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This work is a continuation of earlier results presented by the authors. In the current investigations the biofuels hydrogenated vegetable oil (HVO) and 1-octanol are investigated as pure components and compared to EN 590 Diesel. In a final step both biofuels are blended together in an appropriate ratio to tailor the fuels properties in order to obtain an optimal fuel for a clean combustion. The results of pure HVO indicate a significant reduction in CO-, HC- and combustion noise emissions at constant NOX levels. With regard to soot emissions, at higher part loads, the aromatic free, paraffinic composition of HVO showed a significant reduction compared to EN 590 petroleum Diesel fuel. But at lower loads the high cetane number leads to shorter ignition delays and therefore, ignition under richer conditions.

Despite the trend in increased prosperity, the Indian automotive market, which is traditionally dominated by highly cost-oriented producion, is very sensitive to the price of fuels and vehicles. Due to these very specific market demands, the U-LCV (ultra-light commercial vehicle) segment with single cylinder natural aspirated Diesel engines (typical sub 650 cc displacement) is gaining immense popularity in the recent years. By moving to 2016, with the announcement of leapfrogging directly to Bharat Stage VI (BS VI) emission legislation in India, and in addition to the mandatory application of Diesel particle filters (DPF), there will be a need to implement effective NOx aftertreament systems. Due to the very low power-to-weight ratio of these particular applications, the engine operation takes place under full load conditions in a significant portion of the test cycle.

To comply with the new regulations on particulate matter emissions, the manufacturers of light-duty as well as heavy-duty vehicles more commonly use diesel particulate filters (DPF). The regeneration of DPF depends to a significant extent on the properties of the soot stored. Within the Cluster of Excellence "Tailor-Made Fuels from Biomass (TMFB)" at RWTH Aachen University, the Institute for Combustion Engines carried out a detailed investigation program to explore the potential of future biofuel candidates for optimized combustion systems. The experiments for particulate measurements and analysis were conducted on a EURO 6-compliant High Efficiency Diesel Combustion System (HECS) with petroleum-based diesel fuel as reference and a today's commercial biofuel (i.e., FAME) as well as a potential future biomass-derived fuel candidate (i.e., 2-MTHF/DBE). Thermo gravimetric analyzer (TGA) was used in this study to evaluate the oxidative reactivity of the soot.

Improvements in the efficiency of internal combustion engines has led to a reduction in exhaust gas temperatures. The simultaneous tightening of exhaust emission limits requires ever more complex emission control methods, including aftertreatment whose efficiency is crucially dependent upon the exhaust gas temperature. Double-walled (also called air-gap) exhaust manifold and turbine housing modules made from sheet metal have been used in gasoline engines since 2009. They offer the potential in modern Diesel engines to reduce both the emissions of pollutants and fuel consumption. They also offer advantages in terms of component weight and surface temperatures in comparison to cast iron components. A detailed analysis was conducted to investigate the potential advantages of insulated exhaust systems for modern diesel engines equipped with DOC and SCR coated DPF (SDPF).

As emission regulations are becoming increasingly stringent worldwide, multiple exhaust aftertreatment devices are considered in order to minimize diesel engine tailpipe emissions. For the typical diesel applications in developing markets like India, the fuel consumption is a very decisive selling argument for customers. The total cost of ownership needs to be as low as possible. To meet these competing requirements, the aftertreatment and engines must be optimized at the same time as the performance of the one system affects the other. In state-of-the-art calibration processes, the aftertreatment systems are considered separately from the calibration of the thermodynamics. This conventional approach makes it more challenging to achieve a simultaneous optimization of the fuel consumption and tailpipe emissions under transient operating conditions.

The limited availability of fossil fuels and the increasing environmental pollution will lead to an increased demand for sustainable biofuels. The production of bio-based diesel fuels from vegetable oils is commonly accomplished using a process known as Trans-esterification. The product of Transesterification is Fatty Acid Methyl Ester (FAME), commonly known as Biodiesel. An alternative process is Hydro-treatment of seed oils or animal waste fats to produce highly paraffinic renewable diesel fuel called Hydrogenated Vegetable Oil (HVO). Detailed investigations were carried out by the “Department of Advanced Diesel Engine Development” at FEV GmbH Aachen (Germany), to explore the potential of this biofuel compound as a candidate for future compression ignition engines.

The present work is a continuation of the earlier published results by authors on the investigation of Hydrogenated Vegetable Oil (HVO) on a High Efficiency Diesel Combustion System (SAE Int. J. Fuels Lubr. Paper No. 2013-01-1677 and JSAE Paper No. 283-20145128). In order to further validate and interpret the previously published results of soot microstructure and its consequences on oxidation behavior, the test program was extended to analyze the impact of soot composition, optical properties, and physical properties such as size, concentration etc. on the oxidation behavior. The experiments were performed with pure HVO as well as with petroleum based diesel and today's biofuel (i.e. FAME) as baseline fuels. The soot samples for the different analyses were collected under constant engine operating conditions at indicated raw NOx emissions of Euro 6 level using closed loop combustion control methodology.