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Stringent global emissions legislation demands effective NOx reduction strategies, particularly for the aftertreatment, and current typical liquid urea SCR systems achieve efficiencies greater than 90% [1]. However, with such high-performing systems comes the trade-off of requiring a tank of reductant (urea water solution) to be filled regularly, usually as soon as the fuel fillings or as far as oil changes. Advantages of solid reductants, particularly ammonium carbamate, include greater ammonia densities, enabling the reductant refill interval to be extended several multiples versus a given reductant volume of urea, or diesel exhaust fluid (DEF) [2]. An additional advantage is direct gaseous ammonia dosing, enabling reductant injection at lower exhaust temperatures to widen its operational coverage achieving greater emissions reduction potential [3], as well as eliminating deposits, reducing mixing lengths, and avoiding freeze/thaw risks and investments.

Exhaust aftertreatment systems must function sufficiently over the full useful life of a vehicle. In Europe this is currently defined as 160.000 km. With the introduction of Euro 7 it is expected that the required mileage will be extended to 240.000 km. This will then be consistent with the US legislation. In order to quantify the emission impact of exhaust system degradation, an Euro 7 exhaust aftertreatment system is aged by different accelerated approaches: application of the Standard Bench Cycle, the ZDAKW cycle, a novel ash loading method and borderline aging. The results depict the impact of oil ash on the oxygen storage capacity. For tailpipe emissions, the maximum peak temperatures are the dominant aging factor. The cold start performance is effected by both, thermal degradation and ash accumulation. An evaluation of this emission increase requires appropriate benchmarks.

Tier 4 emissions legislation is emerging as a clear pre-cursor for widespread adoption of exhaust aftertreatment in off-highway applications. Large bore engine manufacturers are faced with the significant challenge of packaging a multitude of catalyst technologies in essentially the same design envelope as their pre-Tier 4 manifestations, while contending with the fuel consumption consequences of the increased back pressure, as well as the incremental cost and weight associated with the aftertreatment equipment. This paper discusses the use of robust metallic catalysts upstream of the exhaust gas turbine, as an effective means to reduce catalyst volume and hence the weight and cost of the entire aftertreatment package. The primarily steady-state operation of many large bore engine applications reduces the complication of overcoming pre-turbine catalyst thermal inertia under transient operation.

The implementation and development efforts of lean NOx trap catalysts for heavy-duty applications decreased a number of years ago. Most heavy-duty engine manufacturers realized that the system complexity as well as the durability of such a system does not allow large volume production without significant risk. The current consensus of the heavy-duty community is that for 2010 the SCR system will be the prime path to meet the 0.2 g/bHPhr NOx emission standard, although this is subject to adequate infrastructure investment and progress. As a low volume manufacturer, in order to comply with the 2007 heavy-duty phase-in emission standards, General Engine Products (a subsidiary of AM General LLC) integrated a NOx adsorber system on the Optimizer 6500 engine. This engine features split combustion chamber design, rotary fuel injection pump and operates with EGR.

Within a project of the Research Association for Combustion Engines e.V., different measures for rising the temperature of exhaust gas aftertreatment components of both a passenger car and an industrial/commercial vehicle engine were investigated on a test bench as well as in simulation. With the passenger car diesel engine and different catalyst configurations, the potential of internal and external heating measures was evaluated. The configuration consisting of a NOx storage catalyst (NSC) and a diesel particulate filter (DPF) illustrates the potential of an electrically heated NSC. The exhaust aftertreatment system consisting of a diesel oxidation catalyst (DOC) and a DPF shows in simulation how variable valve timing in combination with electric heated DOC can be used to increase the exhaust gas temperature and thus fulfill the EU6 emission limits.

The aggressive reduction of future diesel engine NOx emission limits forces the heavy- and light-duty diesel engine manufacturers to develop means to comply with stringent legislation. As a result, different exhaust emission control technologies applicable to NOx have been the subject of many investigations. One of these systems is the NOx adsorber catalyst, which has shown high NOx conversion rates during previous investigations with acceptable fuel consumption penalties. In addition, the NOx adsorber catalyst does not require a secondary on-board reductant. However, the NOx adsorber catalyst also represents the most sulfur sensitive emissions control device currently under investigation for advanced NOx control. To remove the sulfur introduced into the system through the diesel fuel and stored on the catalyst sites during operation, specific regeneration strategies and boundary conditions were investigated and developed.

Dielectric barrier discharge (DBD) offers the advantage to excite and dissociate molecules in the exhaust gas stream. Those dissociated and excited species are oxidizing or reducing harmful exhaust gas components. The advantage of a plasma chemical system in comparison to a catalytic measure for exhaust gas treatment is the instantaneous activity at ambient temperature from the starting of the engine. The investigations reviewed in this paper are dealing with the plasma chemical oxidation of hydrocarbons in the exhaust gas stream during cold start conditions. The article concerns the design and development of a plasma-system in order to decrease the hydrocarbon emissions from engine start till catalyst light off. Vehicle results in the New European Driving Cycle show a hydrocarbon conversion of more than 42% in the first 11 seconds from engine start. In this period nearly all types of hydrocarbon were reduced.

This paper describes an alternative catalyst aging process using a hot gas test stand for thermal aging. The solution presented is characterized by a burner technology that is combined with a combustion enhancement, which allows stoichiometric and rich operating conditions to simulate engine exhaust gases. The resulting efficiency was increased and the operation limits were broadened, compared to combustion engines that are typically used for catalyst aging. The primary modification that enabled this achievement was the recirculation of exhaust gas downstream from catalyst back to the burner. The burner allows the running simplified dynamic durability cycles, which are the standard bench cycle that is defined by the legislation as alternative aging procedure and the fuel shut-off simulation cycle ZDAKW. The hot gas test stand approach has been compared to the conventional engine test bench method.

Gasoline particulate filters (GPF) recently entered the market, and are already regarded a state-of-the-art solution for gasoline exhaust aftertreatment systems to enable EU6d-TEMP fulfilment and beyond. Especially for coated GPF applications, the prognosis of the emission conversion performance over lifetime poses an ambitious challenge, which significantly influences future catalyst diagnosis calibrations. The paper presents key-findings for the different GPF application variants. In the first part, experimental GPF ash loading results are presented. Ash accumulates as thin wall layers and short plugs, but does not penetrate into the wall. However, it suppresses deep bed filtration of soot, initially decreasing the soot-loaded backpressure. For the emission calibration, the non-linear backpressure development complicates the soot load monitoring, eventually leading to compromises between high safety against soot overloading and a low number of active regenerations.