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A 2001 General Motors 4.3 liter V-6 marine engine was baseline emissions tested and then equipped with catalysts. Emission reduction effects of exhaust gas recirculation (EGR) were also explored. Because of a U.S. Coast Guard requirement that inboard engine surface temperatures be kept below 200°F, the engine's exhaust system, including the catalysts, was water-cooled. Engine emissions were measured using the ISO-8178-E4 5-mode steady-state test for recreational marine engines. In baseline configuration, the engine produced 16.6 g HC+NOx/kW-hr, and 111 g CO/kW-hr. In closed-loop control with catalysts, HC+NOx emissions were reduced by 75 percent to 4.1 g/kW-hr, and CO emissions were reduced by 36 percent to 70 g/kW-hr of CO. The catalyzed engine was then installed in a Sea Ray 190 boat, and tested for water reversion on both fresh and salt water using National Marine Manufacturers Association procedures.

This paper describes a method used to compare the emissions from transient operation of an engine with the emissions from steady state operating modes of the engine. Weightings were assigned to each mode based on the transient cycle under evaluation. The method of assigning the weightings for each mode took into account several factors, including the distance between each second of the transient cycle's speed-and-torque point requests (in a speed vs. torque coordinate system) and the given mode. Two transient cycles were chosen. The transient cycles were taken from actual in-use data collected on nonroad engines during in-field operation. The steady state modes selected were based on both International Standard Organization (ISO) test modes, as well as, augmentation based on contour plots of the emissions from nonroad diesel engines. Twenty-four (24) steady-state modes were used. The transient cycle's speed-and-torque points are used to weight each steady state mode in the method.

A simple, inexpensive, critical flow blender has been developed for filling a tedlar bag with controllable concentrations of HC, NOx, CO2, and CO gases at levels encountered in automobile emissions testing. According to a daily schedule, a technician takes the bag to all analyzer sites in the laboratory for analysis. The concentrations indicated by each site are compared to the overall averages. The results are stored in a computerized data base from which control charts, statistical analyses, and interpretations of significant differences among test sites can be made. The precision, accuracy, and statistical interpretations of the data are discussed.

We have developed a methodology for predicting combustion and emissions in a Homogeneous Charge Compression Ignition (HCCI) Engine. This methodology combines a detailed fluid mechanics code with a detailed chemical kinetics code. Instead of directly linking the two codes, which would require an extremely long computational time, the methodology consists of first running the fluid mechanics code to obtain temperature profiles as a function of time. These temperature profiles are then used as input to a multi-zone chemical kinetics code. The advantage of this procedure is that a small number of zones (10) is enough to obtain accurate results. This procedure achieves the benefits of linking the fluid mechanics and the chemical kinetics codes with a great reduction in the computational effort, to a level that can be handled with current computers.

Studies of emissions from vehicles equipped with catalysts have shown that some unregulated emissions can increase when a catalyst is used. One example of this is sulfuric acid, which has been studied extensively. Other unregulated emissions include ammonia and hydrogen cyanide. In a number of studies, these unregulated pollutant emissions have been measured from light-duty vehicles and heavy-duty engines. These emission levels were used in air quality dispersion models to predict the resultant air quality levels. The ambient concentrations predicted for each pollutant were then compared to suggested concentrations at which adverse health effects may be found to determine if additional monitoring or control would be indicated for these pollutants. It was determined that mobile source emissions of sulfuric acid, hydrogen cyanide, and ammonia do not in general result in ambient levels of concern for the air quality situations studied.

A correlation between reflectance type smoke measurements and dry particulate concentrations in diesel exhaust is derived from first principles. The model has one free parameter; the mass-average diameter of the exhaust particulates. Data from the literature indicates that particulate diameters can vary depending upon the injection hardware, fuel properties, and combustion chamber design. Older engines typically have larger average particulate radii and run at higher smoke numbers. Using a simple linear relationship between smoke number and mass-averaged particulate diameter, a good match is obtained between the derived model and experimental data. As a further validation of the model, a technique is derived by which any correlation between smoke and particulate concentration can be validated with only a smoke meter, provided it has multiple draw capabilities. Using this novel technique, the correlation derived here is shown to be functionally correct.

