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A study of unsteady compressible flow for two types of exhaust manifold and CCC (Close-Coupled Catalyst) systems attached to a 4-cylinder DOHC gasoline engine was carried out to investigate the flow distribution of exhaust gases and finally to make the conversion efficiency of catalyst better. An experimental study was conducted, using LDV technique, to measure the velocity distributions inside exhaust manifolds and CCC under practical engine conditions. In this study, through experiment and calculation, the effects of geometric configuration of exhaust manifold on flow maldistribution in monolith were mainly investigated to understand the exhaust flow structure in terms of flow uniformity and to improve the conversion efficiency. As a result of this fundamental study, the modified exhaust manifold (Type B) was designed and manufactured. Full load performance tests and vehicle emission tests were performed to see the effects of flow characteristics on engine performance and emission.

A combined experimental and computational study of 3-D unsteady compressible flow in exhaust manifold and CCC system was performed to understand the flow characteristics and to improve the flow distribution of pulsating exhaust gases within monolith. An experimental study was carried out to measure the velocity distribution in production exhaust manifold and CCC under engine operating conditions using LDV (Laser Doppler Velocimetry) system. Velocity characteristics were measured at planes 25 mm away from the front surface of first monolith and between two monolithic bricks. To provide boundary conditions for the computational study, velocity fields according to crank angle were also measured at the entrance of exhaust manifold. The comparisons of exhaust gas flow patterns in the junction and mixing pipe between experimental and computational results were made.

Efficient hydrocarbon (HC) trap materials have been developed to trap the major emitting HC compounds from gasoline direct injection engines. Online FTIR measurements on different test cycles and catalytic systems showed that AHC, C5 compounds, and CH4 were the most emitted species at cold-start phase (up to 100 sec). Making AHC and C5 as targets for improving the HC light-off, lab scale reactor set-up was established with toluene and iso-pentane feed pumping system along with propane-propene mixture. TGA screening experiments conducted with ex-situ toluene adsorption and the results revealed that BEA type materials have moderate to higher HC trapping temperature and HC storage capacity. In the present investigation, BEA-HS exhibited outstanding stability and trapping ability even after 850 °C hydrothermal aging. PGM and TM based BEA materials were evaluated for HC-TPD experiments with TWC gas composition.

Improved Lean NOx Trap (LNT) catalysts with enhanced NH3 generation feature were developed for the small diesel engine. The next generation LNT system needs to perform good NOx conversions over the wide temperature range including below 200°C for urban driving and above 400°C for motorway of real road driving. However, the extended use of BaO, a component of LNT known to be very effective for high temperature NOx storage, results in the decrease of low temperature NOx conversion due to the degradation of NO oxidation associating with sulfur over time. The improvement of the low-temperature LNT performance is a key requirement for the real driving emission control as the best operation temperature for urea-SCR is above ~250°C. In this study, our next generation LNT with new washcoat architecture has demonstrated improved NOx removal efficiencies under the wider operation temperature window than the current production technology.

We developed new single coated Pd/Rh three-way catalysts (TWC). Several Pd/Rh single layered catalysts were prepared by changing the precious metal (PM) fixation method and adding new base metal oxides (BMO). These samples were compared with double-coated catalyst by using model gas activity test, BET test, XRD test and vehicle emission test. It is found that the performance of the single coated catalyst is as good as that of commercialized double-coated catalyst. The oxygen storage capacity of the single coated catalyst is better than that of double-coated catalyst. Moreover, manufacturing the single coated catalyst enables us to eliminate the unnecessary coating process which is essential to the conventional one. Our test results demonstrate that the developed catalyst has sufficient activity and durability of OSC to meet emission and OBD-II regulations.

Recently, the design of automotive headlamps has become diversified and complicated according to customer needs. Hence, structural complexity of the headlamps has also increased. Complex structure of the headlamps inevitably causes a disturbance in air circulation. For this reason, inadvertent micro-sized water droplets, called fogging, are condensed on the inner surface of headlamp lens due to temperature difference between the inner and outer lens surfaces. To circumvent fogging inside of the headlamp lens, an anti-fogging coating is indispensable. Conventionally, diverse surfactants have been adopted as substantial material for the anti-fogging coating. However, the usage of the surfactants causes undesirable side effect such as water mark arising from vapor condensation, which is an important issue that must be fully resolved. In this study, we developed an innovative anti-fogging coating material without using conventional surfactant.

The integration of SCR catalyst into diesel-particulate filter (SDPF) may be one of most viable ways to meet upcoming stringent emission regulations with new test protocols such as Worldwide harmonized Light vehicles Test Cycles (WLTC) and Real Driving Emissions (RDE) requirements. The chabazite-structured SSZ-13-based catalysts enabled the wide implementation of urea-SCR technology for mobile applications due to their robust thermal stability up to 750°C compared to the thermally unstable ZSM-5-based technologies. However, the thermally stable Cu-SSZ-13 catalyst starts losing its initial activity with the increase of aging time at 850°C, where the SCR catalyst on SDPF can possibly be exposed during filter regeneration under a drop-to-idle (DTI) condition. Therefore, more durable SCR catalysts that survive under higher temperatures have been strongly desired in automotive industry. Recently, we found Cu-exchanged high silica LTA revealed an excellent hydrothermal stability.

