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The Three Way Catalyst (TWC) is an effective pollutant conversion system widely used in current production vehicles to satisfy emissions regulations. A TWC’s conversion efficiency degrades over time due to chemical and/or thermal mechanisms causing the catalyst to age. This reduction in conversion efficiency must be accounted for to ensure full useful life emissions compliance. This paper presents an experimental study of the aging impact on TWC performance. Four TWCs differentiated by their age, given in terms of miles driven, were tested. It is shown that the dynamics of oxygen storage are substantially affected by aging of the TWC. A previously developed physics-based oxygen storage model [1] is subsequently used to incorporate the effect of aging on the total Oxygen Storage Capacity (OSC). Parameter identification results for the different age catalysts show that total oxygen storage capacity decreases substantially with aging and is insensitive to operating conditions.

The duration over which a three way catalyst (TWC) maintains proper functionality during lambda excursions is critically impacted by aging, which affects its oxygen storage capacity (OSC). As such, emissions control strategies, which strive to maintain post TWC air-to-fuel ratios at the stoichiometric value, will benefit from an accurate estimation of TWC age. To this end, this investigation examines a method of TWC age estimation suitable for real-world transient operation. Experimental results are harvested from an instrumented test vehicle equipped with a two-brick TWC during operation on a chassis dynamometer. Four differently aged TWCs are instrumented with wideband and switch-type Lambda sensors upstream (Pre TWC location), and downstream (Mid location) of first catalyst brick.