In 2015 the U.S. Environmental Protection Agency (EPA) and the U.S. Department of Transportation's National Highway Traffic Safety Administration (NHTSA) proposed a new steady-state engine dynamometer test procedure by which heavy-duty engine manufacturers would be required to create engine fuel rate versus engine speed and torque “maps”.[1] These maps would then be used within the agencies' Greenhouse Gas Emission Model (GEM)[2] for full vehicle certification to the agencies' proposed heavy-duty fuel efficiency and greenhouse gas (GHG) emissions standards. This paper presents an alternative to the agencies' proposal, where an engine is tested over the same duty cycles simulated in GEM. This paper explains how a range of vehicle configurations could be specified for GEM to generate engine duty cycles that would then be used for engine testing.

A modified constant volume sampling (CVS) system has been used to sample fugitive hydrocarbon (HC) emissions to determine whether such systems can help identify excess vehicular HC sources, such as leaking gas caps. The approach was successful in distinguishing tightly sealed, marginally leaking and grossly leaking caps. The technique may be useful in motor vehicle inspection and maintenance (I/M) facilities as a less intrusive alternative to techniques requiring pressurization of the fuel system.

Emissions from manual transmission motorcycles have been shown to be dependent upon transmission shift patterns. Presently, when undergoing an emission test for an Environmental Protection Agency (EPA) certification a manufacturer can designate their own shift points during the cycle or utilize an EPA prescribed shift pattern which uses basic up or down shifts at specific speeds regardless of the type of motorcycle, 40 CFR 86.528-78(h). In order to predict the real-life emissions from motorcycles, a comparative real-life shift pattern has been developed which can then be used to evaluate the suitability of the manufacturer’s shift schedule. To that end, a model that predicts shift points for motorcycles has been created. This model is based on the actual operation of different motorcycles by real life operators in a combined city and highway setting.

Due to continuing reductions in EPA's emission standard values for exhaust particulate emissions, industry production has shifted towards engines that produce very low amounts of particulate emissions. Thus, it is very possible that future engines will challenge the error range of the current instrumentation and procedures used to measure particulate emissions by being designed to produce extremely low levels of particulates. When low particulate emitting engines are sampled at low flowrates, the resulting filter loadings may violate the minimum filter loading recommendation in the Heavy Duty Federal Test Procedure [1]. Conversely, higher flow rates may be an inappropriate option for increasing filter loading due to the possibility of stripping volatile organic compounds from the particulate sample or otherwise artificially reducing the accumulated mass [2].

The advent of emission control technology has resulted in significant changes in both the total mass and detailed patterns of hydrocarbons emitted from automobiles. Emission rates of 56 hydrocarbons from 22 motor vehicles, including catalyst and noncatalyst configurations, were determined for the Federal Urban Driving Cycle. An increased relative abundance of methane is indicated for vehicles equipped with oxidation catalysts. In view of the photochemically non-reactive nature of methane, simple and economic procedures for determination of vehicle nonmethane hydrocarbon emission rates are evaluated. In general the procedures evaluated require independent total hydrocarbon and methane analysis, with the nonmethane hydrocarbon level calculated by difference. The procedures are evaluated by comparison of indicated nonmethane hydrocarbon emission rates with rates obtained by summation of individual compound rates determined by advanced gas chromatographic procedures.

As part of the U.S. Environmental Protection Agency’s (EPA’s) continuing assessment of advanced light-duty (LD) automotive technologies to support the setting of appropriate national greenhouse gas (GHG) standards and to evaluate the impact of new technologies on in-use emissions, a 2016 Honda Civic with a 4-cylinder 1.5-liter L15B7 turbocharged engine and continuously variable transmission (CVT) was benchmarked. The test method involved installing the engine and its CVT in an engine-dynamometer test cell with the engine wiring harness tethered to its vehicle parked outside the test cell. Engine and transmission torque, fuel flow, key engine temperatures and pressures, and onboard diagnostics (OBD)/Controller Area Network (CAN) bus data were recorded.

A second carbonyl round robin was conducted to enable participating laboratories doing routine analysis of carbonyls in vehicle exhaust emissions to assess their analytical capabilities. Three sets of solutions in acetonitrile containing varying number and amounts of standard DNPH-carbonyls were prepared. The parent carbonyls are known components of vehicle exhaust emissions. The samples were designed to challenge the capabilities of the participants to separate, identify and quantify all the components. The fourteen participating laboratories included automotive, contract, petroleum and regulatory organizations. All participants were able to separate and identify the C3 carbonyls; a few were not able to separate MEK from butyraldehyde and methacrolein from butyraldehyde; and many were not able to separate adequately the isomers of tolualdehyde. Inadequate separation and lack of appropriate standards resulted in a few misidentifications.

