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After several decades of human spaceflight, the community of space-faring nations has accumulated a diverse and sometimes harrowing history of toxicological events that have plagued human space endeavors almost from the very beginning. Some lessons have been learned in ground-based test beds and others were discovered the hard way - when human lives were at stake in space. From such lessons one can build a risk-management framework for toxicological events to minimize the probability of a harmful exposure, while recognizing that we cannot predict all possible events. Space toxicologists have learned that relatively harmless compounds can be converted by air revitalization systems into compounds that cause serious harm to the crew.

Reduction of metabolic carbon dioxide is one of the essential steps in physiochemical air revitalization for long-duration manned space missions. Under contract with NASA Johnson Space Center, Hamilton Standard is developing an Advanced Carbon Reactor Subsystem (ACRS) to produce water and dense solid carbon from carbon dioxide and hydrogen. The ACRS essentially consists of a Sabatier Methanation Reactor (SMR) to reduce carbon dioxide with hydrogen to methane and water, a gas-liquid separator to remove product water from the methane, and a Carbon Formation Reactor (CFR) to pyrolyze methane to carbon and hydrogen. The hydrogen is recycled to the SMR, while the produce carbon is periodically removed from the CFR. The SMR is well-developed, while the CFR is under development. In this paper, the fundamentals of the SMR and CFR processes are presented and results of Breadboard CFR testing are reported.

Automatic thermal control (ATC) was investigated for implementation into a spacesuit to provide thermal neutrality to the astronaut through a range of activity levels. Two different control concepts were evaluated and compared for their ability to maintain subject thermal comfort. Six test subjects, who were involved in a series of three tests, walked on a treadmill following specific metabolic profiles while wearing the Mark III spacesuit in ambient environmental conditions. Results show that individual subject comfort was effectively provided by both algorithms over a broad range of metabolic activity. ATC appears to be highly effective in providing efficient, “hands-off” thermal regulation requiring minimal instrumentation. Final selection of an algorithm to be implemented in an advanced spacesuit system will require testing in dynamic thermal environments and consideration of technology for advancement in instrumentation and controller performance.

Engineers at the Johnson Space Center (JSC) are using innovative strategies to design the TCS for the Bio-regenerative Planetary Life Support Systems Test Complex (BIO-Plex), a regenerative advanced life support system ground test bed. This paper provides a current description of the BIO-Plex TCS design, testing objectives, analyses, descriptions of the TCS test articles expected to be tested in the BIO-Plex, and forward work regarding TCS. The TCS has been divided into some subsystems identified as permanent “infrastructure” for the BIO-Plex and others that are “test articles” that may change from one test to the next. The infrastructure subsystems are the Heating, Ventilation and Air-Conditioning (HVAC), the Crew Chambers Internal Thermal Control Subsystem (CC ITCS), the Biomass Production Chamber Internal Thermal Control Subsystem (BPC ITCS), the Waste Heat Distribution Subsystem (WHDS) and the External Thermal Control Subsystem (ETCS).

Recovery of potable water from wastewater is essential for the success of long-term manned missions to the moon and Mars. Honeywell International and the team consisting of Thermodistillation Company (Kyiv, Ukraine) and NASA Johnson Space Center (JSC) Crew and Thermal Systems Division are developing a wastewater processing subsystem that is based on centrifugal vacuum distillation. The Wastewater Processing Cascade Distillation Subsystem (CDS) utilizes an innovative and efficient multi-stage thermodynamic process to produce purified water. The rotary centrifugal design of the system also provides gas/liquid phase separation and liquid transport under microgravity conditions. A five-stage prototype of the subsystem was built, delivered and integrated into the NASA JSC Advanced Water Recovery Systems Development Facility for development testing.

A three phase catalytic mathematical model was developed for analysis and optimization of the volatile reactor assembly (VRA) used on International Space Station (ISS) Water Processor. The Langmuir-Hinshelwood Hougen-Watson (L-H) expression was used to describe the surface reaction rate. Small column experiments were used to determine the L-H rate parameters. The test components used in the experiments were acetic acid, acetone, ethanol, 1-propanol, 2-propanol and propionic acid. These compounds are the most prevalent ones found in the influent to the VRA reactor. The VRA model was able to predict performance of small column data and experimental data from the VRA flight experiment.

