This paper presents, chemistry, test data and processing procedures on a non toxic and environmentally friendly chrome-free conversion coating alternative with the same level of adhesion and secondary corrosion resistance as that found in chrome containing conversion coating systems. Test data from military and independent sources will be presented on secondary coating adhesion, electrical conductivity, filiform and neutral salt-spray corrosion resistance as compared to chromate based systems .on magnesium, aluminum and zinc and their respective alloys. The European “RoSH” initiative will not allow for the presence of any hexavalent chromium on imported electrical components as of July first of 2006. Trivalent chromium based systems generate hexavalent chromium due to the oxidation of the trivalent chromium and as such will not be allowed.
This paper presents the derivation of the equations for circumferential, longitudinal and radial heat transfer conductance for a thin shell toroid or a segment of the toroid. A thin shell toroid is one in which the radius to thickness ratio is greater than 10. The equations for the surface area of a toroid or of a toroidal segment will also be derived along with the equation to determine the location of the centroid. The surface area is needed to determine the radial conductance in the toroid or toroidal segment and the centroid is needed to determine the heat transfer center of the toroid or toroidal segment for circumferential and longitudinal conductance. These equations can be used to obtain more accurate results for conductive heat transfer in toroid which is a curved spacecraft components. A comparison will be made (1) using the equations derived in this paper which takes into account the curvature of the toroid (true geometry) and (2) using flat plates to simulate the toroid.
This paper, confined to the application of hard chrome plated liners to high-speed four-stroke diesel and gasoline engines, illustrates the increase in their popularity in the United Kingdom, and the advanced production methods which make this economically possible. The need for balanced engine life has long been apparent and is even more important today, the growth of motor transport having outstripped repair facilities. Iron bore life has been surpassed by improvement in the life of other component parts in the modern diesel engine. The provision of hard chrome plated liners can restore the balance. Further development and turbocharging of diesel engines has shown the need for a bore material capable of preventing scuffing and galling at elevated temperatures. Hard chrome has already proved itself in four-stroke engines under these conditions.
THE PURPOSE of this experiment was to determine the role of residual stresses in fatigue strength independent of other factors usually involved when residual stresses are introduced. It consisted of an investigation of the influence of residual stresses introduced by shotpeening on the fatigue strength of steel (Rockwell C hardness 48) in unidirectional bending. Residual stresses were varied by peening under various conditions of applied strain. This process introduced substantially the same amount and kind of surface cold working with residual stresses varying over a wide range of values. It was found that shotpeening of steel of this hardness is beneficial primarily because of the nature of the macro-residual-stresses introduced by the process. There is no gain attributable to “strain-hardening” for this material. An effort was made to explain the results on the basis of three failure criteria: distortion energy, maximum shear stress, and maximum stress.*
THIS PAPER REPORTS on the present state of the art in the utilization of refractory metals for air frame and powerplant sheet metal components. By far the most promising of these metals to date is molybdenum. The mechanical and physical properties of molybdenum are well-suited for high-temperature service. The combination of relatively high thermal conductivity, low thermal expansion coefficient, good specific heat, and a reasonably high emissivity of a coated surface make this material suitable for exterior surface application on severely aerodynamically heated components. However, in its usable alloyed forms, molybdenum tends to behave in a brittle manner at room temperature, suffering from a high brittle-to-ductile transition temperature. Other unacceptable properties are the presence of laminations in the material, 45-deg preferred angle cracking, and difficulty of controlling interstitial alloying elements. The authors discuss each of these and the progress made in overcoming them
RADIATION can produce almost instantaneous failure of modern aircraft lubricants, tests at Southwest Research Institute show. Two types of failures demonstrated are rapid viscosity rise and loss of heat conductivity. Furthermore, it was found that lubricants can become excessively corrosive under high-level radiation. Generally speaking, the better lubricants appeared to improve in performance while marginal ones deteriorated to a greater extent under radiation. When the better lubricants were subjected to static irradiation prior to the deposition test, there was a minor increase in deposition number as the total dose was increased.
In a 2-year program sponsored by SJAC, an aqueous electroplating process using alkaline Zn-Ni with trivalent chromium post treatment is under evaluation for high strength steel for aircraft application as an alternative to cadmium. Commercial Zn-15%Ni rack/barrel plating solutions are basis for plating aircraft parts or fasteners. Brightener was reduced from the original formula to form porous plating that enables bake-out of hydrogen to avoid hydrogen embrittlement condition. Properties of the deposit, such as appearance, adhesion, un-scribed corrosion resistance, and galvanic corrosion resistance in contact with Al alloy, were evaluated. Coefficient of friction was compared with Cd plating by torque-tension measurements. Evaluation of the plating for scribed corrosion resistance, primer adhesion, etc. will continue in FY2007.
For over a decade, industry prognosticators have been predicting that the use of plastics by automakers would soon surpass the deployment of metals in automobiles, While there is no denying that plastics have made inroads, it recently has become apparent that metal will retain its position as the prime car material for the foreseeable future. One reason for the revised forecast is the development of improved zinc coatings for the automotive industry. Such material as electrogalvanized and Galfan™ are shaping up as steel's saviors when it comes to ensuring that metal will continue to play the major role on car assembly lines. Meanwhile on the other side of the equation, developments in zinc die casting technology have taken the edge off plastics' forward thrust into both functional and decorative car part applications.
Copper and brass radiators have served the automobile industry for many years using traditional fabrication processes. Demand for newer and stronger radiators with lighter weight for the modern vehicles prompted investigation of alternate materials. Properties of zinc alloys and their compatibility with brass suggested these could be used for radiator manufacture. Many zinc alloy compositions were investigated in the initial studies, because a solder alloy has to have many positive attributes. The first screening studies evaluated the ability of the solder to spread over copper and brass surfaces, representing tube, fin, and header materials. The second most important feature was the melting range of the developed alloy. In order to retain the anneal resistance of the fin and temper in the tube it was desirable to have a zinc solder with a melting temperature at 800°F or less.
The extrusion of zinc alloys, with special reference to zinc-titanium alloys, is described. Parameters for this process are defined. The excellent tensile and creep properties obtained in a typical extruded zinc-titanium alloy are presented. Extruded zinc with a quality copper-nickel-chrome plated finish offers a new approach to the production of automotive trim and of similar products.