This paper, confined to the application of hard chrome plated liners to high-speed four-stroke diesel and gasoline engines, illustrates the increase in their popularity in the United Kingdom, and the advanced production methods which make this economically possible. The need for balanced engine life has long been apparent and is even more important today, the growth of motor transport having outstripped repair facilities. Iron bore life has been surpassed by improvement in the life of other component parts in the modern diesel engine. The provision of hard chrome plated liners can restore the balance. Further development and turbocharging of diesel engines has shown the need for a bore material capable of preventing scuffing and galling at elevated temperatures. Hard chrome has already proved itself in four-stroke engines under these conditions.
THE PURPOSE of this experiment was to determine the role of residual stresses in fatigue strength independent of other factors usually involved when residual stresses are introduced. It consisted of an investigation of the influence of residual stresses introduced by shotpeening on the fatigue strength of steel (Rockwell C hardness 48) in unidirectional bending. Residual stresses were varied by peening under various conditions of applied strain. This process introduced substantially the same amount and kind of surface cold working with residual stresses varying over a wide range of values. It was found that shotpeening of steel of this hardness is beneficial primarily because of the nature of the macro-residual-stresses introduced by the process. There is no gain attributable to “strain-hardening” for this material. An effort was made to explain the results on the basis of three failure criteria: distortion energy, maximum shear stress, and maximum stress.*
In a 2-year program sponsored by SJAC, an aqueous electroplating process using alkaline Zn-Ni with trivalent chromium post treatment is under evaluation for high strength steel for aircraft application as an alternative to cadmium. Commercial Zn-15%Ni rack/barrel plating solutions are basis for plating aircraft parts or fasteners. Brightener was reduced from the original formula to form porous plating that enables bake-out of hydrogen to avoid hydrogen embrittlement condition. Properties of the deposit, such as appearance, adhesion, un-scribed corrosion resistance, and galvanic corrosion resistance in contact with Al alloy, were evaluated. Coefficient of friction was compared with Cd plating by torque-tension measurements. Evaluation of the plating for scribed corrosion resistance, primer adhesion, etc. will continue in FY2007.
For over a decade, industry prognosticators have been predicting that the use of plastics by automakers would soon surpass the deployment of metals in automobiles, While there is no denying that plastics have made inroads, it recently has become apparent that metal will retain its position as the prime car material for the foreseeable future. One reason for the revised forecast is the development of improved zinc coatings for the automotive industry. Such material as electrogalvanized and Galfan™ are shaping up as steel's saviors when it comes to ensuring that metal will continue to play the major role on car assembly lines. Meanwhile on the other side of the equation, developments in zinc die casting technology have taken the edge off plastics' forward thrust into both functional and decorative car part applications.
Copper and brass radiators have served the automobile industry for many years using traditional fabrication processes. Demand for newer and stronger radiators with lighter weight for the modern vehicles prompted investigation of alternate materials. Properties of zinc alloys and their compatibility with brass suggested these could be used for radiator manufacture. Many zinc alloy compositions were investigated in the initial studies, because a solder alloy has to have many positive attributes. The first screening studies evaluated the ability of the solder to spread over copper and brass surfaces, representing tube, fin, and header materials. The second most important feature was the melting range of the developed alloy. In order to retain the anneal resistance of the fin and temper in the tube it was desirable to have a zinc solder with a melting temperature at 800°F or less.
The extrusion of zinc alloys, with special reference to zinc-titanium alloys, is described. Parameters for this process are defined. The excellent tensile and creep properties obtained in a typical extruded zinc-titanium alloy are presented. Extruded zinc with a quality copper-nickel-chrome plated finish offers a new approach to the production of automotive trim and of similar products.
