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Combustion with knock is an abnormal phenomenon which constrains the engine performance, thermal efficiency and longevity. The advance timing of the ignition system requires it to be updated with respect to fuel octane number variation. The production series engines are calibrated by the manufacturer to run with a special fuel octane number. In the experiment, the engine was operated at different speeds, loads, spark advance timings and consumed commercial gasoline with research octane numbers (RON) 95, 97 and 100. A 1-dimensional validated engine combustion model was run in the GT-Power software to simulate the engine conditions required to define the knock envelope at the same engine operation conditions as experiment. The knock intensity investigation due to spark advance sweep shows that combustion with noise was started after a specific advance ignition timing and the audible knock occur by increasing the advance timing.