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Technical Paper

“Trapless” Trap – A Catalytic Combustion System of Diesel Particulates Using Ceramic Foam

“Trapless” Trap, which makes possible the effective collecting of particulates in diesel exhaust gas and their simultaneous combustion has been developed by use of a ceramic foam in combination with catalysts containing copper salt. From a TEM photograph, it was observed that the particulate was rapidly oxidized by mobile copper ion, showing worm-eaten like spots. Screening of various base metal salts by TGA presented CUCl2-KCl-NH4VO3 and CuCl2-KCl-(NH4)6Mo7O24 as very active catalysts for diesel particulate oxidation. They had thermal stability up to 900°C when they were supported on titania. The results obtained by measuring the back pressure using 1.8L diesel engine suggest the above trap to be a self-cleaning trapless trap.
Technical Paper

“OptiVent” - A New Approach for Controlling Mass Air Flow and Combustion in Direct Injection SI-Engines

Combustion concepts for future SI engines try to meet CO2-emission commitments and legislation all over the world. Where the Diesel engine has an advantage by principle, the efficiency of the SI engine has to be improved significantly, while of course the exhaust emissions must not become worse. An approach is to reduce the gas exchange losses using fully variable valve trains on the intake side of the combustion engine. OptiVent is a patented new way of controlling the mass air flow in the cylinder of a combustion engine using opening valves during the compression phase of a four stroke engine. This technology regards a wider range of variability on the valvetrain components of the engine especially for opening the valves more than one time during a cycle. On the other hand it is necessary to combine this technology with direct injection to avoid fuel losses in the exhaust system and raising the exhaust hydrocarbon emission of the engine.
Technical Paper

“OPERAS” In Advanced Diesel Engines for Commercial and Military Applications

Advanced diesel engines developed for the commercial market need to be adapted to the military requirements by OPERAS (Optimizing the injection pressure P, the Exhaust gas recirculation E, injection events Retard and/or Advance and the swirl ratio S). The different after treatment devices, already used or expected to be applied to diesel engines, require feed gases of appropriate properties for their efficient operation. To produce these gases some OPERAS are needed to control the diesel combustion process. Since military vehicles do not need the after treatment devices, the OPERAS of the commercial engines should be modified to meet the military requirements for high power density, better fuel economy, reduction of parasitic losses caused by the cooled EGR system, and reduction of invisible black and white smoke in the field.
Technical Paper

“Living and Mobility” - Minimization of the Overall Energy Consumption by Using Synergetic Effects and Predictive Information

Issues relating to the reduction of CO₂ emissions and energy consumption are currently more important than ever before. In the construction engineering and automotive sectors research and development efforts are focused closely on efficient buildings and automobiles. The designated target is a reduction in greenhouse gas emissions and overall energy demand. However, almost all approaches focus solely on either "buildings" or "mobility." By considering both aspects as a single holistic system, further energy saving potential arises due to synergetic effects. The goal of current research projects relating to Smart Homes and Vehicle to Building (V2B) is to smooth the electrical load profile on a household level rather than to reduce the individual-related total energy consumption and thereby the CO₂ emissions.
Technical Paper

“KATPROG” for the Determination of an Optimal Cost Effective Catalyst System

An two-dimensional axial symmetrical finite volume model will be introduced for the calculation of catalytic converters. It is able to predict transient temperatures and conversion rates in different converter systems according to the driving conditions. Input data are the mass-flow rate, the converter inlet temperature and the raw emissions. The performance of this model is demonstrated on an Indian motorcycle application. Cold start behavior and peak temperatures are investigated. This model has proven to be an effective tool for the preselection of an optimal cost effective catalyst system.
Technical Paper

“Investigation of High Achievable Pollutant Reduction on a “State of the Art” Indian 2 Wheelers - Technology Road Map to a Cleaner Air”

Affordable, efficient and durable catalytic converters for the two and three wheeler industry in developing countries are required to reduce vehicle emissions and to participate in a cleaner and healthier environment. As a contribution Continental Emitec started a comprehensive testing program with a state of the art 180 cc Bharat Stage (BS) III Indian motorcycle. The program consists of testing the state of the art of Metallic substrates with structured foils with various catalyst sizes and positions (original or close coupled). The publication presents a short literature survey and the results of the investigation with a big catalyst volume mounted in underfloor position as well as in close coupled position, gained over the World-wide harmonized Motorcycle Test Cycle, considering the two possible vehicle classifications of this motorcycle, Sub-Class 2.1 and Sub-Class 2.2.
Technical Paper

“Influence of Engine Variables on Exhaust Oxides of Nitrogen Concentrations from a Multi-Cylinder Engine”

