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The authors have developed a new partial flow dilution tunnel (hereafter referred to as PPFT), whose principal device is a flux splitting gas divider, as a new means of measuring particulate emissions which can be applied to transient cycle testing of diesel engines. The advantage of this system is that it can achieve perfect constant velocity splitting by means of its structure, and theoretically can also maintain high splitting performance despite fluctuations in the exhaust flow rate, including those due to engine exhaust pulsation. We compared this system with a full tunnel by analyzing the basic performance of the system and measuring particulate matter (PM) using an actual vehicle engine.

A variable valve timing (VVT) mechanism was applied to achieve premixed diesel combustion at higher load for low emissions and high thermal efficiency in a light duty diesel engine. By means of late intake valve closing (LIVC), compressed gas temperatures near the top dead center are lowered, thereby preventing too early ignition and increasing ignition delay to enhance fuel-air mixing. The variability of effective compression ratio has significant potential for ignition timing control of conventional diesel fuel mixtures. At the same time, the expansion ratio is kept constant to ensure thermal efficiency. Combining the control of LIVC, EGR, supercharging systems and high-pressure fuel injection equipment can simultaneously reduce NOx and smoke. The NOx and smoke suppression mechanism in the premixed diesel combustion was analyzed using the 3D-CFD code combined with detailed chemistry.

For reducing exhaust emissions of heavy-duty diesel engines, the authors made an experimental study of diesel combustion using a single cylinder engine. The engine performance and exhaust emissions have been measured using a wide range and high EGR rate under the conditions of high boost intake pressure. The engine test cell has been equipped the external supercharger that is able to raise the boost pressure to 500 kPa, and also equipped the EGR system to increase the EGR rate until 50% under the 500 kPa boost condition. In various test conditions of load and engine speeds the authors have obtained the results, that is, NOx has been reduced drastically without increasing Particulate Matter (PM).

A natural gas direct injection test engine equipped with a newly developed natural gas injector was built. High total hydrocarbon (THC) emission at part-load and high NOx emission at high-load remain as problems for direct injection natural gas engines. THC reduction and combustion improvement by throttling and NOx reduction by EGR were investigated. The following results were obtained: (1) the combustion at light and medium load conditions is improved by throttling. It is possible to improve the thermal efficiency at light-load in spite of the pumping loss by throttling. THC emissions are greatly decreased in this condition; (2) a large NOx reduction can be obtained without combustion deterioration by appropriate EGR at high-load conditions; and (3) it is possible to decrease both THC and NOx emissions by both throttling and EGR at part-load conditions.

Degradation of the deNOx performance has been found in in-use heavy-duty vehicles with a urea-SCR system in Japan. The causes of the degradation were studied, and two major reasons are suggested here: HC poisoning and deactivation of pre-oxidation catalysts. Hydrocarbons that accumulated on the catalysts inhibited the catalysis. Although they were easily removed by a simple heat treatment, the treatment could only partially recover the original catalytic performance for the deNOx reaction. The unrecovered catalytic activity was found to result from the decrease in conversion of NO to NO2 on the pre-oxidation catalyst. The pre-oxidation catalyst was thus studied in detail by various techniques to reveal the causes of the degradation: Exhaust emission tests for in-use vehicles, effect of heat treatment on the urea-SCR systems, structural changes and chemical changes in active components during the deactivation were systematically investigated.

The new 2GR-FKS / FXS engines were developed to achieve stringent fuel economy and emission targets and respond to recent innovations in the field. The major parts of the 2GR-FKS/FXS engines were re-designed based on the well-received dynamic performance and fuel economy aspects of the 2GR-FE engine. The aims of this development were as follows. 1 Best-in-class power performance 2 Environmental performance that maximizes thermal efficiency and complies with fuel economy and emission regulations in each country by a wide margin 3 Engine response typical of V6 engines through drastic weight reduction of moving parts To achieve these conflicting aims, the developed engines use a modified version of the D-4S fuel injection system, which enables selective use of direct and port injection, in addition to advanced technologies such as variable valve technology (VVT) with a mid-position lock system and an exhaust port cooling system.

The biomass fuel is expected to solve the global warming due to a carbon neutral. A rapeseed oil methyl ester (RME) as biomass fuel was selected, and also a low sulfur diesel fuel is tested as reference fuel in this study. The experiments were carried out to improve diesel emissions and engine performance using high boost and high rate EGR system and a common rail injection system in a single cylinder engine. The diesel emissions and engine performance have been measured under the experimental conditions such as charging boost pressure from atmospheric pressure to 401.3kPa maximum and changing EGR rate from 0% to 40% maximum. RME contain about 10 mass % oxygen in the fuel molecule. Furthermore, RME does not contain aromatic hydrocarbons in the fuel. Due to these chemical properties, RME can be used at 40% high EGR condition.

