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Technical Paper

A Mathematical Model for the Vapour Composition and Flammability of Gasoline - Diesel Mixtures in a Fuel Tank

2017-10-08
2017-01-2407
Low Temperature Combustion using compression ignition may provide high efficiency combined with low emissions of oxides of nitrogen and soot. This process is facilitated by fuels with lower cetane number than standard diesel fuel. Mixtures of gasoline and diesel (“dieseline”) may be one way of achieving this, but a practical concern is the flammability of the headspace vapours in the vehicle fuel tank. Gasoline is much more volatile than diesel so, at most ambient temperatures, the headspace vapours in the tank are too rich to burn. A gasoline/diesel mixture in a fuel tank therefore can result in a flammable headspace, particularly at cold ambient temperatures. A mathematical model is presented that predicts the flammability of the headspace vapours in a tank containing mixtures of gasoline and diesel fuel. Fourteen hydrocarbons and ethanol represent the volatile components. Heavier components are treated as non-volatile diluents in the liquid phase.
Technical Paper

A Parametric Study of the Flammability of Dieseline Blends with and without Ethanol

2019-01-15
2019-01-0020
Low Temperature Combustion using compression ignition may provide high efficiency combined with low emissions of oxides of nitrogen and soot. This process is facilitated by fuels with lower cetane number than standard diesel fuel. Mixtures of gasoline and diesel (“dieseline”) may be one way of achieving this; however, a gasoline/diesel mixture in a fuel tank can result in a flammable headspace, particularly at very cold ambient temperatures. A mathematical model to predict the flammability of dieseline blends, including those containing ethanol, was previously validated. In this paper, that model is used to study the flammability of dieseline blends parametrically. Gasolines used in the simulations had Dry Vapour Pressure Equivalent (DVPE) values of 45, 60, 75, 90 and 110 kPa.
Technical Paper

Effect of Diesel Properties on Emissions and Fuel Consumption from Euro 4, 5 and 6 European Passenger Cars

2016-10-17
2016-01-2246
Certain diesel fuel specification properties are considered to be environmental parameters according to the European Fuels Quality Directive (FQD, 2009/EC/30) and previous regulations. These limits included in the EN 590 specification were derived from the European Programme on Emissions, Fuels and Engine Technologies (EPEFE) which was carried out in the 1990’s on diesel vehicles meeting Euro 2 emissions standards. These limits could potentially constrain FAME blending levels higher than 7% v/v. In addition, no significant work has been conducted since to investigate whether relaxing these limits would give rise to performance or emissions debits or fuel consumption benefits in more modern vehicles. The objective of this test programme was to evaluate the impact of specific diesel properties on emissions and fuel consumption in Euro 4, Euro 5 and Euro 6 light-duty diesel vehicle technologies.
Technical Paper

Effect of Octane on the Performance of Two Gasoline Direct Injection Passenger Cars

2015-04-14
2015-01-0767
The performance aspect of gasoline combustion has traditionally been measured using Research Octane Number (RON) and Motor Octane Number (MON) which describe antiknock performance under different conditions. Recent literature suggests that MON is less important than RON in modern cars and a relaxation in the MON specification could improve vehicle performance, while also helping refiners in the production of gasoline. At the same time, for the same octane number change, increasing RON appears to provide more benefit to engine power and acceleration than reducing MON. It has also been suggested that there could be fuel efficiency benefits (on a tank to wheels basis) for specially adapted engines, for example, operating at higher compression ratio, on very high RON (100+). Other workers have advocated the use of an octane index (OI) which incorporates both RON and MON to give an indication of octane quality.
Technical Paper

Explicit Equations to Estimate the Flammability of Blends of Diesel Fuel, Gasoline and Ethanol

2020-09-15
2020-01-2129
Blends of gasoline, diesel fuel and ethanol (“dieseline”) have shown promise in engine studies examining low temperature combustion using compression ignition. They offer the possibility of high efficiency combined with low emissions of oxides of nitrogen and soot. However, unlike gasoline or diesel fuel alone, such mixtures can be flammable in the headspace above the liquid in a vehicle fuel tank at common ambient temperatures. Quantifying their flammability characteristics is important if these fuels are to see commercial service. The parameter of most interest is the Upper Flammable Limit (UFL) temperature, below which the headspace vapour is flammable. In earlier work a mathematical model to predict the flammability of dieseline blends, including those containing ethanol, was developed and validated experimentally. It was then used to study the flammability of a wide variety of dieseline blends parametrically.
Journal Article

Fuel Effects on Regulated and Unregulated Emissions from Three Light-Duty Euro 5 and Euro 6 Diesel Passenger Cars

