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Cordierite-based diesel particulate filters (DPFs) have been in use for heavy duty engine applications for nearly two decades. Recently, passenger car applications for DPFs have begun to appear in Europe due to tightening legislation. While cordierite-based DPFs work well in most applications, it appears that in the passenger car exhaust environment under some uncontrolled regeneration conditions, cracking and melting of the existing cordierite-based DPF products have been reported. The present paper focuses on the development of new, high temperature oxide ceramics for DPF passenger car applications. When designed properly, DPFs made from these new materials do not show cracking or melting under uncontrolled regeneration. The material properties (strength, elastic modulus, coefficient of thermal expansion, etc.) and the filter performance properties (pressure drop, regeneration durability, etc.) have been characterized for DPFs made from these new materials.

Diesel particle filters (DPF) have become a standard aftertreatment component for all current and future on-road diesel engines used in the US. In Europe the introduction of EUVI is expected to also result in the broad implementation of DPF's. The anticipated general trend in engine technology towards higher engine-out NOx/PM ratios results in a somewhat changing set of boundary conditions for the DPF predominantly enabling passive regeneration of the DPF. This enables the design of a novel filter concept optimized for low pressure drop, low thermal mass for optimized regeneration and fast heat-up of a downstream SCR system, therefore reducing CO₂ implications for the DPF operation. In this paper we will discuss results from a next-generation cordierite DPF designed to address these future needs.

India BS6 Stage2 (2023) regulations demand all gasoline direct injection (GDI) vehicles to meet particulate number emissions (PN) below 6x10+11# per km. Gasoline particulate filters (GPF) are a proven technology and enable high PN filtration efficiencies throughout the entire vehicle lifetime. One challenge for GPF applications could be the changing emission performance characteristics as a function of mileage due to collected ash and/or soot deposits with implications on back pressure losses. The main objective of this technical contribution is to study the above-mentioned challenges while applying Indian driving conditions and typical Indian climate and other ambient conditions. The substrate technology selected for this study is a high porosity GPF designed to enable the integration of a three-way functionality into the GPF, commonly described as catalyzed GPF (cGPF).

Governing bodies world-wide are setting increasingly tighter emission standards to help improve air quality. US and Californian LEV/ULEV standards are pace setting, European Stage II legislation has just become effective. In Brazil, the upcoming 1997 standards are also demanding for tighter emission control. The monolithic ceramic honeycomb catalytic converter -for more than the past 20 years- has been a reliable key element in the automotive emission control systems. In order to help meet tightened emission regulation as well to satisfy even more stringent durability requirement, an advanced thinwall ceramic Celcor XT has been developed for increased geometric surface area and reduced backpressure. The product properties as well as FTP and ECE emission and durability test results are being described in this paper. Converter system durability is also determined by robust canning and mounting systems. A durable mounting concept, especially for preconverters, is being described.

Gasoline particulate filters (GPF) recently entered the market, and are already regarded a state-of-the-art solution for gasoline exhaust aftertreatment systems to enable EU6d-TEMP fulfilment and beyond. Especially for coated GPF applications, the prognosis of the emission conversion performance over lifetime poses an ambitious challenge, which significantly influences future catalyst diagnosis calibrations. The paper presents key-findings for the different GPF application variants. In the first part, experimental GPF ash loading results are presented. Ash accumulates as thin wall layers and short plugs, but does not penetrate into the wall. However, it suppresses deep bed filtration of soot, initially decreasing the soot-loaded backpressure. For the emission calibration, the non-linear backpressure development complicates the soot load monitoring, eventually leading to compromises between high safety against soot overloading and a low number of active regenerations.

Accelerated ash loading studies provide a cost-effective means of investigating the long-term impacts of ash accumulation in diesel particulate filters (DPFs). Despite a variety of methods adopted in previous studies for accelerated ash loading, evaluation of their impact on DPF behavior has been limited primarily to pressure drop response (with & without soot), and characterization of properties of the resulting ash deposits for comparison with samples from field testing. In the current study, the potential to use ash recovered from field DPFs to perform accelerated ash loading studies is explored. Additionally, anhydrous gypsum as a surrogate for diesel ash was investigated. Benefits of using gypsum include low cost and easy access, safety during handling and testing, and consistency from test to test. Narrow control of particle sizing and composition can help compare performance over a wide range of filter sizes and applications.

