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A novel ambient dilution tunnel has been designed, tested and employed to measure the emissions from active parked regenerations of Diesel Particulate Filters (DPFs) for 2007 and 2010 certified heavy duty diesel trucks (HDDTs). The 2007 certified engine had greater regulated emissions than the 2010 certified engine. For a fully loaded 2007 DPF there was an initial period of very large mass emissions, which was then followed by very large number of small particle emissions. The Particle Size Distribution, PSD, was distributed over a large range from 10 nm to 10 μm. The parked regenerations of the 2010 DPF had a much lower initial emission pattern, but the second phase of large numbers of small particles was very similar to the 2007 DPF. The emission results during regeneration have been compared to total emissions from recent engine dynamometer testing of 2007 and 2010 DPFs, and they are much larger.

Emissions of particulate matter, or PM, due to brake wear, are not well quantified in current air pollutant emission inventories. Current emission factor models need to be updated to reflect new technologies and materials and to incorporate the effects of changing driving habits and speeds. While emission regulations drive technical innovations that are significantly reducing PM emissions in vehicle exhaust, non-exhaust automotive emissions remain unregulated. Current emission factor models need to be updated to reflect the changes caused by new technologies, materials, and speed-dependent vehicle usage. Most research regarding brake emissions relies on a laboratory setting. Laboratory testing has allowed researchers, application engineers, data modeling engineers, and environmental agencies to generate large datasets for multiple vehicle configurations and friction couple designs.

Heavy-duty vehicles account for approximately 30 percent of the oxides of nitrogen (NOx) and 65 percent of the particulate matter (PM) emissions from the entire California on-road fleet, despite the fact that these vehicles comprise only 2 percent of the same. To meet legislative mandates to reduce excess smoke emissions from in-use heavy-duty diesel-powered vehicles, the Air Resources Board (ARB or Board) adopted, in December 1997, amendments to the regulations governing the operation and enforcement of the Heavy-Duty Vehicle Inspection Program (HDVIP or the “roadside” program) and the Periodic Smoke Inspection Program (PSIP or the “fleet” program). The initial roadside program was adopted in November 1990 in response to Senate Bill (SB) 1997 (stat. 1988, ch. 1544, Presley), and enforced from 1991 to 1993. It was suspended in October 1993, when the Board redirected staff to investigate reformulated fuels issues.

While most studies addressing the fuel effects are based on the Federal Test Procedure (FTP), there are limited studies investigating the fuel effects outside FTP test conditions. In this study, we investigated the differences in exhaust emissions from California Phase 1 to Phase 2 reformulated gasoline over a wide range of speed and ambient temperatures. Eleven catalyst equipped passenger vehicles were tested. The vehicles were comprised of three fuel delivery system configurations, namely, three from carburetor (CARBU), three from throttle body injection (TBI), and five from multi-port fuel injection (MPFI) group. Each vehicle was given 60 tests with the combination of two reformulated fuels: Phase 1 (without oxygenates) and Phase 2 (with oxygenates), three temperatures (50, 75, and 100 °F), and ten speed cycles (average speed ranges from 4 mph to 65 mph).

Light duty gasoline vehicles (LDGV) are estimated to contribute 40% of the total on-road mobile source tailpipe emissions of particulate matter (PM) in California. While considerable efforts have been made to reduce toxic diesel PM emissions going into the future, less emphasis has been placed on PM from LDGVs. The goals of this work were to characterize a small fleet of visibly smoking and high PM emitting LDGVs, to explore the potential PM-reduction benefits of Smog Check and of repairs, and to examine remote sensing devices (RSD) as a potential method for identifying high PM emitters in the in-use fleet. For this study, we recruited a fleet of eight vehicles covering a spectrum of PM emission levels. PM and criteria pollutant emissions were quantified on a dynamometer and CVS dilution tunnel system over the Unified Cycle using standard methods and real time PM instruments.

