combined experimental and modeling study has been conducted to investigate the sources of CO and HC emissions (and the associated combustion inefficiencies) at low-loads. Engine performance and emissions were evaluated as fueling was reduced from knocking conditions to very low loads (ϕ = 0.28 - 0.04) for a variety of operating conditions, including: various intake temperatures, engine speeds, compression ratios, and a comparison of fully premixed and GDI (gasoline-type direct injection) fueling. The experiments were conducted in a single-cylinder engine (0.98 liters) using iso-octane as the fuel. Comparative computations were made using a single-zone model with the full chemistry mechanisms for iso-octane, to determine the expected behavior of the bulk-gases for the limiting case of no heat transfer, crevices, or charge inhomogeneities.

An experimental study has been conducted to characterize NO and soot evolution in an optically-accessible D.I. diesel engine with a square combustion chamber. Two-dimensional laser-induced fluorescence was used to characterize NO evolution. Soot evolution was characterized by two-dimensional laser-induced incandescence (LII) and Mie scattering techniques as well as direct photography of the flame luminosity. The engine operating parameters were set to provide optimum conditions for NO imaging. Attenuation of the UV beam proved to be the major obstacle in obtaining NO images. Therefore, oxygen was added to the intake air charge in order to reduce the optical density of the combustion medium. The NO images showed that the NO formation started almost immediately after ignition and ceased no later than 40 degrees ATDC. No soot images could be obtained by the laser-induced incandescence or Mie scattering methods before 20 degrees ATDC since the soot concentration was very low.

Six chemically defined fuels have been run in a 2.0 liter production engine, in both a deposit-free and deposited state, at five different operating (speed/load) conditions. The fuel used to produce the deposits minimized the development of deposits in the intake system, so that primarily the effect of combustion chamber deposits were considered in this study. The six chemically defined fuels investigated were based on an iso-octane and toluene mix (base fuel). Methyl tertiary butyl ether, cyclohexane, diisobutylene, 1,2,4 trimethylbenzene and ethylbenzene were added to this base fuel to form five tertiary fuel mixtures. Engine-out emissions of speciated hydrocarbons, NOx, CO and CO2 were measured for the base fuel and five tertiary fuel mixtures in both the deposit-free and deposited state. NOx emissions were seen to increase relative to the base fuel for the cyclohexane and ethylbenzene tertiary fuel mixtures.

Chemiluminescence imaging has been applied to investigate the naturally occurring charge stratification in an HCCI engine. This stratification slows the pressure-rise rate (PRR) during combustion, making it critical to the high-load operating limit of these engines. Experiments were conducted in a single-cylinder HCCI engine modified with windows in the combustion chamber for optical access. Using this engine, chemiluminescence images were obtained from three different view angles. These included both single-shot images with intensified CCD cameras and high-speed (20kHz) sequences with an intensified CMOS video camera. The engine was fueled with iso-octane, which has been shown to be a reasonable surrogate for gasoline and exhibits only single-stage ignition at these naturally aspirated conditions. The chemiluminescence images show that the HCCI combustion is not homogeneous but has a strong turbulent structure even when the fuel and air are fully premixed prior to intake.

Combustion phasing is one important issue that must be addressed for HCCI operation. The intake temperature can be adjusted to achieve ignition at the desired crank angle. However, heat-transfer during induction will make the effective intake temperature different from the temperature measured in the runner. Also, depending on the engine speed and port configuration, dynamic flow effects cause various degrees of charge heating. Additionally, residuals from the previous cycle can have significant influence on the charge temperature at the beginning of the compression stroke. Finally, direct injection of fuel will influence the charge temperature since heat is needed for vaporization. This study investigates these effects in a systematic manner with a combination of experiment and cycle simulation using WAVE from Ricardo.

This paper studies autoignition characteristics and HCCI engine combustion of ketone fuels, which are important constituents of recently discovered fungi-derived biofuels. Two ketone compounds, 2,4-dimethyl-3-pentanone (DMPN) and cyclopentanone (CPN), are systematically investigated in the Sandia HCCI engine, and the results are compared with conventional gasoline and neat ethanol. It is found that CPN has the lowest autoignition reactivity of all the biofuels and gasoline blends tested in this HCCI engine. The combustion timing of CPN is also the most sensitive to intake-temperature (Tin) variations, and it is almost insensitive to intake-pressure (Pin) variations. These characteristics and the overall HCCI performance of CPN are similar to those of ethanol. In contrast, DMPN shows multi-faceted autoignition characteristics. On the one hand, DMPN has strong temperature-sensitivity, even at boosted Pin, which is similar to the low-reactivity ethanol and CPN.

