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A novel concept of combined hydrogen production and power generation system based on the combustion of aluminum in water is explored. The energy conversion system proposed is potentially able to provide four different energy sources, such us pressurized hydrogen, high temperature steam, heat, and work at the crankshaft on demand, as well as to fully comply with the environment sustainability requirements. Once aluminum oxide layer is removed, the pure aluminum can react with water producing alumina and hydrogen while releasing a significant amount of energy. Thus, the hydrogen can be stored for further use and the steam can be employed for energy generation or work production in a supplementary power system. The process is proved to be self-sustained and to provide a remarkable amount of energy available as work or hydrogen.

Water injection can be applied to spark ignited gasoline engines to increase the Knock Limit Spark Advance and improve the thermal efficiency. The Knock Limit Spark Advance potential of 6 °CA to 11 °CA is shown by many research groups for EN228 gasoline fuel using experimental and simulation methods. The influence of water is multi-layered since it reduces the in-cylinder temperature by vaporization and higher heat capacity of the fresh gas, it changes the chemical equilibrium in the end gas and increases the ignition delay and decreases the laminar flame speed. The aim of this work is to extend the analysis of water addition to different octane ratings. The simulation method used for the analysis consists of a detailed reaction scheme for gasoline fuels, the Quasi-Dimensional Stochastic Reactor Model and the Detonation Diagram. The detailed reaction scheme is used to create the dual fuel laminar flame speed and combustion chemistry look-up tables.

To act on global warming, CO2 emissions must be reduced. This will require a reduction in the use of fossil fuels for transportation. Because of the large quantities of fossil fuels used in transportation, sources of renewable fuels other than biomass will have to be explored, such as electrofuels synthesized from CO2 using renewable electricity. Potential electrofuels include methanol and ethanol, which have shown promising results in SI engines. However, their low cetane numbers make these fuels unsuitable for CI engines because of their poor auto-ignition qualities. The main objective of this study was to evaluate the viability of using methanol and ethanol in CI engines at compression ratios of 16.7 and 20 with a pilot-main injection strategy in the PPC/CI regime. Single cylinder engine tests on a heavy duty engine were performed under medium load conditions (1262 rpm and 172 Nm).

This paper depicts the main topics of the experimental investigation on alcohol engine development field, aiming at the engineering targets for the emission levels. The first part of this study was focused on engine design optimization for running on ethanol mixed with poly-ethylene glycol (PEG) as ignition improver. It was shown that some design changes in compression ratio, turbine casing, injector nozzle configuration and exhaust pressure governor (EPG) activation, lead to a better engine thermodynamics and its thermochemistry. The second objective of this study was the investigation of engine performance and emission levels, when the ignition improver diethyl ether (DEE) would be generated on board via catalytically dehydration of ethanol, and used directly as soluble mixture or separately fumigated.

To characterize the effects of renewable fuels on particulate emissions from GDI engines, engine experiments were conducted using EN228-compliant gasoline fuel blends containing no oxygenates, 10% ethanol (EtOH), or 22% ethyl tert-butyl ether (ETBE). The experiments were conducted in a single cylinder GDI engine using a 6-hole fuel injector operated at 200 bar injection pressure. Both PN in raw exhaust and solid PN (SPN) were measured at two load points and various start of injection (SOI) timings. Raw PN and SPN results were classified into various size ranges, corresponding to current and future legislations. At early SOI timings, where particulate formation is dominated by diffusion flames on the piston due to liquid film, the oxygenated blends yielded dramatically higher PN and SPN emissions than reference gasoline because of fuel effects.

The evaporation of different fuels and fuel components in hollow-cone sprays at conditions similar to those at stratified cold start has been investigated using a combination of planar laser-induced fluorescence (LIF) and Mie scattering. Ketones of different volatility were used as fluorescent tracers for different fuel components in gasoline-like model fuels and ethanol-based fuels. LIF and Mie images were compared to evaluate to what extent various fuel components had evaporated and obtained a spatial distribution different from that of the liquid drops, as a function of fuel temperature and time after start of injection. A selective and sequential evaporation of fuel components of different volatility was found.

Believed to have a potential in reducing the NOx emission level, hydrogen peroxide was fumigated into the inlet duct of the AVL single cylinder research engine via a standard gasoline injector, normally used in the Volvo 850-car engine. A small metallic sphere installed 3 cm downstream the injector tip, improved the spray formation and the uniform distribution of the fumigated peroxide fluid upstream the intake valve. The hydrogen peroxide flow was varied according to the desired value via an electronic pulse frequency generator. The engine, equipped with an electronic unit injector, was initially run without any fumigation fluid until the specifications of the engine test point were reached and remained very stable. Further, the hydrogen peroxide injection was activated with three different injection flows, and the engine performance, including emission levels, was compared to reference performance.