Carbon dioxide (CO2) removal technology development for portable life support systems (PLSS) has traditionally concentrated in the areas of solid and liquid chemical sorbents and semi-permeable membranes. Most of these systems are too heavy in gravity environments, require prohibitive amounts of consumables for operation on long term planetary missions, or are inoperable on the surface of Mars due to the presence of a CO2 atmosphere. This paper describes the effort performed to mature an innovative CO2 removal technology that meets NASA's planetary mission needs while adhering to the important guiding principles of simplicity, reliability, and operability. A breadboard cryogenic carbon dioxide scrubber for an ejector-based cryogenic PLSS was developed, designed, and tested. The scrubber freezes CO2 and other trace contaminants out of expired ventilation loop gas using cooling available from a liquid oxygen (LOX) based PLSS.

This paper describes the development of a membrane-based dehumidification process for space-based applications, such as spacecraft cabins and extra-vehicular-activity (EVA) space suits. Results presented are from 1) screening tests conducted to determine the efficacy of various membranes to separate water vapor from air, and 2) parametric and long-term tests of membranes operated at conditions that simulate the range of environmental conditions (e.g., temperature and relative humidity [RH]) expected in the planned space station. Also included in this paper is a discussion of preliminary designs of membrane-based dehumidification processes for the space station and EVA space suits. These designs result in compact and energy-efficient systems that offer significant advantages over conventional dehumidification processes.

Five type 4 all-composite compressed natural gas (CNG) fuel tanks produced in 1994 were acquired to study the effects of time and environmental exposure. Tank durability was demonstrated by the ability of the tanks to meet or exceed the ANSI/CSA NGV2-20001 standards after 9 years of field service. All tanks passed the NGV2-2000 standard production test requirements, including hydrostatic pressurization testing and standard leak testing. NGV2-2000 design qualification tests were performed on three of the tanks. Design qualification testing included liner and composite mechanical properties, cyclic pressurization, burst testing, and permeation testing as defined by NGV2-2000. All tanks exceeded the NGV2-2000 test requirements and exhibited no adverse effects from time, environment, and cyclic pressurization.

NASA's proposed lunar lander, Altair, will be exposed to vastly different external temperatures following launch till its final destination on the moon. In addition, the heat rejection is lowest at the lowest environmental temperatures (0.5 kW @ 4K) and highest at the highest environmental temperature (4.5 kW @ 215K). This places a severe demand on the radiator design to handle these extreme turn-down requirements. A radiator with digital turn-down capability is currently under study at JPL as a robust means to meet the heat rejection demands and provide freeze protection while minimizing mass and power consumption. Turndown is achieved by independent control of flow branches with isolating latch valves and a gear pump to evacuate the isolated branches. A bench-top test was conducted to characterize the digital radiator concept. Testing focused on the demonstration of proper valve sequencing to achieve turn-down and recharge of flow legs.

Supply of oxygen (O2) and hydrogen (H2) by electrolyzing water in space will play an important role in meeting the National Aeronautics and Space Administration's (NASA's) needs and goals for future space missions. Both O2 and H2 are envisioned to be used in a variety of processes including crew life support, spacecraft propulsion, extravehicular activity, electrical power generation/storage as well as in scientific experiment and manufacturing processes. Life Systems, Inc., in conjunction with NASA, has been developing an alkaline-based Static Feed Electrolyzer (SFE). During the development of the water electrolysis technology over the past 23 years, an extensive engineering and scientific data base has been assembled.

An energy balance was performed on the life support equipment used during the Phase III, 90-day, human Lunar-Mars Life Support Test Project at the Johnson Space Center. The purpose of the analysis was to account for all the energy sources, uses, and losses in the test-bed. Knowledge from this task may allow more energy efficient designs to be developed. Control volumes were defined and energy balance equations were generated for major systems. The analyses succeeded in balancing the energy fairly well for several systems. Further, the data showed that inefficiencies existed, and means of design optimization were subsequently suggested.

On the International Space Station (ISS), humidity condensate will be collected from the atmosphere and treated by multifiltration to produce potable water for use by the crews. Ground-based development tests have demonstrated that multifiltration beds filled with a series of ion-exchange resins and activated carbons can remove many inorganic and organic contaminants effectively from wastewaters. As a precursor to the use of this technology on the ISS, a demonstration of multifiltration treatment under microgravity conditions was undertaken. On the Space Shuttle, humidity condensate from cabin air is recovered in the atmosphere revitalization system, then stored and periodically vented to space vacuum. A Shuttle Condensate Adsorption Device (SCAD) containing sorbent materials similar to those planned for use on the ISS was developed and flown on STS-68 as a continuation of DSO 317, which was flown initially on STS-45 and STS-47.