This study investigates the potential of partial fuel stratification for reducing the knocking propensity of intake-boosted HCCI engines operating on conventional gasoline. Although intake boosting can substantially increase the high-load capability of HCCI, these engines would be more production-viable if the knock/stability load limit could be extended to allow higher loads at a given boost and/or to provide even higher thermal efficiencies. A technique termed partial fuel stratification (PFS) has recently been shown to greatly reduce the combustion-induced pressure-rise rate (PRR), and therefore the knocking propensity of naturally aspirated HCCI, when the engine is fueled with a φ-sensitive, two-stage-ignition fuel. The current work explores the potential of applying PFS to boosted HCCI operation using conventional gasoline, which does not typically show two-stage ignition. Experiments were conducted in a single-cylinder HCCI research engine (0.98 liters) at 1200 rpm.

High-load HCCI combustion has recently been demonstrated with conventional gasoline using intake pressure boosting. The key is to control the high combustion heat release rates (HRR) by using combustion timing retard and mixture stratification. However, at naturally aspirated and moderately boosted conditions, these techniques did not work well due to the low autoignition reactivity of conventional gasoline at these conditions. This work studies a low-octane distillate fuel with similar volatility to gasoline, termed Hydrobate, for its potential in HCCI engine combustion at naturally aspirated and low-range boosted conditions. The HCCI combustion with fully premixed and partially stratified charges was examined at intake pressures (Pin) from 100 to 180 kPa and constant intake temperature (60°C) and engine speed (1200 rpm).

The potential of boosted HCCI for achieving high loads has been investigated for intake pressures (Piⁿ) from 100 kPa (naturally aspirated) to 325 kPa absolute. Experiments were conducted in a single-cylinder HCCI research engine (0.98 liters) equipped with a compression-ratio 14 piston at 1200 rpm. The intake charge was fully premixed well upstream of the intake, and the fuel was a research-grade (R+M)/2 = 87-octane gasoline with a composition typical of commercial gasolines. Beginning with Piⁿ = 100 kPa, the intake pressure was systematically increased in steps of 20 - 40 kPa, and for each Piⁿ, the fueling was incrementally increased up to the knock/stability limit, beyond which slight changes in combustion conditions can lead to strong knocking or misfire. A combination of reduced intake temperature and cooled EGR was used to compensate for the pressure-induced enhancement of autoignition and to provide sufficient combustion-phasing retard to control knock.

Previous work has shown that conventional diesel ignition improvers, 2-ethylhexyl nitrate (EHN) and di-tert-butyl peroxide (DTBP), can be used to enhance the autoignition of a regular-grade E10 gasoline in a well premixed low-temperature gasoline combustion (LTGC) engine, hereafter termed an HCCI engine, at naturally aspirated and moderately boosted conditions (up to 180 kPa absolute) with a constant engine speed of 1200 rpm and a 14:1 compression ratio. In the current work the effect of EHN on boosted HCCI combustion is further investigated with a higher compression ratio (16:1) piston and over a range of engine speeds (up to 2400 rpm). The results show that the higher compression ratio and engine speeds can make the combustion of a regular-grade E10 gasoline somewhat less stable. The addition of EHN improves the combustion stability by allowing combustion phasing to be more advanced for the same ringing intensity.

Long chain alcohols possess major advantages over the currently used ethanol as bio-components for gasoline, including higher energy content, better engine compatibility, and less water solubility. The rapid developments in biofuel technology have made it possible to produce C 4 -C 5 alcohols cost effectively. These higher alcohols could significantly expand the biofuel content and potentially substitute ethanol in future gasoline mixtures. This study characterizes some fundamental properties of a C 5 alcohol, isopentanol, as a fuel for HCCI engines. Wide ranges of engine speed, intake temperature, intake pressure, and equivalence ratio are investigated. Results are presented in comparison with gasoline or ethanol data previously reported. For a given combustion phasing, isopentanol requires lower intake temperatures than gasoline or ethanol at all tested speeds, indicating a higher HCCI reactivity.

