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Journal Article

Sensitivity Analysis of Ash Packing and Distribution in Diesel Particulate Filters to Transient Changes in Exhaust Conditions

2012-04-16
2012-01-1093
Current CJ-4 lubricant specifications place chemical limits on diesel engine oil formulations to minimize the accumulation of lubricant-derived ash in diesel particulate filters (DPF). While lubricant additive chemistry plays a strong role in determining the amount and type of ash accumulated in the DPF, a number of additional factors play important roles as well. Relative to soot particles, whose residence time in the DPF is short-lived, ash particles remain in the filter for a significant fraction of the filter's useful life. While it is well-known that the properties (packing density, porosity, permeability) of soot deposits are primarily controlled by the local exhaust conditions at the time of particle deposition in the DPF, the cumulative operating history of the filter plays a much stronger role in controlling the properties and distribution of the accumulated ash.
Journal Article

Radio Frequency Diesel Particulate Filter Soot and Ash Level Sensors: Enabling Adaptive Controls for Heavy-Duty Diesel Applications

2014-09-30
2014-01-2349
Diesel Particulate Filters (DPF) are a key component in many on- and off-road aftertreatment systems to meet increasingly stringent particle emissions limits. Efficient thermal management and regeneration control is critical for reliable and cost-effective operation of the combined engine and aftertreatment system. Conventional DPF control systems predominantly rely on a combination of filter pressure drop measurements and predictive models to indirectly estimate the soot loading state of the filter. Over time, the build-up of incombustible ash, primarily derived from metal-containing lubricant additives, accumulates in the filter to levels far exceeding the DPF's soot storage limit. The combined effects of soot and ash build-up dynamically impact the filter's pressure drop response, service life, and fuel consumption, and must be accurately accounted for in order to optimize engine and aftertreatment system performance.
Journal Article

Direct Measurements of Soot/Ash Affinity in the Diesel Particulate Filter by Atomic Force Microscopy and Implications for Ash Accumulation and DPF Degradation

2014-04-01
2014-01-1486
Inorganic engine lubricant additives, which have various specific, necessary functions such as anti-wear, leave the combustion chamber bound to soot particles (approximately ≤1% by mass) as ash [13], and accumulate in aftertreatment components. The diesel particulate filter (DPF) is especially susceptible to ash-related issues due to its wall-flow architecture which physically traps most of the soot and ash emissions. Accumulated lubricant-derived ash results in numerous problems including increased filter pressure drop and decreased catalytic functionality. While much progress has been made to understand the macroscopic details and effects of ash accumulation on DPF performance, this study explores the nano- and micron-scale forces which impact particle adhesion and mobility within the particulate filter.
Journal Article

Characteristics and Effects of Lubricant Additive Chemistry on Ash Properties Impacting Diesel Particulate Filter Service Life

2010-04-12
2010-01-1213
Ash accumulation in diesel particulate filters, mostly from essential lubricant additives, decreases the filter's soot storage capacity, adversely affects fuel economy, and negatively impacts the filter's service life. While the adverse effects of ash accumulation on DPF performance are well known, the underlying mechanisms controlling these effects are not. To address these issues, results of detailed measurements with specially formulated lubricants, correlating ash properties to individual lubricant additives and their effects on DPF pressure drop, are presented. Investigations using the specially-formulated lubricants showed ash consisting primarily of calcium sulfates to exhibit significantly increased flow resistance as opposed to ash primarily composed of zinc phosphates. Furthermore, ash accumulated along the filer walls was found to be packed approximately 25% denser than ash accumulated in the channel end-plugs.
Technical Paper

Characteristics and Effects of Ash Accumulation on Diesel Particulate Filter Performance: Rapidly Aged and Field Aged Results

2009-04-20
2009-01-1086
Ash, mostly from essential lubricant additives, affects diesel particulate filter (DPF) pressure-drop sensitivity and limits filter service life. It raises concern in the lubricant industry to properly specify new oils, and engine and aftertreatment system manufacturers have attempted to find ways to mitigate the problem. To address these issues, results of detailed measurements of ash characteristics in the DPF and their effects on filter performance are presented. In this study, a heavy-duty diesel engine was outfitted with a specially designed rapid lubricant degradation and aftertreatment ash loading system. Unlike previous studies, this system allows for the control of specific exhaust characteristics including ash emission rate, ash-to-particle ratio, ash composition, and exhaust temperature and flow rates independent of the engine operating condition.
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