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The particulate matter (PM) produced from a diesel engine-simulating combustor was characterized in its morphology, microstructure, and fractal geometry by using a unique thermophoretic sampling and Transmission Electron Microscopy (TEM) system. These results revealed that diesel PM produced from the laboratory-scale burner showed similar morphological characteristics to the particulates produced from diesel engines. The flame air/fuel ratio and the particulate temperature history have significant influences on both particle size and fractal geometry. The primary particle sizes were measured to be 14.7 nm and 14.8 nm under stoichiometric and fuel-rich flame conditions, respectively. These primary particle sizes are smaller than those produced from diesel engines. The radii of gyration for the aggregate particles were 83.8 nm and 47.5 nm under these two flame conditions.

A thermophoretic particulate sampling device was used to investigate the detailed morphology and microstructure of diesel particulates at various engine-operating conditions. A 75 HP Caterpillar single-cylinder direct-injection diesel engine was operated to sample particulate matter from the high-temperature exhaust stream. The morphology and microstructure of the collected diesel particulates were analyzed using a high-resolution transmission electron microscope and subsequent image processing/data acquisition system. The analysis revealed that spherical primary particles were agglomerated together to form large aggregate clusters for most of engine speed and load conditions. Measured primary particle sizes ranged from 34.4 to 28.5 nm at various engine-operating conditions. The smaller primary particles observed at high engine-operating conditions were believed to be caused by particle oxidation at the high combustion temperature.