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Technical Paper

“RoHS” Compliant Chrome - Free Conversion Coating for Aerospace Manufacturing

2006-09-12
2006-01-3130
This paper presents, chemistry, test data and processing procedures on a non toxic and environmentally friendly chrome-free conversion coating alternative with the same level of adhesion and secondary corrosion resistance as that found in chrome containing conversion coating systems. Test data from military and independent sources will be presented on secondary coating adhesion, electrical conductivity, filiform and neutral salt-spray corrosion resistance as compared to chromate based systems .on magnesium, aluminum and zinc and their respective alloys. The European “RoSH” initiative will not allow for the presence of any hexavalent chromium on imported electrical components as of July first of 2006. Trivalent chromium based systems generate hexavalent chromium due to the oxidation of the trivalent chromium and as such will not be allowed.
Technical Paper

“Cromard” Thin Wall Steel Liners and Hard Chrome Plated Liners for High Production Gasoline and Diesel Engines

1964-01-01
640361
This paper, confined to the application of hard chrome plated liners to high-speed four-stroke diesel and gasoline engines, illustrates the increase in their popularity in the United Kingdom, and the advanced production methods which make this economically possible. The need for balanced engine life has long been apparent and is even more important today, the growth of motor transport having outstripped repair facilities. Iron bore life has been surpassed by improvement in the life of other component parts in the modern diesel engine. The provision of hard chrome plated liners can restore the balance. Further development and turbocharging of diesel engines has shown the need for a bore material capable of preventing scuffing and galling at elevated temperatures. Hard chrome has already proved itself in four-stroke engines under these conditions.
Technical Paper

the effect of Residual Stresses Induced by Strain-Peening upon Fatigue Strength

1960-01-01
600018
THE PURPOSE of this experiment was to determine the role of residual stresses in fatigue strength independent of other factors usually involved when residual stresses are introduced. It consisted of an investigation of the influence of residual stresses introduced by shotpeening on the fatigue strength of steel (Rockwell C hardness 48) in unidirectional bending. Residual stresses were varied by peening under various conditions of applied strain. This process introduced substantially the same amount and kind of surface cold working with residual stresses varying over a wide range of values. It was found that shotpeening of steel of this hardness is beneficial primarily because of the nature of the macro-residual-stresses introduced by the process. There is no gain attributable to “strain-hardening” for this material. An effort was made to explain the results on the basis of three failure criteria: distortion energy, maximum shear stress, and maximum stress.*
Technical Paper

Zn-Ni Plating as a Cadmium Alternative

2007-09-17
2007-01-3837
In a 2-year program sponsored by SJAC, an aqueous electroplating process using alkaline Zn-Ni with trivalent chromium post treatment is under evaluation for high strength steel for aircraft application as an alternative to cadmium. Commercial Zn-15%Ni rack/barrel plating solutions are basis for plating aircraft parts or fasteners. Brightener was reduced from the original formula to form porous plating that enables bake-out of hydrogen to avoid hydrogen embrittlement condition. Properties of the deposit, such as appearance, adhesion, un-scribed corrosion resistance, and galvanic corrosion resistance in contact with Al alloy, were evaluated. Coefficient of friction was compared with Cd plating by torque-tension measurements. Evaluation of the plating for scribed corrosion resistance, primer adhesion, etc. will continue in FY2007.
Technical Paper

Zinc-Magnesium-Aluminium (ZM)-HDG-Coated Steel Sheet for Structural Parts to Outer Panels

2017-03-28
2017-01-0507
Zinc-coatings with a substantial Magnesium content have been in use for over 30 years by now. Unlike the well-established Zn-Al-Mg coatings originating from Japan which have significant higher alloying contents applied mainly for building applications, this Zinc Magnesium Aluminum coating (ZM) is also specifically designed to meet the requirements of car manufacturers. The ZM coating introduced by voestalpine, corrender, is in the upper range of ZM-alloying compositions, which was set by VDA (German Association of the Automotive Industry) and SAE to be within 1.0 to 2.0 wt. % Mg and 1.0 to 3.0 wt. % Al. The properties of these “European” Zinc-Magnesium coatings are well comparable within this range. Compared to GI and GA ZM coatings exhibit significant advantages in the press shops with its excellent formability and reduced galling and powdering respectively which is a significant advantage for the forming of outer panels.
Technical Paper

Zinc on the Move: Advancements in Coatings and Castings Keep the Metal Competitive

1986-02-01
860611
For over a decade, industry prognosticators have been predicting that the use of plastics by automakers would soon surpass the deployment of metals in automobiles, While there is no denying that plastics have made inroads, it recently has become apparent that metal will retain its position as the prime car material for the foreseeable future. One reason for the revised forecast is the development of improved zinc coatings for the automotive industry. Such material as electrogalvanized and Galfan™ are shaping up as steel's saviors when it comes to ensuring that metal will continue to play the major role on car assembly lines. Meanwhile on the other side of the equation, developments in zinc die casting technology have taken the edge off plastics' forward thrust into both functional and decorative car part applications.
Technical Paper

Zinc Soldered Copper and Brass Radiators: Their Processing and Their Test Results

1992-02-01
920177
Copper and brass radiators have served the automobile industry for many years using traditional fabrication processes. Demand for newer and stronger radiators with lighter weight for the modern vehicles prompted investigation of alternate materials. Properties of zinc alloys and their compatibility with brass suggested these could be used for radiator manufacture. Many zinc alloy compositions were investigated in the initial studies, because a solder alloy has to have many positive attributes. The first screening studies evaluated the ability of the solder to spread over copper and brass surfaces, representing tube, fin, and header materials. The second most important feature was the melting range of the developed alloy. In order to retain the anneal resistance of the fin and temper in the tube it was desirable to have a zinc solder with a melting temperature at 800°F or less.
Technical Paper

Zinc Extrusion

1966-02-01
660051
The extrusion of zinc alloys, with special reference to zinc-titanium alloys, is described. Parameters for this process are defined. The excellent tensile and creep properties obtained in a typical extruded zinc-titanium alloy are presented. Extruded zinc with a quality copper-nickel-chrome plated finish offers a new approach to the production of automotive trim and of similar products.
Technical Paper

Zinc Electrochemical Metallizing for Corrosion Protection of Automobile Wheel Hubs

1991-10-01
912288
Many papers have been written for SAE on electrochemical metallizing, a modern term for “selective” or “brush” plating. These papers have dealt primarily with the aerospace industry, including the use of non-embrittling cadmium LHE® coatings for corrosion protection on aircraft. Shadowed by 30 years of successes in the aerospace industry, electrochemical metallizing corrosion protection in the automotive industry is often overlooked. Specifically, the use of selectively applied zinc coatings for corrosion protection on wheel hubs during manufacture has proven integral at several European automotive manufacturers. In the past, environmental conditions have corroded both the hubs and wheels of automobiles. Quite often the corrosion is in the microscopic gap between the hub and the wheel, which over time causes the wheel to seize and prevents removal. This has been frustrating to both stranded motorists and shop mechanics.
Technical Paper

Zinc Diecast Die Design for Plating Applications

1983-02-01
830178
AS PART of its continuing research to improve the die casting process, International Lead Zinc Research Organization, Inc. has prepared a computer program, “Computer-Aided Design for Zinc Die Casting Dies,” which will enable a die caster to design the metal flow system for a die within a matter of minutes—simply and more accurately than ever possible, previously. It is helping convert what has been an art into a science.
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