2020-09-15
2020-01-2147
Substantial advances in European road vehicle emissions have been achieved over the past 3 decades driven by strengthening revisions in emissions legislation and enabled by advances in fuel, vehicle engine and emissions control technologies. As both vehicle technology and emissions legislation in Europe continue to evolve, Concawe has conducted a study to examine the opportunities that fuels can provide to further reduce emissions from light-duty diesel passenger cars. Three European diesel cars spanning Euro 5, Euro 6b and Euro 6d-TEMP emissions certification levels have been tested over the cold-start WLTC (Worldwide harmonized Light-duty Test Cycle) with 6 fuels: an EN590-compliant B5 (petroleum diesel containing 5% biodiesel by volume), a bio-derived paraffinic diesel, a 50:50 blend of the aforementioned fuels, a low density petroleum-derived B5, a B30 and the same B30 additized with a high dose of cetane number improver.
Journal Article

Impact of Biodiesel Blends on Fuel Consumption and Emissions in Euro 4 Compliant Vehicles

2010-05-05
2010-01-1484
Fatty Acid Methyl Ester (FAME) products derived from vegetable oils and animal fats are now widely used in European diesel fuels and their use will increase in order to meet mandated targets for the use of renewable products in road fuels. As more FAME enters the diesel pool, understanding the impact of higher FAME levels on the performance and emissions of modern light-duty diesel vehicles is increasingly important. Of special significance to Well-to-Wheels (WTW) calculations is the potential impact that higher FAME levels may have on the vehicle's volumetric fuel consumption. The primary objective of this study was to generate statistically robust fuel consumption data on three light-duty diesel vehicles complying with Euro 4 emissions regulations. These vehicles were evaluated on a chassis dynamometer using four fuels: a hydrocarbon-only diesel fuel and three FAME/diesel fuel blends containing up to 50% v/v FAME. One FAME type, a Rapeseed Methyl Ester (RME), was used throughout.
Journal Article

Impact of FAME Content on the Regeneration Frequency of Diesel Particulate Filters (DPFs)

2014-04-01
2014-01-1605
Modern diesel vehicles utilize two technologies, one fuel based and one hardware based, that have been motivated by recent European legislation: diesel fuel blends containing Fatty Acid Methyl Esters (FAME) and Diesel Particulate Filters (DPF). Oxygenates, like FAME, are known to reduce PM formation in the combustion chamber and reduce the amount of soot that must be filtered from the engine exhaust by the DPF. This effect is also expected to lengthen the time between DPF regenerations and reduce the fuel consumption penalty that is associated with soot loading and regeneration. This study investigated the effect of FAME content, up to 50% v/v (B50), in diesel fuel on the DPF regeneration frequency by repeatedly running a Euro 5 multi-cylinder bench engine over the European regulatory cycle (NEDC) until a specified soot loading limit had been reached.
Technical Paper

Impact of Fuel Properties on Advanced Combustion Performance in a Diesel Bench Engine and Demonstrator Vehicle

2010-04-12
2010-01-0334
Six diesel, kerosene, gasoline-like, and naphtha fuels have been tested in a single cylinder diesel engine and a demonstrator vehicle, both equipped with similar engine technology and optimized for advanced combustion performance. This study was completed in order to investigate the potential to reduce engine-out emissions while maintaining engine efficiency and noise levels through changes in both engine hardware and fuel properties. The fuels investigated in this study were selected in order to better understand the effects of ignition quality, volatility, and molecular composition on engine-out emissions and performance. The optimized bench engine used in this study included engine hardware enhancements that are likely to be used to meet Euro 6 emissions limits and beyond, in part by operating under advanced combustion conditions, at least under some speed and load conditions.
Technical Paper

Modelling a Gasoline Compression Ignition (GCI) Engine Concept

2014-04-01
2014-01-1305
Future engines and vehicles will be required to reduce both regulated and CO2 emissions. To achieve this performance, they will be configured with advanced hardware and engine control technology that will enable their operation on a broader range of fuel properties than today. Previous work has shown that an advanced compression ignition bench engine can operate successfully on a European market gasoline over a range of speed/load conditions while achieving diesel-like engine efficiency and acceptable regulated emissions and noise levels. Stable Gasoline CI (GCI) combustion using a European market gasoline was achieved at high to medium engine loads but combustion at lower loads was very sensitive to EGR rates, leading to longer ignition delays and a steep cylinder pressure rise.
Journal Article

Vapour Space Flammability Considerations for Gasoline Compression Ignition Vehicles Operating on “Dieseline” Blends.

2016-10-17
2016-01-2266
Gasoline Compression Ignition (GCI) has been identified as a technology which could give both high efficiency and relatively low engine-out emissions. The introduction of any new vehicle technology requires widespread availability of appropriate fuels. It would be ideal therefore if GCI vehicles were able to operate using the standard grade of gasoline that is available at the pump. However, in spite of recent progress, operation at idle and low loads still remains a formidable challenge, given the relatively low autoignition reactivity of conventional gasoline at these conditions. One conceivable solution would be to use both diesel and gasoline, either in separate tanks or blended as a single fuel (“dieseline”). However, with this latter option, a major concern for dieseline would be whether a flammable mixture could exist in the vapour space in the fuel tank.
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