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Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.

Environmental and economic issues related to the aeronautic transport, with particular reference to the high-speed one are opening new perspectives to pulsejets and derived pulse detonation engines. Their importance relates to high thrust to weight ratio and low cost of manufacturing with very low energy efficiency. This papers presents a preliminary evaluation in the direction of a new family of pulsejets which can be coupled with both an air compression system which is currently in pre-patenting study and a more efficient and enduring valve systems with respect to today ones. This new pulsejet has bee specifically studied to reach three objectives: a better thermodynamic efficiency, a substantial reduction of vibrations by a multi-chamber cooled architecture, a much longer operative life by more affordable valves. Another objective of this research connects directly to the possibility of feeding the pulsejet with hydrogen.

Future human exploration roadmaps involve the development of temporary or permanent outposts on Moon and Mars. The capability of providing astronauts with proper conditions for living and working in extraterrestrial environments is therefore a key issue for the sustainability of those roadmaps, and closed-loop Environment Control and Life Support Systems (ECLSSs) and bio-regenerative plants represent the necessary evolution of current technologies for complying with the challenging requirements imposed. This paper presents the architectural design of a terrestrial plant to be exploited to test and validate air and water management technologies for a biological life support system in a closed environment. The plant includes a crew area and a plant growth area. These two spaces can be considered as either a unique volume or two separated environments with reduced contact, e.g. for plant harvesting or other up-keeping activities.

In the paper several application techniques of MonteCarlo (MC) method applied to thermal analysis of space vehicles are presented. Although these methods are widely used in other engineering domains, their introduction to the thermal one is quite recent and not fully developed in the industrial practice. This paper aims at showing that, even without demanding computation resources (all what presented has been obtained with a single processor PC) MonteCarlo analysis techniques, in a preliminary design phase, can support and integrate engineering judgment of the thermal designer. In particular, it is exploited the applicability of the method to reduced thermal models, with a clear advantage in terms of computation time. An original approach is proposed, and results are shown. The papers shows the applicability of the MC method to the case when experimental data of the uncertain parameters are available, using the bootstrap re-sampling techniques.

This work presents a comprehensive numerical model for ice accretion and Ice Protection System (IPS) simulation over a 2D component, such as an airfoil. The model is based on the Myers model for ice accretion and extended to include the possibility of a heated substratum. Six different icing conditions that can occur during in-flight ice accretion with an Electro-Thermal Ice Protection System (ETIPS) activated are identified. Each condition presents one or more layers with a different water phase. Depending on the heat fluxes, there could be only liquid water, ice, or a combination of both on the substratum. The possible layers are the ice layer on the substratum, the running liquid film over ice or substratum, and the static liquid film between ice and substratum caused by ice melting. The last layer, which is always present, is the substratum. The physical model that describes the evolution of these layers is based on the Stefan problem. For each layer, one heat equation is solved.