Laws concerning to emissions from heavy duty (HD) internal combustion engines are becoming increasingly stringent. New engine technologies are therefore needed to satisfy these new legal requirements and reduce fossil fuel dependency. One way to achieve both objectives is to partially replace fossil fuels with alternatives that are more sustainable with respect to emissions of greenhouse gas, particulates and NOx. As a first step towards the development of a direct injected dual fuel engine using diesel fuel and renewable alcohols such as methanol or ethanol, we have studied ethanol (E100) sprays generated with a standard high pressure diesel fuel injection system in a high pressure/temperature spray chamber with optical access. The experiments were performed at a gas density of ∼27kg/m3 at ∼550 °C and ∼60 bar, representing typical operating conditions for a HD engine at low loads.

This work utilizes previously developed VSB2 (VSB2 Stochastic Blob and Bubble) multicomponent fuel spray model to study significance of using non-ideal thermodynamics for droplet evaporation under direct injection engine like operating conditions. Non-ideal thermodynamics is used to account for vapor-liquid equilibrium arising from evaporation of multicomponent fuel droplets. In specific, the evaporation of ethanol/iso-octane blend is studied in this work. Two compositions of the blend are tested, E-10 and E-85 respectively (the number denotes percentage of ethanol in blend). The VSB2 spray model is implemented into OpenFoam CFD code which is used to study evaporation of the blend in constant volume combustion vessel. Liquid and vapor penetration lengths for the E-10 case are calculated and compared with the experiment. The simulation results show reasonable agreement with the experiment. Simulation is performed with two methods- ideal and non-ideal thermodynamics respectively.

The influence of ethanol content in gasoline on speciated emissions from a direct injection stratified charge (DISC) SI engine is assessed. The engine tested is a commercial DISC one that has a wall guided combustion system. The emissions were analyzed using both Fourier transform infrared (FTIR) spectroscopy and conventional emission measurement equipment. Seven fuels were compared in the study. The first range of fuels was of alkylate type, designed to have 0, 5, 10 and 15 % ethanol in gasoline without changing the evaporation curve. European emissions certification fuel was tested, with and without 5 % ethanol, and finally a specially blended high volatility gasoline was also tested. The measurements were conducted at part-load, where the combustion is in stratified mode. The engine used a series engine control unit (ECU) that regulated the fuel injection, ignition and exhaust gas recirculation (EGR).

Over the past few years, an open-source code called OpenFOAM has been becoming a promising CFD tool for multi-dimensional numerical simulations of internal combustion engines. The primary goal of the present study is to assess the feasibility of the code for computations of hollow-cone sprays discharged by an outward-opening pintle-type injector by simulating the experiments performed recently by Hemdal et al., (SAE 2009-01-1496) with gasoline and ethanol sprays under the following conditions: air temperature Tair = 295 or 350 K, air pressure pair = 6 bar, fuel temperature Tfuel = 243, or 295, or 320 K, and fuel injection pressure pinj = 50, or 125, or 200 bar. To simulate the experiments, a pintle injector model and the physical properties of gasoline were implemented in OpenFOAM. The flow field calculated using the pintle injector model is more realistic than that yielded by the default unit injector model normally used in OpenFOAM.

Sulphur poisoning and regeneration of NOx trap catalysts have been studied in synthetic exhausts and in an engine bench. Sulphur gradually poisoned the NOx storage sites in the axial direction of the NOx trap. During sulphur regenerations, hydrogen was found to be more efficient than carbon monoxide in removing the sulphur from the trap. The sulphur regeneration became more efficient the richer the environment (λ<1) and the higher the temperature (at least 600°C). H2S was found to be the main product during the sulphur regeneration. However, it was possible to reduce the H2S formation and instead produce more SO2 by running with lambda close to one or by pulsing lambda. Even if a relatively large amount of sulphur was removed from the NOx trap, these methods gave a much less efficient regeneration per sulphur atom removed than when running relatively rich constantly. Finally, a model that could explain this observation was proposed.

Environmental and economic issues related to the aeronautic transport, with particular reference to the high-speed one are opening new perspectives to pulsejets and derived pulse detonation engines. Their importance relates to high thrust to weight ratio and low cost of manufacturing with very low energy efficiency. This papers presents a preliminary evaluation in the direction of a new family of pulsejets which can be coupled with both an air compression system which is currently in pre-patenting study and a more efficient and enduring valve systems with respect to today ones. This new pulsejet has bee specifically studied to reach three objectives: a better thermodynamic efficiency, a substantial reduction of vibrations by a multi-chamber cooled architecture, a much longer operative life by more affordable valves. Another objective of this research connects directly to the possibility of feeding the pulsejet with hydrogen.

The ignition delay of ethanol with different nitrate and polyethylene glycol based ignition improvers was investigated in a single-cylinder DI Diesel engine. The nitrate-based improvers provided a shorter ignition delay than the polyethylene glycol improvers, but the results indicate that the efficiency of the polyethylene glycol improvers increases with the length of the molecular chains. Comparison with reference fuels gives a cetane number of approximately 44 for ethanol with 4% of the best nitrate-based improver versus 40 for ethanol with 7% polyethylene glycol improver. It is shown, that the random ignition delay for all the fuels has a normal distribution, and that the reference fuel of every measurement series has a constant expected ignition delay. Ignition delay measurements in a constant-volume combustion vessel failed to produce the same trends as in the engine for the ethanol fuels.