Many papers have been written for SAE on electrochemical metallizing, a modern term for “selective” or “brush” plating. These papers have dealt primarily with the aerospace industry, including the use of non-embrittling cadmium LHE® coatings for corrosion protection on aircraft. Shadowed by 30 years of successes in the aerospace industry, electrochemical metallizing corrosion protection in the automotive industry is often overlooked. Specifically, the use of selectively applied zinc coatings for corrosion protection on wheel hubs during manufacture has proven integral at several European automotive manufacturers. In the past, environmental conditions have corroded both the hubs and wheels of automobiles. Quite often the corrosion is in the microscopic gap between the hub and the wheel, which over time causes the wheel to seize and prevents removal. This has been frustrating to both stranded motorists and shop mechanics.
AS PART of its continuing research to improve the die casting process, International Lead Zinc Research Organization, Inc. has prepared a computer program, “Computer-Aided Design for Zinc Die Casting Dies,” which will enable a die caster to design the metal flow system for a die within a matter of minutes—simply and more accurately than ever possible, previously. It is helping convert what has been an art into a science.
The role of zinc die castings in the materials marketplace has changed significantly in the last generation. In response to a shift in the available market, the industry has made major advances intended to improve competitiveness in both traditional and non-traditional areas. Better efficiency and performance have been achieved by the application of new methods and technologies. The ZA alloys, introduced to die casting during the last decade, have markedly expanded the capabilities of both zinc and the die casting process. This paper presents a review of several zinc die castings used in automatic applications.
Zinc die casting products and metal casting processes continue to evolve for the benefit of end users. Through cooperative global research programs continuous improvements are still being made to the broad range of excellent mechanical properties, easy castability and the wide choice of finishes available for zinc die castings. Recent advances will be highlighted with case histories specific to automotive applications.
Traditional and new zinc-based casting alloys for functional and decorative applications are reviewed. Their compositions and standard alloy specifications are described, and recommendations for casting process selection and prototyping of applications are offered. The information presented shows the versatility achievable with zinc alloys. It is aimed at helping part designers make the most effective use of zinc for their component requirements.
High damping capacity materials are useful in attenuating vibrations in mechanical structures such as functional automotive bracketry. The intrinsic damping properties of zinc alloys have only recently been systematically measured. Low and high frequency damping experiments have been conducted on die cast zinc alloys. and damping capacity has been measured as a function of temperature at high frequencies. The alloys show excellent damping properties over the range from 5 Hertz to a few hundred Hertz. for service applications from 40-80°C (104-176°F).
The ZA series of zinc alloys produce high strength die castings with the same cast-to size capability as the well proven SAE 903 alloy. The enhanced properties have been utilised in the two engine components described in this paper. ZA 27 has been used for the tooth belt drive camshaft pulley of a motorcycle engine and ZA8 has been used for the temperature resistant housing of a car ignition distributor.
The Reflection Grating Spectrometer experiment (RGS) on the ESA corner stone X-Ray Multi-Mirror Mission (XMM) uses charge coupled devices (CCD) as detectors. Thermal requirements are the main driver for the layout of the detector housing. Parasitic heat inputs stem primarily from radiative coupling and from conduction over the structural support. Improvements in the design of the electro optical model (EOM) over the bread board model (BBM) resulted in a system that guarantees a CCD temperature of -130 °C at the end of the mission while not precluding the possibility to heat the detectors as high as +130°C which might be useful for annealing the CCDs.
THE X-ray spectrum readily adapts itself to problems in chemical analysis and crystal formation. It is effective on very minute particles which otherwise cannot be segregated. A permanent record is made, and the specimens may be used over and over again, as the X-ray is non-destructive. As a means of inspection, X-ray clearly shows the interior of objects such as weldings castings, forgings, cold-worked metals, and so on. Inhomogeneities that are very slight in width and a fraction of one per cent in thickness are seen easily on a radiograph. Defects thus found may be eliminated summarily by checking various steps in production.
With X-ray stress and fine structure analyses, results have been obtained that are inconsistent with present views of the structure and tempering kinetics of hardened steels. Experimental results are reported, and an attempt is made to establish a model of the tempering kinetics of hardened steels. It is shown that the Snoek and Cottrell effects are the dominating mechanisms of diffusion and that they lead to the formation of two α phases of differing carbon content; the phase with the accumulated carbon finally results in the formation of cementite.