Eleven experienced commercial automotive technicians were recruited and trained to repair IM240 emission failures using a specially developed 30 hour course. The training course emphasized the use of an oscilloscope and a flow chart and wave form strategy to repair vehicles. Each technicians' performance was evaluated based on the repair of three or four in-use Arizona IM240 failures. Pre-training and post-training written tests were also administered. Results from this limited study were encouraging. After the technician training, HC and CO emission levels were reduced by 69% and NOx by 58%. More importantly, most of the technicians learned some new and useful diagnostic and equipment skills which they can immediately apply to their businesses. They also became more motivated to tackle the challenge of repairing vehicles to low transient emissions, and aware of the existence and use of new sophisticated diagnostic tools such as oscilloscopes.

A Methanol catalyst test program has been conducted in two phases. The purpose of Phase I was to determine whether a base metal or lightly-loaded noble metal catalyst could reduce Methanol engine exhaust emissions with an efficiency comparable to conventional gasoline engine catalytic converters. The goal of Phase II was the reduction of aldehyde and unburned fuel emissions to very low levels by the use of noble metal catalysts with catalyst loadings higher than those in Phase I. Catalysts tested in Phase I were evaluated as three-way converters as well as under simulated oxidation catalyst conditions. Phase II catalysts were tested as three-way converters only. For Phase I, the most consistently efficient catalysts over the range of pollutants measured were platinum/rhodium configurations. None of the catalysts tested in Phase I were able to meet a NOx level of 1 gram per mile when operated in the oxidation mode.

The current trend by Class 2 and 3 truck manufacturers is to offer diesel engine options to those customers requiring more usable torque, better fuel economy and longer engine life than can be obtained from large displacement gasoline engines. This paper documents the collective efforts of Chrysler Motors and Cummins Engine Company to engineer the turbocharged, direct injection Cummins 6BT5.9 diesel engine into the Dodge Ram D/W 250/350 trucks. Included in the paper are detailed discussions of Cummins' development of the unique vehicle systems required to integrate the diesel engine into the existing truck package, and the methods used by Chrysler and Cummins to manage a joint effort of this magnitude. Also highlighted are the significant involvement of Chrysler manufacturing throughout the program, and the extensive use of modular assemblies by design, including major powertrain componentry.

There are many sources of variability when sampling motor vehicle emissions, including intermittant losses to “wetted” sampling system surfaces if water condensation occurs and thermal decomposition if sampling system surfaces get excessively hot. The risk of losses varies during typical transient speed emissions tests and depends upon many variables such as temperature, pressure, exhaust dilution ratio, dilution air humidity, fuel composition, and emissions composition. Procedures are described for injection of known concentrations of compounds of interest into transient motor vehicle exhaust for the purpose of characterizing losses between the vehicle tailpipe and emissions analyzer.

The influence of the addition of oxygenated hydrocarbons to diesel fuels has been studied, using a detailed chemical kinetic model. Resulting changes in ignition and soot precursor production have been examined. N-heptane was used as a representative diesel fuel, and methanol, ethanol, dimethyl ether, dimethoxymethane and methyl butanoate were used as oxygenated fuel additives. It was found that addition of oxygenated hydrocarbons reduced the production of soot precursors. When the overall oxygen content in the fuel reached approximately 30-40 % by mass, production of soot precursors fell effectively to zero, in agreement with experimental studies. The kinetic factors responsible for these observations are discussed.

On-vehicle proof-of-concept testing was conducted to evaluate the ability of the dual oxygen sensor catalyst evaluation method to identify serious losses in catalyst efficiency under actual vehicle operating conditions. The dual oxygen sensor method, which utilizes a comparison between an upstream oxygen sensor and an oxygen sensor placed downstream of the catalyst, was initially studied by the Environmental Protection Agency (EPA) under steady-state operating conditions on an engine dynamometer and reported in Clemmens, et al. (1).* At the time that study was released, questions were raised as to whether the technological concepts developed on a test fixture could be transferred to a vehicle operating under normal transient conditions.

Beginning in 2007, heavy-duty engine manufacturers in the U.S. have been responsible for verifying the compliance on in-use vehicles with Not-to-Exceed (NTE) standards under the Heavy-Duty In-Use Testing Program (HDIUT). This in-use testing is conducted using Portable Emission Measurement Systems (PEMS) which are installed on the vehicles to measure emissions during real-world operation. A key component of the HDIUT program is the generation of measurement allowances which account for the relative accuracy of PEMS as compared to more conventional, laboratory based measurement techniques. A program to determine these measurement allowances for gaseous emissions was jointly funded by the U.S. Environmental Protection Agency (EPA), the California Air Resources Board (CARB), and various member companies of the Engine Manufacturer's Association (EMA).