The use of biodiesel fuels as an alternative fuel for petroleum diesel fuel is very effective for the reduction of CO2 emission, because biodiesel is produced from renewable biomass resources. Biodiesel is usually blended to conventional diesel fuel in various proportions. It is possible that this biodiesel blending causes the problems on emission characteristics of modern diesel engine, because it could be confirmed that the application of neat biodiesel to modern diesel engines whose control parameters were optimized for conventional diesel fuel deteriorated the emission performances. It is necessary to clarify the effect of biodiesel blending on exhaust emissions of modern diesel engine. Rapeseed oil methyl ester (RME) was selected as a biodiesel used in this study.

The use of biomass fuels for vehicles has been a focus of attention all over the world in terms of prevention of global warming, effective utilization of resources and local revitalization. For the purpose of beneficial use of unused biomass resources, the movement of the use of bioethanol and biodiesel made from them has spread in Japan. In Japan, biodiesel is mainly made from waste cooking oil collected by local communities or governments, and in terms of local production for local consumption, it is used as neat fuel (100% biofuel) or mixed with diesel fuel in high concentration for the vehicles. On the other hand, extremely low emission level must be kept for not only gasoline vehicles but also diesel vehicles in the post new long-term regulation implemented from 2009 in Japan.

The effect of boiling point difference as well as the flash boiling of two-component normal paraffin fuels on combustion and exhaust emission has been examined under different test conditions. To obtain a wide variation in boiling point between components different high boiling point fuels (n-undecane, n-tridecane and n-hexadecane) were blended with a low boiling point fuel (n-pentane) and different low boiling point fuels (n-pentane, n-hexane, and n-heptane) were blended with a high boiling point fuel (n-hexadecane). In addition the volume fraction of n-pentane was varied to have the best mixture ratio with n-tridecane. These fuel combinations exhibit different potential for flash boiling based on a certain ambient condition. The results indicate that though the potential for flash boiling is the highest for a mixture of n-pentane and n-hexadecane it emits about 20% higher PM than a mixture of n-pentane and n-tridecane.

Reduction of exhaust emissions and BSFC was studied for high pressure, wide range, and high EGR rates in a Super-clean Diesel six-cylinder heavy duty engine. The GVW 25-ton vehicle has 10.52 L engine displacement, with maximum power of 300 kW and maximum torque of 1842 Nm. The engine is equipped with high-pressure fuel injection of a 200 MPa level common-rail system. A variable geometry turbocharger (VGT) was newly designed. The maximum pressure ratio of the compressor is about twice that of the previous design: 2.5. Additionally, wide range and a high EGR rate are achieved by high pressure-loop EGR (HP-EGR) and low pressure-loop EGR (LP-EGR) with described VGT and high-pressure fuel injection. The HP-EGR can reduce NOx concentrations in the exhaust pipe, but the high EGR rate worsens smoke. The HP-EGR system layout has an important shortcoming: it has great differences of the intake EGR gas amount into each cylinder, worsens smoke.

The emission reduction from diesel engines is one of major issues in heavy duty diesel engines. Super Clean Diesel (SCD) Engine for heavy-duty trucks has also been researched and developed since 2002. The main specifications of the SCD Engine are six cylinders in-line and 10.5 l with a turbo-intercooled and cooled EGR system. The common rail system, of which the maximum injection pressure is 200 MPa, is adopted. The turbocharger is capable of increasing boost pressure up to 501.3 kPa. The EGR system consists of both a high-pressure loop (HP) EGR system and a low-pressure loop (LP) EGR system. The combination of these EGR systems reduces NOx and PM emissions effectively in both steady-state and transient conditions. The emissions of the SCD Engine reach NOx=0.2 g/kWh and PM=0.01 g/kWh with aftertreatment system. The adopted aftertreatment system includes a Lean NOx Trap (LNT) and Diesel Particulate Filter (DPF).

Lean NOx trap (LNT) and Urea-SCR system are effective aftertreatment systems as NOx reduction device in diesel engines. On the other hand, DPF has already been developed as PM reduction device and it has been used in various vehicles. LNT can absorb and reduce NOx emission in wide range exhaust temperatures, from 150°C to 400°C, and the size of LNT component can be compact in comparison with Urea-SCR system because LNT uses the diesel fuel as a reducing agent and it is needless to install the reducing agent tank in the vehicle. In this study, authors have shown that the NOx conversion rate of LNT is high in the case of extremely low NOx concentration from the engine. Also, the effects of LNT and DPF were examined using the Super Clean Diesel (SCD) Engine, which has low NOx level before aftertreatment and has been finished as Japanese national project.