This study provides one of the first evaluations of the integrated particle size distribution (IPSD) method in comparison with the current gravimetric method for measuring particulate matter (PM) emissions from light-duty vehicles. The IPSD method combines particle size distributions with size dependent particle effective density to determine mass concentrations of suspended particles. The method allows for simultaneous determination of particle mass, particle surface area, and particle number concentrations. It will provide a greater understanding of PM mass emissions at low levels, and therefore has the potential to complement the current gravimetric method at low PM emission levels. Six vehicles, including three gasoline direct injected (GDI) vehicles, two port fuel injected (PFI) vehicles, and one diesel vehicle, were tested over the Federal Test Procedure (FTP) driving cycle on a light-duty chassis dynamometer.

This paper summarizes the Heavy-Duty In-Use Testing (HDUIT) measurement allowance program for Particulate Matter Portable Emissions Measurement Systems (PM-PEMS). The measurement allowance program was designed to determine the incremental error between PM measurements using the laboratory constant volume sampler (CVS) filter method and in-use testing with a PEMS. Two independent PM-PEMS that included the Sensors Portable Particulate Measuring Device (PPMD) and the Horiba Transient Particulate Matter (TRPM) were used in this program. An additional instrument that included the AVL Micro Soot Sensor (MSS) was used in conjunction with the Sensors PPMD to be considered a PM-PEMS. A series of steady state and transient tests were performed in a 40 CFR Part 1065 compliant engine dynamometer test cell using a 2007 on-highway heavy-duty diesel engine to quantify the accuracy and precision of the PEMS in comparison with the CVS filter-based method.

The California Air Resources Board (CARB) examined the performance of a Partial Flow Sampling System (PFSS) against a reference Constant Volume Sampling (CVS) system in measuring emissions from a heavy-duty vehicle (HDV) during dynamometer testing at CARB's Stockton Heavy-Duty Emissions Laboratory (SL). The SL PFSS system is a Sierra BG-2 system that uses flow-based (rather than CO2-based) dilution. The CVS system uses the University of California, Riverside's (UCR) Mobile Emissions Laboratory (MEL). The test vehicle was a 2000 model-year HD tractor powered by a CAT C-15 engine. Exhaust samples were collected simultaneously with the SL and MEL systems and analyzed for total particulate matter (PM), oxides of nitrogen (NOx), carbon dioxide (CO2), carbon monoxide (CO), and total hydrocarbons (THC). The samples were taken during steady-state vehicle operation. Each test mode was repeated seven times in each of two patterns: consecutive and sequential.

The California Air Resources Board (CARB) adopted the Low Emission Vehicle (LEV) III regulations in January 2012, which lowered the particulate matter (PM) emissions standards for light-duty vehicles (LDVs) from 10 milligrams per mile (10 mg/mile) to 3 mg/mile beginning with model year (MY) 2017 and 1 mg/mile beginning with MY 2025. To confirm the ability to measure PM emissions below 1 mg/mile, a total of 23 LDVs (MY pre-2004 to 2009) were tested at CARB's Haagen-Smit Laboratory (HSL) (10 LDVs) and the United States Environmental Protection Agency's (US EPA) National Vehicle and Fuel Emissions Laboratory (NVEFL) (13 LDVs) using the federal test procedure (FTP) drive schedule. One LDV with PM emissions ranging from 0.6 - 0.8 mg/mile was tested at three CARB HSL test cells to investigate intra-lab and inter-lab variability. Reference, trip, and tunnel filter blanks were collected as part of routine quality control (QC) procedures.

Present motor vehicle particulate matter (PM) emission measurement regulations (Code of Federal Regulations (CFR) 40 Part 1065, 1066) require gravimetric determination of PM mass collected onto filter media from dilute exhaust. To improve the current sampling and measurement procedures for TIER 3 PM emissions standard of 3 mg/mile, CFR part 1066 adopted five alternative PM sampling options. One option of great interest is sampling the entire test using a single flow-weighed filter rather than the conventional three-filter (one filter per test phase) approach. The single filter method could lessen the time needed for gravimetric determination by reducing the quantity of filters used for a test and possibly reduce the uncertainty in gravimetric measurements, particularly at sub 1 mg/mile PM levels. This study evaluates the single filter and, to a limited extent, the 2-filter alternatives adopted in 40 CFR Part 1066.