HC-SCR is more convenient when compared to urea-SCR, since for HC-SCR, diesel fuel can be used as the reductant which is already available onboard the vehicle. However, the DeNOX efficiency for HC-SCR is lower than that of urea-SCR in both low and high temperature windows. In an attempt to improve the DeNOX efficiency of HC-SCR, the effect of hydrogen were evaluated for the fresh and aged catalyst over 2 wt.% Ag/Al₂O₃ using a Euro-4 diesel engine. In this engine bench test, diesel fuel as the reductant was injected directly into the exhaust gas stream and the hydrogen was supplied from a hydrogen bomb. The engine was operated at 2,500 rpm and BMEP 4 bar. The engine-out NOX was around 180 ppm-200 ppm. H₂/NOX and HC₁/NOX ratios were 5, 10, 20, and 3, 6, 9, respectively. The HC-SCR inlet exhaust gas temperatures were around 215°C, 245°C, and 275°C. The catalyst volumes used in this test were 2.5L and 5L for both fresh and aged catalysts.

Compressed natural gas (CNG) has been regarded as an alternative fuel for current fossil fuels such as gasoline and diesel. Recently the increasing interest in shale gas is drawing more attention to CNG vehicles of which number is expected to increase. Exhaust gas from CNG engines with lean combustion contains relatively low nitrogen oxides and particulate matters compared to conventional fossil fuel based engines. However, high amount of unburned methane, which has much higher greenhouse warming potential than CO2, limits the wide use of CNG for many applications. Even though Pd-based catalysts have been popularly studied in order to convert methane, their activity and durability have not been sufficient for practical applications to aftertreatment of lean burn CNG engines and the formation of a new Pd containing.

The worldwide fuel economy compliance level has been tightening, at the same time, LEV-III/Euro-6d/China-6/BS-6 regulations for NMOG and NOx emissions are being introduced or already effective. Therefore, intensive research effort has been conducted in order to improve the fuel efficiency of passenger cars and reduce exhaust emission. In response to these demands, turbocharged gasoline direct injection (TGDI) engine is being introduced for gasoline vehicles in consideration of fuel efficiency improvement, high output and driving performance compared to naturally aspirated (NA) engine. However, due to its larger thermal mass from the turbo hardware in the exhaust, it suffers from the cold-start emission. The main hazardous gases emitted from gasoline vehicles are CO, HC and NOx, and a three-way catalyst (TWC) is installed for the purification of these harmful emissions.

Generally, vehicles do not need power during deceleration. Therefore, the fuel efficiency can be improved by stopping the fuel injection in this period. However, when the fuel cut is activated, NOx is emitted immediately after fuel cut. During the fuel cut period, a large amount of fresh air flows into the catalytic converter installed on a vehicle since there is no combustion. Thus, the catalytic materials are converted into an oxidizing atmosphere. As a result, NOx purification performance of the catalyst deteriorates, and eventually NOx is emitted when combustion restarts. The quantity of NOx in this period is relatively small. However, in case of increasing fuel cuts, emission problem could arise. Therefore, in order to meet the stringent regulation such as LEV III-SULEV20 or 30, the number of fuel cuts need to be limited. The problem is that this strategy leads to a disadvantage of fuel efficiency.

As the current and future emission regulations become stringent, the research on exhaust manifold with CCC (Close Coupled Catalyst) has been the interesting and remarkable subject. To design of exhaust manifold with CCC is a difficult task due to the complexity of the flow distribution caused by the pulsating flows that are emitted at the exhaust ports. This study is concerned with the theoretical and experimental approach to improve catalyst flow uniformity through the basic understanding of exhaust flow characteristics. Computational and experimental approach to the flow for exhaust manifold of conventional cast type, stainless steel bending type with 900 cell CCC system in a 4-cylinder gasoline engine was performed to investigate the flow distribution of exhaust gases.

Urea-SCR systems have become one effective method for meeting the ever tightening NOx emission control regulations for diesel engines. Higher activity of SCR catalysts in the low temperature region is crucial for meeting emission regulations and improving fuel economy. Some of the new catalytic components in the literature have shown good low temperature SCR activity, but they have not been fully confirmed to be durable enough for mobile applications. Fe-zeolite has been widely used in mobile applications due to its wide operating temperature window, but after exposure to large amounts of HCs at low temperatures, it is easily deactivated. We developed new SCR catalysts with improved low temperature activity and improved durability against HC fouling and thermal sintering by combining OSC (oxygen storage component) with Fe-zeolite.