The automotive industry continues to develop technologies for reducing vehicle fuel consumption. Specifically, vehicle lightweighting is expected to be a key enabler for achieving fleet CO2 reduction targets for 2025 and beyond. Hybrid glass laminates that incorporate fusion draw and ion exchange innovations are thinner and thereby, offer more than 30% weight reduction compared to conventional automotive laminates. These lightweight hybrid laminates provide additional benefits, including improved toughness and superior optics. However, glazing weight reduction leads to an increase in transmission of sound through the laminates for certain frequencies. This paper documents a study that uses a systematic test-based approach to understand the sensitivity of interior vehicle noise behavior to changes in acoustic attenuation driven by installation of lightweight glass.

To aid in the catalytic converter design and development process, a test apparatus was designed and built which will allow comparative evaluation of the durability of candidate mat materials under highly controlled thermal and vibration environments. The apparatus directly controls relative shear deflection between the substrate and can to impose known levels of mat material strain while recording the transmitted shear force across the mat material. Substrate and can temperatures are controlled at constant levels using a resistive thermal exposure (RTE) technique. Mat material fatigue after several million cycles is evident by a substantial decrease in the transmitted force. A fragility test was found to be an excellent method to quickly compare candidate materials to be used for a specific application. Examples of test results from several materials are given to show the utility of the mat material evaluation technique.

As the official proposal for emission regulation Euro 7 has been released by European Commission, PN above 10nm is taken into consideration for the ultrafine particulate emissions control. The challenges of GPF filtration efficiency emerge for the light-duty manufactures to meet the future emission standards. In the present study, a China 6 compliant vehicle was tested to reveal its performance over the China 6 standards and potential to meet the upcoming Euro 7. Three GPF product types (Gen 1, Gen 2, and concept Gen 3) were mounted to the tested vehicle. WLTC tests were conducted on chassis dynamometer in laboratory as well as a self-designed aggressive cycle (“Base Cycle”) tests. To explore the GPFs performance for PN emissions above 10nm against the proposed limit 6.0E11 #/km, PN emission above 10nm were measured in our laboratory tests for both engine out and tailpipe as well as the PN emission above 23nm.

Examination of field-fractured windshields was conducted for purposes of determining the principle fracture mechanisms experienced in-use. Samples for the study were gathered both in the United States (New York) and in Europe (France) to explore whether the primary causes of failure were similar for the different geographic regions. In total, over two hundred individual field-fractures were obtained and examined for the study. Detailed fracture analysis of the parts was performed, and multiple fracture mechanisms were identified and quantified. It was found that the two most frequently observed failure modes were common for both regions with the most frequent cause (~70%) of fractures being due to sharp contact of the exterior ply, while Hertzian cone cracking of the outer ply was the second leading cause (~20%). Several other modes were also identified. Given that sharp impact fracture was the dominant observed failure mode, a high-speed, sharp impact test method was developed.

Significant particulate emission reductions of diesel engines can be achieved using diesel particulate filters (DPFs). Ceramic wall flow filters with a PM efficiency of >90% have proven to be effective components in emission control. The challenge for the application lies with the development and adaptation of a reliable regeneration strategy. The main focus is emission efficiency over the legally required durability periods, as well as over the useful vehicle life. It will be shown, that new DPF systems are characterized by a high degree of integration with the engine management system, to allow for initiation of the regeneration and its control for optimum DPF protection. Using selected cases, the optimum combination and tuning will be demonstrated for successful regenerations, taking into account DPF properties.

Catalytic converter substrates for automobile emission control have to operate under the hostile conditions of the automotive exhaust. This paper will first discuss the mechanical and physical properties to ensure durable mechanical function of the catalytic substrate and converter system. High temperature mechanical and thermal shock substrate requirements and properties will be discussed. The functionality of a catalytic converter is significantly influenced by the catalytic coating. At the same time, substrate characteristics as will be shown, also effect converter functional parameters like back pressure, light-off and conversion efficiency. The importance of the substrate parameters cell shape, cell density and substrate mass and their effect on thermohydraulic parameters like heat- and mass transfer factors for various cell structures and substrates will be presented.

This paper details the development of the EX-80 composition, a new cordierite material for use as a diesel particulate filter (DPF), that was developed based on the following objectives; (1) improved thermal durability, (2) high filtration efficiency and (3) low pressure drop. The achievement of these goals was demonstrated through engine testing, stress modeling, and other evaluations. EX-80 has a low coefficient of thermal expansion (CTE) averaging less than 4x10-7°C-1 (25°C-800°C), the Modulus of Rupture (MOR) averages greater than 350 psi and the Modulus of Elasticity (MOE) averages less than 0.8 x 106 psi. The improvement of these three properties has resulted in improved thermal durability for EX-80 as compared to the current Corning DPF compositions (EX-47, EX-54 and EX-66). The new cordierite composition has been designed to achieve a low pressure drop as a function of soot loading (0.30 inHg/gm of soot collected), coupled with high efficiency, averaging greater than 90%.