The impact of biodiesel and new generation biofuels on emissions from heavy-duty diesel engines was investigated using a California Air Resources Board (CARB) certified diesel fuel as a base fuel. This study was performed on two heavy-duty diesel engines, a 2006 engine and a diesel particle filter (DPF) equipped 2007 engine, on an engine dynamometer over four different test cycles. Emissions from soy-based and animal-based biodiesel, renewable diesel fuel, and gas-to-liquid (GTL) diesel fuel were evaluated at blend levels ranging from 5 to 100%. Consistent with previous studies, particulate matter (PM), hydrocarbons (HC), and carbon monoxide (CO) emissions generally showed increasing reductions with increasing biodiesel and renewable/GTL diesel fuel blend levels for the non-DPF equipped engine. The levels of these reductions were generally comparable to those found in previous studies performed using more typical Federal diesel fuels.

The sampling protocol proposed by the international PMP program for determination of particle emissions from clean light-duty vehicles was applied to the emissions from a California heavy-duty trap-equipped diesel truck. CARB is interested in developing opinions about the potential of this new European approach for emission determination and in exploring its utility for use in California. In this exercise, the use of various commercially available instruments for counting and sizing particles in the context of the PMP recommendations are explored. A single vehicle on a chassis dynamometer was exercised over steady-state and transient cycles. Multiple measurements of gaseous, mass, and particle emissions were collected in order to determine statistical significance. The PMP approach yielded particle emission measurements with higher precision and accuracy than the reference mass-based emission measurement.

Neat methanol fuel (M100) has many advantages for achieving low emission levels as an automotive fuel, but there are several items that require attention before this fuel can replace conventional fuels. One item involves the low flame luminosity of methanol. An extensive literature search and laboratory evaluation were conducted to identify potential additive candidates to improve the luminosity of a methanol flame. Potential compounds were screened based on their concentration, luminosity improvement, and duration of luminosity improvement during the burn. Three compounds were found to increase the flame luminosity for segments of the burn at relatively low concentrations: toluene, cyclopentene, and indan. In combination, these three compounds markedly improved the luminosity of methanol throughout the majority of the burn. The two combinations were 1) 4 percent toluene plus 2 percent indan and 2) 5 percent cyclopentene plus 5 percent indan in methanol.

The U.S. EPA and the California Air Resources Board have adopted standards to reduce emissions from recreational marine vessels. Existing regulations focus on reducing hydrocarbons. There are no regulations on particulate emissions; particulate is expected to be reduced as a side benefit of hydrocarbon control. The goal of this study was to develop a sampling methodology to measure particulate emissions from marine outboard and personal watercraft engines. Eight marine engines of various engine technologies and power output were tested. Emissions measured in this program included hydrocarbons, carbon monoxide, oxides of nitrogen. Particulate emissions will be presented in a follow-up paper.

In order to demonstrate the performance of a retrofitted selective catalytic reduction (SCR) system while also addressing the issues associated with greater use of biodiesel, a 2005 International 9200i tractor owned by the City of Santa Monica was retrofitted with a titania-vanadia-tungsten catalyst and a urea dosing system supplied by Extengine Systems, Inc. This tractor was operated under normal service conditions within the City of Santa Monica refuse collection and transportation fleet. An on-board emissions measurement system supplied by Engine, Fuel, and Emissions Engineering, Inc. was installed on the vehicle; it measured the emissions and fuel use of the vehicle while it operated on ultra-low-sulfur diesel (ULSD), 20% biodiesel (B20), and 99% biodiesel (B99) on consecutive days.