The influence of engine variables on the concentration of oxides of nitrogen present in the exhaust of a multicylinder engine was studied. The concentrations of nitric oxide (NO) were measured with either a mass spectrometer or a non-dispersive infrared analyzer. The NO concentration was low for rich operation (deficient in oxygen) and increased with air-fuel ratio to a peak value at ratios slightly leaner than stoichiometric proportions. A further increase in air-fuel ratio resulted in reduced NO concentrations. Advanced spark timing, decreased manifold vacuum, increased coolant temperature and combustion chamber deposit buildup were also found to increase exhaust NO concentration. These results support either directly or indirectly the hypothesis that exhaust NO concentration is primarily a result of the peak combustion gas temperature and the available oxygen.
Technical Paper

“Future” Diesel Fuel Compositions - Their Influence on Particulates

Five different diesel fuels, having been made available by the mineral oil industry within the framework of a research program of the Coordinating European Council (CEC/PF-26), were examined in addition to this program by the Klöckner-Humboldt-Deutz AG by means of the 13-mode test in accordance with the former US legislation and the ECE regulation No. 49 and by US Transient Tests. The results have been compared with results based on commercial European diesel fuel. There has been observed the emission behaviour of an 8-cylinder NA engine with a “state of the art” direct fuel injection system by particularly taking into consideration the particulate emission and the particulate components. The gaseous emissions, particularly CO and HC, are unfavourably influenced by low cetane numbers being associated with increased aromaticity in the diesel fuel.
Technical Paper

“Fuel Flow Method2” for Estimating Aircraft Emissions

In recent years there has been increasing interest in quantifying the emissions from aircraft in order to generate inventories of emissions for climate models, technology and scenario studies, and inventories of emissions for airline fleets typically presented in environmental reports. The preferred method for calculating aircraft engine emissions of NOx, HC, and CO is the proprietary “P3T3” method. This method relies on proprietary airplane and engine performance models along with proprietary engine emissions characterizations. In response and in order to provide a transparent method for calculating aircraft engine emissions non proprietary fuel flow based methods 1,2,3 have been developed. This paper presents derivation, updates, and clarifications of the fuel flow method methodology known as “Fuel Flow Method 2”.
Technical Paper

“Evaluation of the Drift of vehicle Inspection/Maintenance Emission Analyzers in use- A California Case Study”

Quality assurance (QA) in motor vehicle emissions inspection/maintenance (I/M) programs is a continuing concern, especially in decentralized programs with hundreds or even thousands of licensed stations. The emissions analyzers used in such stations are an important focus of governmental QA efforts because of the central role of analyzers in determining which vehicles need to be repaired. Therefore, the In-use performance of I/M emission analyzers has a large impact on the quality of 1/M programs as a whole. This paper reports on the results of an investigation in California designed to determine in-use performance of emission analyzers in the field. The investigation was designed to evaluate both drift rates and the ability of analyzer systems with automatic gas calibration capability to correct analyzer responses outside of accepted tolerances.
Technical Paper

“Doing More with Less” - The Fuel Economy Benefits of Cooled EGR on a Direct Injected Spark Ignited Boosted Engine

Due to the rising costs of fuel and increasingly stringent regulations, auto makers are in need of technology to enable more fuel-efficient powertrain technologies to be introduced to the marketplace. Such powertrains must not sacrifice performance, safety or driver comfort. Today's engine and powertrain manufacturers must, therefore, do more with less by achieving acceptable vehicle performance while reducing fuel consumption. One effective method to achieve this is the extreme downsizing of current direct injection spark ignited (DISI) engines through the use of high levels of boosting and cooled exhaust gas recirculation (EGR). Key challenges to highly downsized gasoline engines are retarded combustion to prevent engine knocking and the necessity to operate at air/fuel ratios that are significantly richer than the stoichiometric ratio.
Technical Paper

“Catalytic Engine” NOx Reduction of Diesel Engines with New Concept Onboard Ammonia Synthesis System

Ammonia is one of the most useful compounds that react with NOx selectively on a catalyst, such as V2O5-TiO2, under oxygen containing exhaust gas. However ammonia cannot be stored because of its toxicity for the small power generator in populated areas or for the diesel vehicles. A new concept for NOx reduction in diesel engine using ammonia is introduced. This system is constructed from the hydrogen generator by fuel reformer, the ammonia synthesizer, SCR catalyst for NOx reduction and the gas injection system of reformed gas into the cylinder. Experimental results show that, the SCR catalyst provides a very high rate of NOx reduction, reformed gas injection into cylinder is very effective for particulate reduction. WHEN CONSIDERING INTERNAL COMBUSTION ENGINES of the 1990's the question of how to harmonize the engine with the natural environments is one of the greatest problems. The internal combustion engine changes a substance into energy via its explosive combustion.
Technical Paper

“A Flame Ionization Technique for Measuring Total Hydrocarbons in Diesel Exhaust”

