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This paper presents a comparison of aqueous corrosion rates in 5% NaCl solution for eight experimental creep-resistant magnesium alloys considered for automotive powertrain applications, as well as three reference alloys (pure magnesium, AM50B and AZ91D). The corrosion rates were measured using the techniques of titration, weight loss, hydrogen evolution, and DC polarization. The corrosion rates measured by these techniques are compared with each other as well as with those obtained with salt-spray testing using ASTM B117. The advantages and disadvantages of the various corrosion measurement techniques are discussed.

Corrosion-fatigue (CF) and stress corrosion cracking (SCC) have long been recognized as the major degradation and failure mechanisms of engineering materials under combined mechanical loading and corrosive environments. How to model and characterize these failure phenomena and how to screen, rank, and select materials in corrosion-fatigue and stress corrosion cracking resistance is a significant challenge in the automotive industry and many engineering applications. In this paper, the mathematical structure of a superposition-theory based corrosion-fatigue model is investigated and possible closed-form and approximate solutions are sought. Based on the model and the associated solutions and test results, screening and ranking of the materials in fatigue, corrosion-fatigue are discussed.

This study reports the performance of three different automotive magnesium substrate materials (AM60B diecastings, AZ31-H24 sheet, and AM30 extrusions), each bonded to a common aluminum reference material with two different toughened adhesives. The magnesium substrates were pretreated with six different commercial pretreatments both with and without a final fused-powder polymeric topcoat. These samples were then evaluated by comparing initial lap-shear strength to the lap-shear strength after cyclic-corrosion testing. Additionally, use of a scribe through the polymer primer permitted assessment of: 1) distance of corrosion undercutting from the scribe (filiform), and 2) percent corrosion over the area of the coupon. The results showed that the performance of each magnesium pretreatment varied on cast AM60B, sheet AZ31-H24, and extruded AM30 substrates.

This paper investigates the interfacial fracture properties of composite-metal laminates by using the single-cantilever beam testing technique. The hybrid systems consisted of a layer of aluminum alloy (6061 or 2024-T3) bonded to polypropylene based composites. In this study, two non-chromate surface treatments were applied to the aluminum substrates: SafeGard CC-300 Chrome free seal (from Sanchem Inc.) and TCP-HF (from Metalast International Inc.). These are environmentally friendly surface treatments that enhance the adhesion and corrosion resistance of aluminum alloys. Flat hybrid panels were manufactured using a one step cold press manufacturing procedure. Single cantilever bend specimens were cut from the panels and tested at 1mm/min. Results have shown that the CC-300 treated Al 2024-T3 alloy and Twintex exhibited higher interfacial fracture energy values.