The California Air Resources Board requires that new California vehicles be equipped with on-board diagnostic (OBD) systems. Starting with the 1988 models, these systems were required on new passenger cars, light-duty trucks and medium-duty vehicles equipped with three-way catalysts and feed-back fuel controls. The purpose of the OBD system is to expedite the proper repair of emission-related malfunctions and, thus, reduce vehicle emissions. When malfunctons are detected, a malfunction indicator light (MIL) mounted in the dash panel illuminates cautioning the vehicle operator that a repair is needed. Also, a fault code is stored in the OBD computer memory. When the vehicle is brought to a repair facility, the fault code provides the mechanic with the likely areas of malfunction for repairing the vehicle. After the repair is performed, the fault code is cleared, the MIL is extinguished, and the OBD system will subsequently confirm if the proper repair has been performed.

Since the mid-1990s, light-duty vehicles equipped with gasoline direct injection (GDI) engines have been added to the vehicle fleet in increasing numbers. Compared to conventional port fuel injection (PFI) engines, GDI engines provide higher power output for the same size engine, higher fuel efficiency, and lower carbon dioxide (CO₂) emissions. Due to the paucity of particulate matter (PM) emission data for light-duty gasoline vehicles in general and the increasing interest in these emissions relative to climate and air quality concerns, it is important to investigate PM emissions from current-generation GDI technologies. In this study, nine 2007-2010 light-duty GDI vehicles equipped with either wall-guided or spray-guided fuel injection systems were tested using California commercial gasoline fuel containing six percent ethanol by volume. Criteria pollutants including gaseous and PM emissions were measured over the Federal Test Procedure (FTP) transient test cycle.

Particulate matter (PM) emitted from light-duty gasoline powered vehicles is under increasing scrutiny due to potential adverse health effects and on ever increasing number of vehicles in the fleet. In this program, a group of California ULEV II and SULEV II certified light-duty gasoline vehicles were tested for PM mass and number emissions and compared with older model LEV I certified gasoline vehicles under the Federal Test Procedure (FTP) test cycle. PM mass and number emissions were collected from a Constant Volume Sampling (CVS) full dilution system. PM mass samples were collected with the gravimetric method. Filter conditioning and weighing procedures are in compliance with the Code of Federal Regulations (CFR) Part 1065. Total particles (solid and volatile) were measured using multiple fast response particle counting instruments including a TSI Engine Exhaust Particle Sizer (EEPS) and two Condensation Particle Counters (CPC).

The use of a partial flow sampling system (PFSS) to measure nonroad steady-state diesel engine particulate matter (PM) emissions is a technique for certification approved by a number of regulatory agencies around the world including the US EPA. Recently, there have been proposals to change future nonroad tests to include testing over a nonroad transient cycle. PFSS units that can quantify PM over the transient cycle have also been discussed. The full flow constant volume sampling (CVS) technique has been the standard method for collecting PM under transient engine operation. It is expensive and requires large facilities as compared to a typical PFSS. Despite the need for a cheaper alternative to the CVS, there has been a concern regarding how well the PM measured using a PFSS compared to that measured by the CVS. In this study, three PFSS units, including AVL SPC, Horiba MDLT, and Sierra BG-2 were investigated in parallel with a full flow CVS.

Heavy duty diesel vehicle (HDDV) emissions are known to affect air quality, but few studies have quantified the real-world contribution to the inventory. The objective of this study was to provide data that may enable ambient emissions investigators to m,odel the air quality more accurately. The 25 vehicles reported in this paper are from the first phase of a program to determine representative regulated emissions from Heavy Heavy-Duty Diesel Trucks (HHDDT) operating in Southern California. Emissions data were gathered using a chassis dynamometer, full flow dilution tunnel, and research grade analyzers. The subject program employed two truck test weights and four new test modes (one was idle operation), in addition to the Urban Dynamometer Driving Schedule (UDDS), and the AC50/80 cycle. The reason for such a broad test cycle scope was to determine thoroughly how HHDDT emissions are influenced by operating cycle to improve accuracy of models.