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Six diesel, kerosene, gasoline-like, and naphtha fuels have been tested in a single cylinder diesel engine and a demonstrator vehicle, both equipped with similar engine technology and optimized for advanced combustion performance. This study was completed in order to investigate the potential to reduce engine-out emissions while maintaining engine efficiency and noise levels through changes in both engine hardware and fuel properties. The fuels investigated in this study were selected in order to better understand the effects of ignition quality, volatility, and molecular composition on engine-out emissions and performance. The optimized bench engine used in this study included engine hardware enhancements that are likely to be used to meet Euro 6 emissions limits and beyond, in part by operating under advanced combustion conditions, at least under some speed and load conditions.