The key diesel emission control papers of the last 12 months have been summarized. In addition, the emerging US and European light-duty and heavy-duty tailpipe regulations are compared. Results are reported on light-duty diesel filtration regeneration systems and experiences, including effects of ash build-up and some recent modeling work. On the heavy-duty side, optimization of SCR catalysts and systems are described, as well as experiences with the first integrated SCR/filter systems, which are already achieving “Euro V” 2008 standards. An update on NOx adsorbers is also provided. The results with new NOx formulations are described, as well as the system performance in a light-duty diesel application.

This paper gives a comprehensive overview of the current state-of-the-art in diesel emission control. The nature of diesel particulates is summarized. The variety of diesel particulate filter regeneration strategies that will become so important to filter application are reviewed. Filter retrofit and durability issues are addressed. DeNOx catalysts, SCR, NOx traps for diesel, and non-thermal plasma methods are summarized. Integrated NOx/PM systems are described. And reduction of exhaust toxics is discussed. The paper covers all major conferences in the year 2000 that occurred in the US and Europe. US and Europe.

This review summarizes the latest developments in diesel emissions regarding regulations, engines, NOx (nitrogen oxides) control, particulate matter (PM) reductions, and hydrocarbon (HC) and CO oxidation. Regulations are advancing with proposals for 70% tightening of fleet average light-duty (LD) criteria emissions likely to be proposed in California for ~2016-22. CO₂ regulations in both the heavy- and light-duty sectors will also tighten and impact diesel engines and emissions, probably long into the future. Engine technology is addressing these needs. Light-duty diesel engines are making incremental gains with combustion enhancements that allow downsizing for CO₂ savings. Heavy-duty (HD) engine show trade-offs between hardware recipes, exhaust deNOx control, and fuel consumption.

Honeycomb based diesel particulate filters have proven to be extremely effective in the removal of diesel soot. Under certain conditions, involving heavy soot loads and a shift of the engine into the idle mode during the early stages of the regeneration process, the current designs of cordierite filters have shown some tendency toward partial melting. A brief review of the SAE literature is presented, indicating that the temperatures reached during regeneration decrease substantially as the bulk heat capacity of the filter increases. Analysis of these literature data indicates that the top temperatures experienced during regeneration can be decreased by hundreds of degrees, by relatively modest increases in the bulk heat capacity of the bodies. New data are presented confirming how the top temperature varies with different filter designs in which the bulk heat capacity varies.

Until recently, the complexity of the Diesel Particulate Filter (DPF) system has hindered its commercial success. Stringent regulations of diesel emissions has lead to advancements in this technology, therefore mainstreaming the use of DPFs in light- and heavy-duty diesel filtration applications. This book covers the latest and most important research in DPF systems, focusing mainly on the advancements of the years 2002-2006. Editor Timothy V. Johnson selected the top 29 SAE papers covering the most significant research in this technology.

Upcoming EU5 and expected emissions legislation BS5 in India in combination with efforts to optimize the overall fuel economy has created new challenges in the development of aftertreatment systems for passenger cars equipped with diesel engines. Since EU5 and BS5 emissions legislation will strongly be focused on the reduction of particulate matter it is likely that all vehicle applications will need aftertreatment systems with diesel particulate filters. High filtration efficiency combined with a high resistance to thermo-mechanical stress is a strong requirement for diesel particulate filters to meet EU5 and BS5 emission legislation. Besides those requirements the backpressure of particulate filters has to be considered since backpressure is also related to fuel economy and therefore CO₂ emissions.

Extruded metal honeycombs are used as electrically heated catalysts (EHCs). The durability requirements of this application make demands on high surface area, thin cross-section metal honeycombs. Significant durability improvements over previous extruded metal honeycomb EHCs have been achieved by material and package design changes. The product redesign was supported by finite element models and extensive testing. The redesigned EHC has passed severe laboratory and field testing. The tests include electrical cycling to 1000°C/1600 cycles, hot vibration to 60g/900°C and demanding on-vehicle exposure. Excellent durability of the extruded metal honeycomb has been demonstrated.