The method of flame ionization was used for measuring total hydrocarbons in both single-cylinder and multicylinder 4-cycle, direct injection diesel engine exhaust. Use of the emission parameters of hydrocarbon concentration, per cent unburned fuel, specific hydrocarbon rate, mass of hydrocarbons per million cycles, mass of hydrocarbons per mile, and mass of hydrocarbons per ton-mile are discussed. The basic approach used in the flame ionization detector is shown. The hydrocarbon sample was transferred from the exhaust system through a heated sample line and oven operating at 375 F. The sample line was aspirated to reduce the sample residence time to 2 sec. The effect various sampling locations have on hydrocarbon measurements from a single-cylinder engine is shown and discussed. The effects of load, speed, and injection timing on hydrocarbon emission data are shown for a single-cylinder engine.
Technical Paper

‘Regulated’ and ‘Non-regulated’ Emissions from Modern European Passenger Cars

Regulated emissions from four current production European vehicles were measured over the Common Artemis Driving Cycles (CADC). Particulate Mass and Particle Number measurements were made in accordance with the newly-developed draft Particulate Measurement Programme (PMP) developed for the UN-ECE's expert group on pollution and energy (GRPE). During the test programme measurements were also made of currently non-regulated emissions including PAHs and speciation of the particulate material and key hydrocarbons. CADC results are presented for each of the four vehicles tested (one conventional gasoline vehicle, two different types of diesel without Diesel Particulate Filter (DPF) and one diesel with DPF) with results measured on the regulated New European Driving Cycle (NEDC) test for comparison. The emissions results on the Artemis cycles showed some significant differences from those on the regulated (NEDC) test cycle.
Technical Paper

‘Issues and Behaviors of Airborne Particulate Matters under Microgravity Environment’

During several ISS missions, there were false alarms at both US and Russian smoke detectors. High local airborne particulate concentrations and interior deposits are considered the causes for such anomalies. Alternatives are proposed to replace or complement these faulty smoke detectors. The entrained zeolite particles may play a role in causing problems with check valves and air save pumps in CDRA and Vozdukh. Another incidence has been the dispersion of particulates out of Metox regeneration oven. Particulate matters with aerodynamic diameter of 15 microns and above, which normally settle down on earth, stay airborne under micro-gravity and thereby cause the above-mentioned nuisances. The motion of such a particle along a gas stream with an initial velocity can be expressed by theoretical equations. Stokes' Law leads to the descriptions of inertial precipitation of aerosols that are important in solving the issues.
Technical Paper

‘A Comparative Study of the Integrity of Joints Between Multilayer Fuel Line Constructions and Different Connector ‘Barb’ Designs

With the advent of low evaporative emission requirements there has been the rapid adoption of multilayer extrusion technology into the production of Fuel and Vapour tubing used on Fuel systems on automobiles. Multilayer extrusion technology enables a manufacturer of Fuel and Vapour tubing to simultaneously co-extrude dissimilar thermoplastic materials in tubular form. This allows the manufacturer to combine expensive and brittle high performance evaporative emission ‘barrier’ polymers with lower cost engineering polymers. However, it is a well-known characteristic of these multilayer tube constructions that the joints between them and connector ‘barbs’ have lower joint integrity. Joint integrity is most often quantified by ‘Pull-off’ and leakage tests. Recent developments in LEV-II requirements for 2004 and beyond indicate that joint integrity will become a focus area for study and improvement.
Technical Paper

λDSF: Dynamic Skip Fire with Homogeneous Lean Burn for Improved Fuel Consumption, Emissions and Drivability

Dynamic skip fire (DSF) has shown significant fuel economy improvement potential via reduction of pumping losses that generally affect throttled spark-ignition (SI) engines. In DSF operation, individual cylinders are fired on-demand near peak efficiency to satisfy driver torque demand. For vehicles with a downsized-boosted 4-cylinder engine, DSF can reduce fuel consumption by 8% in the WLTC (Class 3) drive cycle. The relatively low cost of cylinder deactivation hardware further improves the production value of DSF. Lean burn strategies in gasoline engines have also demonstrated significant fuel efficiency gains resulting from reduced pumping losses and improved thermodynamic characteristics, such as higher specific heat ratio and lower heat losses. Fuel-air mixture stratification is generally required to achieve stable combustion at low loads.
Technical Paper

α-Pinene - A High Energy Density Biofuel for SI Engine Applications

This study proposes a novel biofuel for spark ignition (SI) engine, α-pinene (C10H16), which is non-oxygenated and thus has a gravimetric energy density comparable to that of hydrocarbon fuels. The ignition characteristics of α-pinene were evaluated in an ignition quality tester (IQT) under standard temperature and pressure conditions. The measured ignition delay time (IDT) of α-pinene is 10.5 ms, which is lower than that of iso-octane, 17.9 ms. The estimated research octane number (RON) for pinene from IQT is 85. A temperature sweep in IQT showed that that α-pinene is less reactive at low temperatures, but more reactive at high temperatures when compared to isooctane. These results suggest that α-pinene has high octane sensitivity (OS) and is suitable for operation in turbocharged SI engines. With these considerations, α-pinene was operated in a single cylinder SI engine.