This paper describes the process and analysis used to select a refrigerant and thermodynamic cycle as the basis of a vapor compression heat pump requiring a high temperature lift. Use of a vapor compression heat pump versus other types was based on prior work performed for the Electric Power Research Institute. A high lift heat pump is needed to enable a thermal control system to remove heat down to 275K from a habitable volume when the external thermal environment is severe. For example, a long term habitat will reject heat from a space radiator to a 325K environment. The first step in the selection process was to perform an optimization trade study, quantifying the effect of radiator operating temperature and heat pump efficiency on total system mass; then, select the radiator operating temperature corresponding to the lowest system mass. Total system mass included radiators, all heat pump components and the power supply system.

Regenerative-type subsystems are being tested at JSC to provide atmosphere revitalization functions of oxygen supply and carbon dioxide (CO2) removal for a future Space Station. Oxygen is supplied by an electrolysis subsystem, developed by General Electric, Wilmington, Mass., which uses the product water from either the CO2 reduction subsystem or a water reclamation process. CO2 is removed and concentrated by an electrochemical process, developed by Life Systems, Inc., Cleveland, Ohio. The concentrated CO2 is reduced in a Sabatier process with the hydrogen from the electrolysis process to water and methane. This subsystem is developed by Hamilton Standard, Windsor Locks, Conn. These subsystems are being integrated into an atmosphere revitalization group. This paper describes the integrated test configuration and the initial checkout test. The feasibility and design compatibility of these subsystems integrated into an air revitalization system is discussed.

This paper presents and discusses the results of an integrated 4-Bed Molecular Sieve (4BMS), mechanical compressor, and Sabatier Engineering Development Unit (EDU) test. Testing was required to evaluate the integrated performance of these components of a closed loop atmosphere revitalization system together with a proposed compressor control algorithm. A theoretical model and numerical simulation had been used to develop the control algorithm; however, testing was necessary to verify the simulation results and further refine the model. Hardware testing of a fully integrated system also provided a better understanding of the practical inefficiencies and control issues, which are unavailable from a theoretical model.

The quantitative analysis of the food system for long-term space missions is a crucial factor for the comparison of different food plans and for the evaluation of the food system as part of the overall mission. Such analysis should include important factors such as nutrition, palatability, diet cycle length, and psychological issues related to food. This paper will give the details of a mathematical model that was developed during the first author's participation as a Summer Faculty Fellow at Johnson Space Center. The model includes nutrition, palatability, diet cycle length, and psychological issues as important components. The model is compatible with the Equivalent System Mass (ESM) metric previously developed as the Advance Life Support (ALS) Research and Technology Metric.

This paper describes the need and solution for minimizing EVA airlock time and depress gas losses using a new method that minimizes EVA out-the-door time for a suited astronaut and reclaims most of the airlock depress gas. This method consists of one or more related concepts that use an evacuated reservoir tank to store and reclaim the airlock depress gas. The evacuated tank can be an inflatable tank, a spent fuel tank from a lunar lander descent stage, or a backup airlock. During EVA airlock operations, the airlock and reservoir would be equalized at some low pressure, and through proper selection of reservoir size, most of the depress gas would be stored in the reservoir for later reclamation. The benefit of this method is directly applicable to long duration lunar and Mars missions that require multiple EVA missions (up to 100, two-person lunar EVAs) and conservation of consumables, including depress pump power and depress gas.

As next generation space suit concepts enable extravehicular activity (EVA) mission capability to extend beyond anything currently available today, revolutionary advances in life support technologies are required to achieve anticipated NASA mission profiles that may measure years in duration and require hundreds of sorties. Since most life support systems require power, increased mass and volume efficiency of the energy storage materials can have a dramatic impact on reducing the overall weight of next generation space suits. This paper details the development of a multifunctional fiber battery to address these needs.

At present, Nickel Hydrogen batteries are tested at Marshall Space Flight Center (MSFC) in support of the Hubble Space Telescope (HST) program. In previous years, Nickel Cadmium batteries were tested at MSFC in support of HST. The Nickel Cadmium Battery Expert System-2 (NICBES-2) was employed on the HST six battery test bed to evaluate the performance of the HST Electrical Power System (EPS). With the beginning of testing of the nickel hydrogen six battery test bed, NICBES-2 had to be converted to NICkel Hydrogen Battery Expert System (NICHES). This paper describes the conversion of the NICBES-2 to the NICHES as well as future plans for NICHES.