A planar temperature imaging diagnostic has been developed and applied to an investigation of naturally occurring thermal stratification in an HCCI engine. Natural thermal stratification is critical for high-load HCCI operation because it slows the combustion heat release; however, little is known about its development or distribution. A tracer-based single-line PLIF imaging technique was selected for its good precision and simplicity. Temperature-map images were derived from the PLIF images, based on the temperature sensitivity of the fluorescence signal of the toluene tracer added to the fuel. A well premixed intake charge assured that variations in fuel/air mixture did not affect the signal. Measurements were made in a single-cylinder optically accessible HCCI research engine (displacement = 0.98 liters) at a typical 1200 rpm operating condition. Since natural thermal stratification develops prior to autoignition, all measurements were made for motored operation.

Diesel engines are a source of suspended ambient particulate matter, and some concerns have been raised about the health effects from the inhalation of these particles. Nitrated polycyclic aromatics adsorbed on these particles have been shown to have the potential to cause mutations in living cells. Particulate matter collected on teflon-coated glass fiber filters produces results that may be open to question because of the possible generation of artifactual nitrated aromatics during the filtration process. An experiment using a constant-volume combustion bomb was used with four oxidants (air, nitrogen-free oxidant (29% O2 21% Ar 50% CO2), 50% O2/50% N2, and O2 (99.95% pure)), to address the concern over artifactual generation of nitrated-PAH on the filtration medium. Soot samples were collected both in situ on a cooled plug and on teflon-coated glass fiber filters in the exhaust line. Chemical comparisons of the collected samples were accomplished using chromatographic procedures.

Chemiluminescence imaging has been applied to a parametric investigation of diesel autoignition. Time-resolved images of the natural light emission were made in an optically accessible DI diesel engine of the heavy-duty size class using an intensified CCD video camera. Measurements were obtained at a base operating condition, corresponding to a motored TDC temperature and density of 992 K and 16.6 kg/m3, and for TDC temperatures and densities above and below these values. Data were taken with a 42.5 cetane number blend of the diesel reference fuels for all conditions, and measurements were also made with no. 2 diesel fuel (D2) at the base condition. For each condition, temporal sequences of images were acquired from the time of first detectable chemiluminescence up through fully sooting combustion, and the images were analyzed to obtain quantitative measurements of the average emission intensity.

To gain a better understanding of how the onset of incomplete bulk-gas reactions changes with engine speed and fuel-type, a parametric study of HCCI combustion and emissions has been conducted. The experimental part of the study was performed at naturally aspirated conditions and included fueling sweeps at four engine speeds (600, 1200, 1800 and 2400 rpm) for research grade gasoline, pure iso-octane and two mixtures of the primary reference fuels (i.e. n-heptane and iso-octane) with octane numbers of 80 and 60. Additionally, single-zone CHEMKIN computations with a detailed mechanism for iso-octane were conducted. The results show that there is a strong coupling between the ignition quality of the fuel and the required intake temperature to phase the combustion at TDC. There is also a direct influence of intake temperature on the completeness of combustion. This is the case because the CO-to-CO2 reactions are highly sensitive to the peak combustion temperatures.

Low-temperature gasoline combustion (LTGC) engines can provide high efficiencies and extremely low NOx and particulate emissions, but controlling the combustion timing remains a challenge. This paper explores the potential of Partial Fuel Stratification (PFS) to provide fast control of CA50 in an LTGC engine. Two different compression ratios are used (CR=16:1 and 14:1) that provide high efficiencies and are compatible with mixed-mode SI-LTGC engines. The fuel used is a research grade E10 gasoline (RON 92, MON 85) representative of a regular-grade market gasoline found in the United States. The fuel was supplied with a gasoline-type direct injector (GDI) mounted centrally in the cylinder. To create the PFS, the GDI injector was pulsed twice each engine cycle. First, an injection early in the intake stroke delivered the majority of the fuel (70 - 80%), establishing the minimum equivalence ratio in the charge.

Two methods for mitigating unacceptably high HCCI heat-release rates are investigated and compared in this combined experimental/CFD work. Retarding the combustion phasing by decreasing the intake temperature is found to have good potential for smoothing heat-release rates and reducing engine knock. There are at least three reasons for this: 1) lower combustion temperatures, 2) less pressure rise when the combustion is occurring during the expansion stroke, and 3) the natural thermal stratification increases around TDC. However, overly retarded combustion leads to unstable operation with partial-burn cycles resulting in high IMEPg variations and increased emissions. Enhanced natural thermal stratification by increased heat-transfer rates was explored by lowering the coolant temperature from 100 to 50°C. This strategy substantially decreased the heat-release rates and lowered the knocking intensity under certain conditions.