Homogeneous Charge Compression Ignition (HCCI) is effective for the simultaneous reduction of soot and NOx emissions from diesel engine. In general, high octane number and volatility fuels (gasoline components or gaseous fuels) are used for HCCI operation, because very lean mixture must be formed during ignition delay of the fuel. However, it is necessary to improve fuel injection systems, when these fuels are used in diesel engine. The purpose of the present study is the achievement of HCCI combustion in DI diesel engine without the large-scale improvements of engine components. Various high octane number fuels are mixed with diesel fuel as a base fuel, and the mixed fuels are directly applied to DI diesel engine. At first, the cylinder pressure and heat release rate of each mixed fuel are analyzed. The ignition delay of HCCI operation decreases with an increase in the operation load, although that of conventional diesel operation does not almost varied.

In order to discuss future technical issues for urea SCR (selective catalytic reduction) system, it is necessary to assess various technical possibilities that would be applied to urea SCR systems which is capable of complying with future emission level requirements, for example Japanese 2009 emission regulation. In this paper, three measures (enhanced insulation on a DOC (diesel oxidation catalyst), aggressive urea solution injection and idling stop) are installed on a urea SCR system of a commercial engine system in order to achieve further NOx (nitrogen oxide) reductions. With combination of these three measures, NOx is drastically reduced to the levels lower than 0.7 g/kWh, which is a NOx limit value of the Japanese 2009 emission regulation. NH3 (ammonia) and HCN (hydro cyanide) are also measured as unregulated harmful components.

A prototype CNG engine for heavy-duty trucks has been developed. The engine had sufficient output in practical use, and the green-house gas emission rate was below that of the base diesel engine. Furthermore, the NOx emission rate was reduced to 0.16 g/kWh in the JE05 mode as results of having fully adjusted air fuel ratio control. The measured emission characteristics of particles from the prototype CNG engine demonstrated that oil consumption was related to the number of particles. Moreover, when oil consumption is at an appropriate level, the accumulation mode particles are significantly reduced, and the nuclei mode particles are fewer than those of diesel-fueled engines.

The Poly-Aromatic Hydrocarbon (PAH) formation process from benzene was studied using a laminar flow reactor and GC-MS. In addition to PAH, acetylene and ethylene were observed. Without oxygen at temperatures over 1070 K, the amount of PAH and C2 species increased as the benzene concentration decreased. Addition of oxygen caused a linear decrease in the benzene concentration, and almost all of the benzene was consumed under stoichiometric conditions at all temperatures. At 1053 K, the concentrations of PAH and C2 species were not affected by the addition of oxygen. On the other hand, when the temperature was greater than 1070 K, the amount of PAH formed increased as the equivalence ratio increased, until the equivalence ratio was about 4. Above this equivalence ratio, the amounts decreased. Amounts of phenanthrene and biphenyl were large compared to those of other PAHs, which indicated that the dominant PAH formation path is the formation of phenanthrene via biphenyl.

Recently, particulate matter (PM) emission from internal combustion engines, especially particles having the diameter of less than 100 nm (Nano-particles) are being considered for their potential hazards posed to human health and the environment. Nano-particles are unstable and easily influenced by the conditions of engine operation and measurement techniques. In this study, the influences of cooling and dilution processes on nano- particles are presented to understand the generation and dilution mechanisms, and to further development of an accurate measurement method. It is found that the thermo-dilurter is necessary for measuring the nano-particles with higher accuracy. Accurate measurement of nano-particles requires immediate dilution of the exhaust gases by hot air.

The use of a Thermo-Denuder (TD) is proposed to suppress the nano-particle measurement fluctuations caused by the volatile components in the available techniques. The problems encountered during the use of thermo-denuder for nano-particle measurement and their respective solutions are suggested. The behavior of nano-particles in the TD itself is not clearly understood but the thermo-denuder influences both the volatile and solid particles. As a first report, only the effect of TD dimension on solid nano-particle measurements is presented. It is concluded that the TD influences the nano-particles i.e. loss of particles occurs even the sample gas contains no volatile fractions. A sharp temperature gradient between the low temperature wall of the absorption part of TD and hot sample gas causes particle losses due to thermophoresis effect. Especially the smaller particles are affected significantly.

Exhaust emissions and particulate matter (PM) from an engine with a conventional continuous regeneration diesel particulate filter (DPF) were measured to evaluate DPF performance under the Japan 13-mode cycle, European Stationary Cycle and various transient cycles: U.S. transient cycle, Japan Automobile Research Institute cycle, and World-wide Heavy Duty Cycle. The emission tendencies with and without DPF under these conditions were clarified. According to these experiments, accumulated PM in the DPF under the driving modes mentioned above has influence on measurement errors. It is necessary to estimate the amount of accumulated PM in the DPF to evaluate the PM reduction rate correctly. This study also measured particle size distribution of diesel exhaust particulates (DEP) downstream of the DPF using an electrical low-pressure impactor (ELPI). As a result, we determined that most of the particles not trapped by the DPF are less than 110nm.